Understanding Spontaneous Detonation of Ammonium Nitrate

Approximately 1.5 million tonnes of ammonium nitrate are transported annually across Queensland, Australia—equivalent to nearly 100 truckloads per day. This is in the form of both AN prill and ammonium nitrate based emulsions (ANE). In a recent incident, a collision involving an ANE tanker resulted in a detonation that caused extensive blast-related damage and led to the closure of a major highway. Had this event occurred within a populated area, the consequences would have been catastrophic. For over a century, investigations into the causes of such spontaneous detonations have been inconclusive. A recently completed industry supported research project has made a pivotal discovery: a surface reaction mechanism leading to hydrogen generation has been identified as a precursor to detonation. If sufficient hydrogen accumulates and subsequently ignites, it can release enough energy to initiate the detonation of bulk ammonium nitrate and ANE. Controlled experiments conducted during the project successfully demonstrated hydrogen-driven detonation events. Previous work by Proulx and Scovira, presented at the 2000 ISEE Conference, described spontaneous detonations in hot, reactive ground and the mitigating effects of buffered emulsions and ANFO. Building upon their observations, this study reproduces similar incidents under laboratory conditions, confirming that hydrogen generation also results from reactive ground interactions. Importantly, the findings challenge traditional assumptions, demonstrating that ammonium nitrate and ANE detonation in reactive environments does not require an ignition temperature threshold, confinement, or a classical chemical decomposition pathway.