The Recovery of Copper from Lead Blast Furnace Bullion

Copper entering a lead ,smelter in concentrate or from other sources is recoVered as matte and speiss which contain appreciable quantities of lead. The matte and speiss are usually sold to copper smelters to recover the copper content and also any gold and silver in these products, but the value of the lead is largely lost. Some copper plants pay for portion of the lead content, but regarded as a means of recovering lead it is more costly and less efficient than if the lead were recovered at the lead smelter.Because of the value of this lead loss, the metallurgy of copper recovery has assumed greater importance in recent years owing to the rise on the price of lead.Two processes are in use today to produce matte and speiss, namely the iron matte process and the soda matte process developed by the American Smelting and Refining Co. 1 in D.S.A. The latter process is characterised by a higher copper to lead ratio than the older iron matting process.The following analyses are typical of matte and speiss produced at Broken Hill Associated Smelters, by both processes, although the soda matte process is still in a developmental stage and experience indicates that matte and speiss of lower lead tenor can be produced under favourable conditions.