Triethylenetetramine (TETA) - Powerful Leachant in Lead Recovery

PbSO4 is a commonly encountered component of the materials used in lead recycling (e.g. battery paste) and in by-products of metallurgical processes (e.g. residues from zinc hydrometallurgy, dust from copper smelting). Smelting of battery paste results in SO2 emission and in generation of significant amounts of hazardous ‘white slag’. Those adverse phenomena can be eliminated by removal of sulphur from the paste. Lead-bearing by-product materials are of polymetallic character with usually low Pb content, which makes lead recovery technologically difficult and uneconomic. However it can be successfully achieved by extraction of lead sulphate from solid phase with triethylenetetramine (TETA) water solutions. That compound has capability for selective solvation of a whole lead sulphate molecule. Virtually pure lead carbonate can be precipitated by means of saturation of lead-loaded aqueous TETA solution with carbon dioxide, and complete regeneration of the extractant is achieved by fixing of sulphate ion into gypsum through operation of calcium hydroxide suspension. The paper presents results of the lab and pilot scale studies into process of battery paste desulphurisation and recovery of lead from the residue of zinc calcine leaching.