Theory and Practice of Roasting Sulphide Concentrates

"IntroductionIN 1940, in a series of articles, M. W. von Bernewitz(l) reviewed in detail roasting of gold and silver sulphide ores and concentrates. Since that time some significant developments in roasting have taken place, and a number of papers have appeared in the Canadian technical literature, dealing severally with the roasting of a particular ore or concentrate.The purpose of this paper is not only to review some of these Canadian papers and bring the information on Canadian roasting practices to .date, but also to analyse the mechanism of roasting. Hence, it is proposed to start with a study of physico-cl1emical factors fundamental in roasting, the knowledge of which, by creating a sound basis for a proper roaster design, makes good roasting possible.Physico-Chemical FactorsRoasting can be defined as heating sulphide ores in presence of air below fusion points of the constituent minerals, at such temperatures as to convert metallic sulphides to oxides. Hence, roasting is a chemical process.The object of roasting is, by changing, chemically, mineral constituents of sulphide ores, to make the economic recovery of the desired •Constituent metal by a subsequent standard treatment possible. For instance, pyritic ores, containing gold in sub-microscopic form which no amount of grinding would release, are roasted in order, by oxidizing the sulphides, to open up their structures to such an extent as to enable cyanide solutions to come into contact with the gold and dissolve it. The production of porous calcine is, therefore, the object of roasting of refractory auriferous sulphide ores or concentrates. Such a porous calcine may be defined as a desirable calcine, and the roasts which produce desirable calcines can in their turn be termed desirable roasts."