The Structure - Property Relationship Of Polymers Used In Red Mud Flocculation

High anionic functionality acrylamide co-polymers and poly(sodium acrylate) are used as red mud flocculants in bauxite processing operations. These synthetic polymers are effectively displacing starch as the dominant polymer in red mud settling. The performance of these polymers is primarily dependent on the bauxite mineralogy, the alkalinity of the red mud slurry, and the anionic functionality and molecular size (viscosity) of the polymer. In this paper, the physical and chemical properties of the synthetic watersoluble polymers will be reviewed. The relationship between polymer structure and red mud slurry properties as they control polymer performance in settling red muds common to digester and washer circuits will be illustrated. The availability of polymers of varying functionality and viscosity will permit bauxite processors to make significant improvements in the economics of red mud disposal and valuable reagent recovery.