Thermal Production of Magnesium

Introduction The production of magnesium by direct reduction of the oxide has far passed the experimental stage and was responsible for 30 per cent of the recent wartime production of 246,000 tons per annum. This paper describes the small-scale experiments which culminated in a number of the wartime plants. The paper traces the author's early experiments on various direct reduction reactions leading to his choice of the ferrosilicon reduction of dolomite and the realization that this reaction would proceed at a satisfactory rate at temperatures obtainable in metal apparatus. MgO has a standard heat of formation of 146,100 cal. and is therefore one of the most difficult oxides to reduce. However, if advantage is taken of the relative volatility of magnesium metal, thermally unfavourable reactions may be utilized. In reaction MgO + X = XO+ Mg . . . . . . . . . . . . . (1) the removal of Mg as a gas at high temperatures displaces the equilibrium to the right in the face of the unfavourable thermo-chemistry which is inevitable with any X other than calcium metal. If X is carbon, not only is the reaction highly endothermic, but CO is gaseous. A temperature of l,864°C. is required to produce a pressure of one atmosphere of Mg. Between l,900°C. and perhaps 400°C., the back reaction takes place readily and special shock cooling devices are required to recover magnesium from the gaseous mixture. This reaction does not lend itself to small-scale experiments and was not examined by the author. If, in reaction, carbon is replaced by a relatively pan-volatile metal, the oxide of which is also non-volatile and possesses a fairly high heat of formation, a reduction reaction is offered which is free from the difficulties associated with carbon. The typical case of silicon will serve as an example: 2MgO + Si = SiO2 + 2Mg (g) . . . . . . . . . . . . . . . . . . . . . . (2) At temperatures above l,000°C., a positive pressure of magnesium will exist over the system. Removal of the magnesium vapour will displace the reaction to the right in the face .of an unfavourable thermal balance. Since magnesium is the only volatile component at this temperature, it may be evolved and condensed, using attractively simple distillation technique.