X-ray diffraction study of stress state in nanoaluminium and metal?hydrogen systems produced by mechanical alloying of powders

Interest in metal-hydrogen systems can be manifold. Small amounts of hydrogen adsorbed by elemental metals and alloys usually result in strong changes in the physical and mechanical properties of engineering materials. Overwhelmingly, these changes, viz. hydrogen embrittlement, are considered deleterious with respect to structural performance of engineering materials. However, the changes, often studied by metallurgists and metal physicists, can present new possibilities and applications. A prominent example is the recent interest in safe, solid-state hydrogen storage in metallic lattices. In a new laboratory in MTL, Ottawa, a study has been initiated to investigate the effect of "micro- and macro- alloying" of Al and Mg powders with hydrogen (in high-energy mechanical alloying mills) on plastic deformation in metal and metal hydride structures. It is anticipated that high-rate impacting and subsequent grain refinement in the mill will have an effect on hydrogen storage capacity in lightweight magnesium and aluminum alloys. First examination of the state-of-stress by X-ray diffraction in high-rate milled, nanostructured pure aluminum, aluminum milled with a solid surfactant, and aluminum or magnesium alloy milled with hydride and/or gas hydrogen will be presented.