The Development Mechanism Of Surface Charge Of Serpentine And Implications For Sulphide Flotation

The development of surface charge of serpentine mineral and implications for sulphide ?otation have been studied through flotation tests, sedimentation tests, zeta potential measurements and optical microscope photos. The results show that the serpentine mineral was positively charged at an extensive pH range, with an isoelectric point (IEP) of 11.9. The magnitude and sign of the pyrite particles were pH dependent and were negative for pH values above 2. At pH value 9, where ?otation of nickel sul?de ores is routinely performed, serpentine and pyrite particles attract through an electrostatic mechanism. Slime coatings of serpentine adhere to the surface of pyrite, reducing pyrite flotation recovery. The removal of magnesium ions from the serpentine surface by acid leaching results in a decrease of serpentine IEP and eliminates the adverse effect of serpentine on pyrite flotation. Therefore, it has been clearly established that the surface charge value developed in the serpentine/aqueous electrical interface is a function of the serpentine surface incongruently dissolution. As a result of hydroxyl dissolution, the magnesium ions are left in serpentine surface, which is responsible for serpentine surface charge. The methods, which can remove magnesium ions from serpentine surface, can be used to eliminate the adverse effect of serpentine on pyrite flotation.