The Chemistry And Structure-Activity Relationships For NEV Sulfide Collectors

The chemistry and structure-activity relationships for four new classes of sulfide mineral and precious metals collectors developed recently are discussed in this paper. These collector classes are alkoxycarbonyl alkyl thionocarbamates and thioureas, dialkyl (or diaryl) monothiophosphates and dialkyl monothiophosphinates. The main emphasis will be to highlight the differences between collectors and their affinities for various minerals on the basis of data on kinetics of adsorption on pure minerals, natural ore flotation and microscopy of flotation concentrates. The mechanism of interaction of these collectors with sulfide minerals is also discussed with the available data on the FTIR and solution chemistry studies.