Search Documents

SAMUEL T. HOYT,? Minneapolis, Minn. (written discussion||).-The subject of grain inheritance in iron and steel is apparently one which can he considered from the point of view of the two laws governing the rate of formation of crystal nuclei and the linear velocity of crystallization, which have been investigated by Tammann and collaborators, and of the additional law of coalescence. According to the work of Tammann, both the nuclei number, which is taken to be the number of crystal nuclei to form per unit volume per unit time, and the linear velocity of crystalli-

Jan 5, 1918

By Volker Ruth

DURING an experimental investigation of the Kirken dall effect in the Ag-Au system, cracks along grain boundaries in connection with a shift of adjoining crys tallites are observed on the gold-rich side of the couple. Also on the gold-rich side the formation of a zone of small protrusions is found.' The growth law of the width of this zone indicates that the protrusion formation is a secondary effect of diffusion. The protrusions are not found within a distance of approximately 60 from a grain boundary. Unaffected regions along grain boundaries were also observed by Doherty and Davis during precipitation of vacancies in aluminum2 and by Wyon and Lacombe during precipitation of iron in aluminum.3 Thus we may suppose that we have an effect analogous to precipitation in which the crystal tends to maintain its equilibrium vacancy concentration by transporting excess atoms to the surface. At an early stage (i.e., before sintering has influenced the shape of the protrusions) the protrusions have similar shapes (three sided pyramids and roof shapes) and similar orientations within a single grain but vary from one grain to another. Further experiments were carried out on cylindrical Au-Ag single crystal couples. During the weld-

Jan 1, 1963

By A. C. Halferdahl

DURING a study of reactions involving iron sulfides, it became desirable to know approxi-mately the heat of decomposition of pyrite. The values given for the heats of formation of pyrite and ferrous sulfide are 35,500 calories and 23,070 calories respectively. For the reaction 2FeS2= 2FeS+S:, the heat effect would be-24,860 calories. But pyrite gives sulfur and pyrrhotite upon heating and the latter is a solid solution of sulfur in ferrous sulfide. The only meas-urements of this decomposition are those of Allen and Lombard1 of the Geophysical Laboratory who have measured dissociation pressures of both covellite and pyrite and have carefully reviewed the literature. They give a table of values for covellite as determined by Preuner and Brockmoller2 and by Wasjuchnowa3 and compare these values with their own measurements. The conclusion is that the measurements of Preuner and Brockmoller are seriously in error, while Was-juchnowa's values fit in well with those of Allen and Lombard. Wasjuchnowa's measurements were made by a dynamic method, while Allen and Lombard em-plowed a static method on both covellite and pyrite. Tables I and II reproduce the measurements of Wasjuchnowa and of Lombard and Allen on covellite and pyrite.

Jan 11, 1927

By S. R. B. Cooke, S. W. Clark

Adsorption of calcium and magnesium by quartz was determined over a wide pH range using flame photometry for solution analysis. A parallelism was noted between calcium adsorption at alkaline pH and flotation of activated quartz by means of various fatty acid collectors. Abstraction of calcium from 100 ppm solutions increased above pH 10.5 until all of the calcium was removed at pH values between 12 and 12.5. Calcium was desorbed from the quartz over the pH range 12.5 to 13.0 and returned to the solution. Precipitation of magnesium hydroxide prevented measurement of magnesium adsorption above a pH of 9.9. A calcium adsorption isotherm determined at pH 9 matched measurements of barium adsorption by other investigators over the range where adsorption corresponded to the equation of a Freundlich adsorption isotherm. In accordance with the Gouy-Chapman theory for adsorption in the diffuse layer, adsorption of the divalent cations under these conditions was four times the adsorption of monovalent sodium. Activation of quartz by multivalent metal cations in flotation using anionic collectors has been studied by many investigators. The occurrence of activator cations in the water of flotation mills makes depression of silaceous gangue very difficult. Alternatively, in some flotation systems it is practical to cause activation of quartz so that it is floated from the desirable mineral values. The present study was initiated to investigate the activation of quartz by measuring adsorption of calcium and magnesium ions as a function of solution pH. Early empirical tests showed that quartz would be activated to flotation using anionic collectors if any of a number of divalent or trivalent metallic cations were present in the pulp.1*2 Subsequent studies by Clemmer,3 Cooke and Digre,4 Cooke,5 Schuhmann and Prakash,6 and Cooke, Iwasaki, and Choi,7-8 showed that flotation depended strongly upon the alkalinity of the flotation pulp, the concentration of the activating cations, and the chain length and structure of the organic collectors used. The concept of the electrical double layer has been applied to the case of the quartz-aqueous solution interface by Gaudin and Fuerstenau,9-10 and by de Bruyn 11 to explain the activation of quartz by multivalent metal cations. Studies of the surface of quartz by Gaudin and Fuerstenau9,10,12 and by Li " using the streaming potential technique contributed much information on the electro kinetic condition of the surface of quartz in the presence of various organic and inorganic ions. Measurement of adsorption of ac-

Jan 1, 1969

By M. F. COOLBAUGH

WHEN I was asked to speak on the subject of leaching, I did not realize that a complete summary of recent progress in leaching had been given by Stuart Croasdale. I shall try to give some other phases of the subject that were not touched by Mr. Croasdale. Not all metallurgists are in harmony as to their methods of treating metals. If they were it would probably mean lack of progress. They can be divided into two classes-the pyrometallurgists, using fire means, and the hydrometallurgists, or those using leaching methods. Conflict is always good for progress; we have it in politics, and in religion there are fundamentalists, and those who are not fundamentalists. As representing pyrometallurgy, may I hope not to be classed among the fundamentalists. The leaching of ores is not new. The leaching of ores for the recovery of metals, however, is quite new. The older leaching was simply to recover the salts. Agricola, back in 1555, I think it was, outlined a great many methods of leaching for the recovery of salts. They called them solid juices at that time. There was no real competition, however, between leaching meth-

