The potential application of natural minerals in ceramic and metal-matrix composites

"Current practice in advanced materials processing has involved the dispersion of a second-phase, commonly SiC, glass, or other non-metallic fibres/whiskers/particulates to enhance physical characteristics of the matrix. These matrices may be either ceramic or metallic but in either case it is important that the physical and chemical properties of each phase be compatible. The dispersed, finely divided second phase is often both expensive and foreign-produced and may exhibit chemical instability at elevated temperatures. Thus, it would appear that certain naturally-occurring industrial mineral fibres/whiskers/particulates might offer an attractive and low-cost alternative. Suitable candidates, such as wollastonite and sillimanite, are available in Canada and may be milled to produce particles whose shape is appropriate for this application. It is suggested that wollastonite, in particular, may be a useful modifying agent in metal matrix composites utilizing AI, Al-Si, Zn-Al or other light metals and alloys. In addition, the possible use of these minerals in ceramic matrix materials is also addressed, with reference to a preliminary thermodynamic analysis of the systems involved.IntroductionBackgroundA composite material may be thought of as consisting of a matrix component, the properties of which are improved by the addition of a second component or dispersed phase which forms a distinct three-dimensional interface with the matrix. This matrix is commonly either metallic or ceramic, which leads to the two most popular types of composites: metal-matrix composites (MMC); and ceramic-matrix composites (CMC).Such materials are by no means new. Early composites include fiberglass, mixtures of plaster and horsehair in wall plastering, as well as use of natural materials such as bamboo in fishing rods. Some of the newer applications include high strength, low-weight bicycle rims, as well as the more familiar role in aircraft and automobile engine components."