The Use of an Agitated Bed of Particles as an Electrode System for Metal Deposition

A number of suggestions have been made to improve the design of cells used for electro winning and electro refining of metals. Most of these designs have been aimed at increasing the current density used in order to improve cell capacity, although the purpose of some has been to produce electro deposited metals in a continuous manner. Improvements in the electrolyte flow pattern in conventional cells have resulted in an increase in the rate of mass transport of metal ions to the electrode surface; giving rise to lower concentrat- ion polarization and an improvement in the nature of the product obtained, Other cell designs are based on a moving electrode, usually a rotating disk, and these may include provision for removal of the product in a continuous manner, The maximum current density which can be used in an electro- lytic deposition process is determined by the limiting diffusion current, the physical nature of the, product, the purity of the product required and by the increase in power costs which result from the higher cell voltages, This paper examines the properties of an agitated bed of particles as an electrode system when used for a metal deposition Process,