The Aluminum Reduction of Magnesium Compounds

DURING the last three years, investigations on the aluminum reduction of magnesium-bearing compounds have been initiated at the Institute of Inorganic Chemistry, The Technical University of Norway. The results of these investigations are reported in this paper. Very little information exists in the literature on the reaction between magnesium compounds and metallic aluminum. The available information itself is conflicting, and, to clarify the existing discrepancy, the reactions between aluminum and magnesium oxide (MgO), caJcined dolomite (CaO . MgO) and olivine (Mg2SiO.) were studied. The logical approach for the study of these reactions between condensed states with the formation of a gaseous phase is, ( 1) the measurement of the equilibrium vapour pressure of the gas, in this case magnesium, associated with the respective reactions and, (2) the identification of the end products of the reaction in order to establish the re-action scheme.