Thinning of the Ozone Layer

It has become increasingly clear in recent years that human kind has developed the capacity to alter the environment of the Earth on a global scale. The changes are often subtle. This is particularly true in the case of stratospheric ozone. Ozone is produced primarily in the stratosphere, at altitudes in excess of 20 km, initially through the action of ultraviolet sunlight dissociating molecular oxygen. According to theory as it existed up to a few years ago, ozone is removed mainly by reaction with atomic oxygen. In the unperturbed environment, this reaction proceeds both directly, and by paths catalyzed by trace quantities of nitrogen radicals. Molina and Rowland [Nature, 249, 810, 1974] pointed out that decomposition of industrial chloroflurocarbons could in-troduce an additional source of radicals to the strato-sphere. Chlorine radicals are even more efficient than nitrogen in catalyzing recombination of oxygen atoms with ozone; models suggested that we might expect reductions in the vertical column density of ozone of as much as a few per cent over the next several decades. A reduction in ozone of x¦/a, by increasing the flux of ultraviolet sunlight reaching the surface, was predicted to result in an increase of about 2x% in the number of cases of skin cancer, with other less well defined impacts on the non-human environment for life.