The Effects of Zirconium in Cast Iron

Abstract Zirconium markedly affects the formation of graphite in cast iron and may promote the formation of normal flake gaphite, fine flakes of eutectiform graphite, or spheroid nodular graphite, according to the composition of the Iron and the amount of the zirconium addition. Usually, it is employed in the form of a complex addition agent in order to facilitate its introduction and to guide its effect. The reported applications of zirconium as an inoculant for the production of pearlitic high-strength cast iron indicates that it is most effective as a silicon-manganese-zirconium alloy. Added in this form it reduces chill and minimizes zones of ferrite and eutectiform graphite. In low-sulphur cast iron, zirconium in amounts greater than 0.10 per cent tends to promote the development of eutectiform graphite. These irons are characterized by freedom from primary cementite or normal flake graphite and exhibit very little tendency to shrinkage on solidification. In hyper-eutectic low-sulphur cast iron, zirconium causes the formation of a partially nodular graphite structure. A combination of magnesium with silicon-zirconium alloy was found to produce completely nodular graphite structures without the hazards associated with the addition of elemental magnesium.