Using Liquid Carbon Dioxide to Extract Platinum Group Metal-Chlorides from Aqueous Streams

Liquid carbon dioxide can be used as a replacement for organic solvents in the extraction of anionic PGM complexes from an aqueous phase. This can be achieved only if highly carbon dioxide-soluble chelating agents are developed because conventional chelating agent-metal complexes, such as trioctylamine-gold chloride, are not soluble in liquid carbon dioxide (although trioctylamine is CO,-soluble). Our novel CO,-soluble chelating agents have a fluorinated tail and a conventional amine head group. Both the chelating agent and the chelating agent-metal complex are soluble at ambient temperature at pressures between 7-35 MPa. Equilibrium constants in the 105 range have been measured (in Freon 113, a low pressure screening liquid for carbon dioxide), indicating that these compounds will strongly bind the metal chloride. For example, 93% of Pt-chloride was extracted into Freon 113 using a 3.5:1I ratio of a double-tailed fluoroalkyl amine chelating:metal chloride. 88% recovery of Pt-chloride into liquid carbon dioxide was achieved using the same chelating agent at a 3.5:1 ratio.