The Kinetics of Elution of Gold Cyanide from Activated Carbon

The Zadra, AARL and organic elution processes and variations of them are presently widely used to recover gold from activated carbon. Despite this the study of the kinetics of elution have received relatively little attention. It is the aim of this study to investigate the rate processes taking place during elution in both inorganic and organic solutions. Batch adsorption and elution rate and equilibrium experiments were performed. The spatial concentration of gold inside carbon particles at various stages of the adsorption and elution processes were measured with a scanning electron microscope using an image analyzer to control and manage the micro-analysis data. The activated carbon particles exhibited film and intra-particle mass transfer rate- controlled behaviour during adsorption in a caustic aqueous solution at 95°C. Elutions in the aqueous caustic acetone solution at 30°C and the caustic aqueous solution at 95°C were unaffected by change in stirring rate. Elution was modelled by desorption reaction rate-control at the outer surface of the carbon particle. Adsorption and elution isotherms under duplicated solution conditions showed reasonable agreement for the inorganic solution and a large disparity for the organic solution.