The Minerology and Geochemistry of the Whim Creek Gossan

The gossan developed from the Whim Creek Cu-Zn-Pb-Ag sulphide deposit, in the Pilbara region of Western Australia, occurs near the top of a ridge in a dissected plateau 01 moderate relief. The gossan is characterized by the abundance of secondary ore minerals which indicates that it is relatively immature, due to climatic conditions and erosional stripping.The abundant presence of secondary carbonates indicates that the low pH generally resulting from sulphide oxidation has been neutralized, probably by the buffering effect of carbonatcs and silicates. Fe, Cu, Pb, 'Ag and Sn have been enriched in the gossan relative to the primary ore, and Mn, Ti, Co and Ni have been strongly depleted; other elements have remained substantially unchanged. The gossan has a strong gcochemical signature characterized by high Cu, Zn, Pb, As, Sb, Sn, Ag and Mo coutents. Boxwork textures are poorly developed, bu't the gossan has other diagnostic mineralogical features including sulphide inclusions in quartz and the presence of residual cassiterite.