Total Recycling of Spent Auto-Catalyst using Alkaline Roasting and Sulfuric Acid Dissolution

"Spent auto-catalyst is a potential secondary resource because of the higher concentration of valuable platinum group metals (PGMs) as compared to the primary ores. Despite the well-developed commercially tenable technologies, further researches are being carried out to extract the PGMs with high efficiency. It is however, critical in this context to reuse not only the PGMs but also other metals contained in the spent auto-catalyst particularly that of the cordierite substrate such as aluminum, magnesium and cerium oxide (CeO2). This is important in view of the fact that no recycling process has ever stressed upon the recovery of cordierite substrate and CeO2 since the main target metals are mostly the PGMs. In this study, a new hydrometallurgical approach has been proposed in order to recover the PGMs as well as cerium oxide and materials from the cordierite substrate by using sodium hydroxide roasting followed by sulfuric acid dissolution. Under the optimal conditions for roasting at above 600°C, and weight ratio of sample to NaOH of 1:1 for 60 min, the cordierite was converted to the soluble phases. Dissolution of the roasting products using H2SO4 solution (1M) at 25°C for 60 min enriched the PGMs and Cerium oxide contents in the residue. Subsequently, PGMs in solution after dissolution can be cemented using Al and Cerium oxide in residue can be recovered by hot digestion using concentrated H2SO4.. INTRODUCTION Auto-catalyst can significantly control the gaseous emission of automobiles, and has been considered as a potential secondary source of Platinum group metals (PGMs) after being decommissioned from the vehicles. The PGMs demand is continuously increasing to comply with the growing vehicle population and the tightening of emission standards all over the world; meanwhile the natural resources of these metals is facing the threat of depletion. Therefore, it is crucial to progressively substitute with an alternate resource to supply PGMs other than that of the primary ores. Nowadays, vehicular transportations worldwide are totally installed with the auto-catalysts. However, they should be replaced after reaching their service life. If there is no recycling of such resources, huge amount of valuable metals will be wasted. The quantity of PGMs that can be recovered from the spent auto-catalyst depends on the size of car, which averages to 1-2 grams for small cars and 12-15 grams for the big truck; this is significantly higher than that of the primary ores containing 2-10 grams PGMs per ton. Consequently, the recovery of PGMs from spent auto-catalyst becomes extremely favorable as compared to the primary resources due to higher concentration of PGMs, with much lower and simpler processing steps, and lesser pollution."