The Dissolution Behavior of Gold in Ammoniacal

The leaching of gold in ammoniacal solutions containing various oxidants in an autoclave has been investigated. Also studied are thermodynamic and kinetic aspects of the ammonia leaching of gold and silver. The variables studied included stirring speed, temperature, concentration of ammonia, ammonium, and various anions. Arrhenius activation energy values were found to be between 47.1 kJ/mol and 86.2 kJ/mol depending upon the kinds of oxidants used. An electrochemical reaction controlling mechanism has been proposed for the dissolution reaction. The leaching behavior of gold and silver from various ores in ammoniacal solutions containing various oxidants has also been investigated. The samples tested included sulfidic as well as carbonaceous refractory ores. The recoveries of gold and silver from these refractory ores were better than 96% within 2-3 hours of leaching time.