X-Ray Microtomography Analyis Of Aluminum Electrolysis Cathodes

The phenomena occurring in the cathode and at the cathode surface of aluminum electrolysis cells are very important in regards to cathode voltage drop and cathode wear. In the current study, laboratory-scale aluminum electrolysis cell cathodes were analyzed by X-ray microtomography. This technique allows an excellent visualization of the distribution of different substances, if their respective X-ray attenuation coefficients are different enough. In the current case, the important difference in the mean atomic number between cryolitic bath and graphitic carbon results in good contrasts. The volumetric bath penetration profile, porosity and impurities distribution in the cathode were thus obtained. Furthermore, metallic impurities and bath heterogeneities were observed at the cathode surface. Observations were also made with Scanning Electron Microscopy - Energy Dispersive Spectroscopy (SEM-EDS).