Wear behavior of martensite and ferrite in high chromium steel balls in wet grinding and implication to flotation

The wear behaviors of grinding media with different chemical composition and microstructures in wet grinding of a quartz-pyrrhotite mixture were investigated under various environments. The marked ball wear tests showed that the wear rate could be minimized by a suitable combination of martensite and ferrite within the same ball. A ball composed solely of hard martensite exhibited increased wear under an oxygen environment, while balls composed of both soft ferrite together with hard martensite exhibited decreased wear due presumably to the difference in their passivation behaviors. The galvanic interaction between the two phases as well as among these phases and an electroactive mineral were investigated through electrochemical measurements under abrasive condition in a slurry. The rates of formation of passive film controlled the corrosion currents of the high chromium steel media. Corrosive wear and its effect on flotation are discussed using the passivation kinetics model thereby developed.