XPS studies of chalcopyrite and sphalerite surface modification by high: Power electromagnetic pulses (HPEMP)

"XPS investigations of the influence of HPEMP - treatment duration on the surface composition for natural chalcopyrite and sphalerite are described. HPEMP is a video pulse with a nanosecond front lasting between 5 and 10 ns. The electrical field component can reach 30 kV, whereas pulses repetition frequency is 100 Hz. In general, the formation of metal-deficient surfaces, polysulphides or elemental sulphur and oxides/hydroxides, were determined during the treatment for both sulphides as well as the essential differences of the way of mineral surface transformation during the treatment. The chalcopyrite surface shows the formation of elemental sulphur under the HPEMP treatment at 103 pulses while appearance of unstable sulphite species was detected at the chalcopyrite surface within 5 seconds (0.5•103 pulses) under the same treatment conditions. The results indicate that the quantity of adsorbed water (at.%) is changed considerably during the HPEM - treatment depending on treatment duration for both minerals. The concentration of water onto the chalcopyrite surface decreased during 30 seconds (3•103 pulses) of the HPEMP - treatment and it rose after the treatment at 5•103 pulses. The inverse dependency was obtained for sphalerite surface. Single mineral flotation tests have shown the significant increasing of the minerals recovery."