Use of Non-Ionic Surfactants as Emulsifier in Coal Flotation: An Experience from Lab-Scale to Plant

Reagents form a crucial part of flotation process as they have the power to control the surface properties of minerals. In case of coal flotation, collectors and frothers are two the important and commonly used reagents. But other types of reagents such as promoters, modifiers and depressants are also finding wide applications because of their availability to improve selectivity and increase recovery. Because of these chemicals the scenario has changed from flotation being used mostly for high rank hydrophobic coals to low rank, oxidised or inferior coals. In the present work a case is presented in which two non-ionic surfactants (abbreviated as A & B) known to act as emulsifier have been studied to get a better flotation performance for a preparation plant with varying feed characteristics. Laboratory flotation tests were conducted with both the surfactants using three feed samples of the plant by varying the dosage at three different levels. The highest combustible matter recovery (more than 80%) was obtained for surfactant B at a dosage of 75 ppm (parts per million) for feed 1. But at the same dosage the recovery decreased by 21% and 10.2 % respectively for feed 2 and 3. On the other hand surfactant A showed a consistent result for all the three feed samples giving the highest value at a dosage of 50 ppm followed by a decrease beyond this point. The tests were complemented by contact angle measurements that demonstrated the same trend. In addition to this the reproducibility of data for Surfactant A was checked and found that the standard deviations for both separation efficiency and combustible matter recovery were within the permissible range (less than 5%). Finally an in-plant process optimization study to evaluate the performance and applicability of surfactant A at industrial level was done and has been discussed.