The interactive effects of the sulphite ion, pH, and dissolved oxygen on the flotation of chalcopyrite and galena from Black Mountain ore

These effects were investigated in batch flotation studies, and by the measurement of rest and pulp potentials. At Iow additions of sulphurous acid as the pH regulator, flotation rate increased with increasing concentrations of dissolved oxygen. The recovery of chalcopyrite dropped significantly below a pH value of about 6,5 at 25 p.p.m. of dissolved oxygen, and below a pH value of about 6 at a dissolved-oxygen concentration of 8,2 p.p.m. The rest and pulp potentia Is measured indicated that dixanthogen is the dominant species formed on chalcopyrite surfaces during flotation with sodium ethyl xanthate. The results suggested that the same species might have formed on galena surfaces in the pulp after the ore had been milled in a ceramic mill under nitrogen. Increased additions of sulphurous, sulphuric, and hydrochloric acids increased the rest potentia Is, while the addition of sodium sulphite decreased these potentials.