The Application of Atomic Absorption Spectrometry to the Determination of Precious and Base Metals

"Extraction of Gold in Ketone from a suitably prepared sample of sulphide or siliceous ore or concentrate permits a rapid and accurate determination by Atomic Absorption. Mill test products and exploration development samples are acid-treated to effect complete dissolution of silver, copper, zinc, lead, molybdenum and iron present. Interferences in the determination of molybdenum are described. Results by Atomic Absorption are comparable to those afforded by other acceptable methods.INTRODUCTIONDuring recent years much has been written and discussed concerning Atomic Absorption Spectrometry as a technique for determining the concentration of metallic elements. We would, however, recommend a perusal of the paper presented by J. C. Ingles at the annual meeting of Canadian Gold Metallurgists held in Ottawa, January, 1966. The paper was published in the August, 1966, issue of the Canadian Mining Journal, and contains general information on Atomic Absorption.The purpose of our paper is to present certain specific method procedures for the determination of several precious and base metals normally present in Mine, Mill and Smelter products. Of necessity, analytical results should be as accurate as the most suitable available method permits, whether for metallurgical balance, settlement purpose, ore beneficiation programs, or exploration property development. The success of such programs is relative to the accuracy, speed and economics of the analysis. It is obvious, therefore, that in presenting our paper we consider the technique has achieved the desired evaluation."