The non-oxidative dissolution of nickel sulphides in aqueous acidic solutions

An account is given of a study on the non-oxidative dissolution in aqueous acidic solutions of nickel sulphides of different stoichiometric composition, in which a rotating ring-disc electrode was used. The rate of dissolution was found to depend on the potential of the sulphide and the nickel-to-sulphur stoichiometric ratio. A maximum rate for the dissolution of nickel from nickel sulphides containing an excess of nickel was recorded at potentials around -0,2 to -O,3V. The rate decreased markedly at more anodic potentials. For nickel-deficient nickel sulphides, the nonoxidative dissolution rate increased with a cathodic shift in potential. Under open-circuit conditions, a nickel sulphide of a composition approximating Ni ,S. reacted most rapidly. The dissolution rate was controlled by either a chemical or an electrochemical reaction at the electrode surface, had an activation energy of between 50 and 65 kJ.mol-1, and was independent of stirring speed.