Technical Note - Different Rates of Dissolution of Zinc by Aeration of Sphalerite in Different Container Materials

Results of experiments for dissolution of zinc by aeration of sphalerite in glass, copper, galvanised iron and stainless steel vessels of identical dimensions are reported. It was found that in a glass container dissolution of zinc reaches a maximum after 30 min aeration and then decreases whereas in the copper container dissolution remains nearly unchanged up to 30 min aeration and then increases. In the cases of galvanised iron and stainless steel containers zinc dissolution increased steadily with time up to 60 min aeration. It is suggested that the different rates of dissolution in glass and copper containers may be due to electro-chemical actions.