Zero emission gas power - A concept of integration between SOFC and absorption enhanced gas reforming

Zero Emission Gas power, ZEG, is a novel concept where a high temperature solid oxide fuel cell (SOFC) is integrated with a reforming reactor producing hydrogen from natural gas through Sorption Enhanced Steam Methane Reforming (SESMR). The SOFC is used as a high temperature heat source for regeneration of the CO2-absorbent. Moreover, by using part of the produced hydrogen as fuel for the SOFC, the waste heat of the process is considerably reduced. Thus, the process has a very high thermal efficiency and produces both electricity and hydrogen from natural gas. In addition, a stream of pure CO2 is produced in the regeneration step and can be deposited or used commercially. Initial cost estimates indicate a cost of electricity and a cost of hydrogen well below today's prices. A small (1kWel + 1kW H2) demonstration set-up is under construction and experimental results and related research will be presented. This set-up comprises one 2.5kWth H2 SESMR-reactor (about 0.85 Nm3/h H2) operating batchwise with dolomite as the CO2-sorbent. The reactor developed is designed like a parallel plate heat exchanger where the mixture of sorbent and reforming catalyst is packed between the heat exchanging plates. The demonstration set-up includes a 1kW SOFC operating in a continuous mode. The set¬up will therefore demonstrate continuous simultaneous hydrogen- and electricity production, but cannot demonstrate simultanuous electricity- and CO2-production. The set?up is well equipped for on-line monitoring of gas composition, flows and temperatures. This important part of the demonstration set-up is developed and provided by Christian Michelsen Research (CMR). A minor part of the project is the development of a continuous circulating fluidized bed SESMR-reactor system and in another related project the focus is on the development of more suitable sorbents. In these two projects co-operation with University of British Columbia and Lousianna State University, respectively, is highly appreciated.