The Role of Sulphurization in the Genesis of Iron-Nickel Sulphide Deposits of the Porcupine District, Ontario

"Sulphurization of peridotite, that is 'to say reaction between sulphur from an external source and iron and nickel in the silicate minerals of the peridotite or in partially consolidated magma, is believed to be the me-chanism by which the small iron-nickel sulphide deposits associated with the ultrabasic rocks of the Porcupine district have formed.The pyrrhotite-pentlandite ore at the Alexo mine, Dundonald township, is localized by a shear that closely follows the lower contact of a peridotite lens. In the past, to account for this orebody, the magmatic segregation hypothesis has been advanced on the basis of textural evidence and the presence of the sulphides at the base of the lens. The nickel sulphide de-posits of the Porcupine, however, are not characteristically found along the basal contacts of bodies of peridotite. Furthermore, this study has shown that textures formerly thought indicative of magmatic segregation have been formed in certain deposits by the selective replacement of silicates by sulphides.At the Alexo mine, very minor amounts of pentlandite and heazle-woodite (Ni3S2) occur in the peridot-ite hanging wall adjacent to the ore. These sulphides are interpreted as having formed by sulphurization, the sulphur involved coming from the pyrrhotite-pentla.ndite ore emplaced along the shear. This reaction aureole raises the question of the role of sulphurization in the formation of the main mass of the sulphide ore. The very localized equilibrium that has been found to exist between sulphides and silicates in deposits throughout the area, the results of nineteen sulphur isotope determinations, and the abundance of pyrite and pyrrhotite in the volcanic country rocks of the Porcupine indicate that these deposits were formed by sulphurization rather than magmatic segregation."