Jan 1, 1926

YEAR OF ELECTION 1922. FEDERICO GIOLITTI Torino, Italy. 1917. HERBERT HOOVER Washington, D. C. 1941. DANIEL COWAN JACKLING San Francisco, Calif. 1939. HENRY KRUMB New York, N. Y. 1942. Essington Lewis Melbourne Vic., Australia 1921. C. McDERMID London, England. 1942. PAUL DYER MERICA New York, N. Y. 1913. EZEQUIEL ORDONEZ Mexico City, Mexico. 1938. A.M. PORTEVIN Paris France 1937. JOHN V.W. REYNDERS, New York, N. Y. 1937. GEORGE S. RICE Washington, D. C. 1911. ROBERT H. RICHARDS Cambridge, Mass. 1934. T.A. RICKARD Victoria, B.C., Canada

Jan 1, 1943

"Located on the Big Hole River, three miles from Divide, Montana, and 21.75 miles from Butte.Built in 1899.DAM: Rock-filled wooden crib, 512 ft. long and 57.5 feet high.SPILLWAY: Equipped with flash-boards 189 ft. long, 8 ft. 10 inches high.PENSTOCKS: Two 8 ft. diameter of steel, each branching and supplying two wheels.WHEELS: Four double horizontal, double discharge turbines, made by The James Leffel & Co., 1,000 h-p., 180 r. p. m., direct connected to generators, operating at 60 ft. head. GENERATORS: Four G. E., revolving field, 750 k-w., 180 r. p. m., 800 volt, 3 phase, 60 cycle alternators.EXCITERS: Two water-wheel driven exciters.TRANSFORMERS: 12 250-k-w. G. E. air blast, primary 15,000 volts, Secondary 800 volts.OPERATION: The plant operates essentially as a peak load plant. Except in flood period, there is insufficient water to operate at full load continually. In December its average output is about 500 k-w."

Jan 1, 1913

R. W. Raymond, New York City: From a study of Mr. Johnson's paper, I conclude that his apparatus is simple in construction and operation, and imitates in a revolving machine the movements of hand-shoveling. It does what a man would do in removing sand from the waste-water with a perforated shovel. I am sorry to say that I fear the present condition of the brown-ore mining industry in the East, as long as

Jan 1, 1899

(Members are urged to send in for this column any notes of interest concerning themselves or their fellow-members.) The following members registered at Institute headquarters during the month of April: J. C. Ralston, Spokane, Wash. E. P. Ross, Johnson City, Tenn. C. H. James, London, Eng. F. L. Garrison, Philadelphia, Pa. E. H. Benjamin, Oakland, Cal. A. Radcliffe, Copiapo, Chile. W. H. Shockley, Palo Alto, Cal. S. S. Wyer, Columbus, Ohio. A. C. Mauney, Salisbury, N. C. W. B. Kunhardt, Reading, Pa. A. W. Newberry, Los Angeles, Cal. W. E. Saunders, Philadelphia, Pa.

Jan 5, 1913

By D. Hartley

United States Steel Corp's. Minntac mine is located at Mt. Iron, Minn. on the Mesabi Iron range. The taconite pit is two miles wide, with a maximum depth of 170 ft. Millions of tons of crude ore, waste rock, and surface overburden are handled annually at the mine. All crude ore plus some of the lower-grade rock are rail-hauled; other materials are trucked. Length of rail haul averages 3.5 mi, with a lift of 140 ft. The maximum grade against the load is 1 ½ %. Nine 1200 hp diesel-electric locomotives handle trains of 40-and 50-cu yd side dump cars in crude ore and lower-grade rock service. In addition to this continuous operation, locomotives handle coarse tailings disposal and switching duties on an intermittent basis. All railroad equipment operates under the supervision of a mine control foreman through voice radio communication. The pit foreman also has this frequency available, quickly accommodating any changes in operation that may be required.

Jan 1, 1970

JOHN W. BELL (communication to the Secretary*).-I have to thank Mr. Merrill not only for his very kind remarks, but for the weight of his implied opinion that the work accomplished probably has an important practical aspect. I think there is a distinct although unuttered impression among engineers, that it will be time enough for them to begin to take an interest in the law of crushing when it emerges from the cloud of violent and even vituperative controversy that has hovered over it during the last 6 or 7 years. I have a very confident feeling that as the result of the work done by Mr. Gates, by me and by Messrs. Mitchell, Baily and Cockfield, who so loyally helped me to obtain the necessary data, at least the practical law of crushing has emerged; that it is ready and available for use by our fellow engineers, and that it will help them to unravel a number of the many practical problems they are con¬stantly confronted with. In regard to Mr. Gates' discussion, I would indeed like to believe that McGill could claim, as a minor achievement, the credit which Mr. Gates so generously bestows of having established the "law" of crushing. I think that more work would be required to establish this claim in the, strict sense of the word, as there is a fairly large gap between the coarse and fine crushing results. I am not worried about that gap, because the reason for it is quite clear to me; at the same time I-think it will be well to bridge it by a series of tests, and I am bound to admit that the testing machine is the most promising machine right at hand to work with, although whether the minute amounts of power required to crush small quantities of rock can be so accurately integrated as to insure high accuracy in the final result is still a question in my mind. If we had an Amsler-Laffon machine I would certainly try it. Mr. Gates' remarks about choke crushing are extremely interesting. He compels me to wonder, too. It is a new and probably a very important factor to be considered in this connection. I am in perfect accord with Mr. Gates about the desirability of the determination of crushing constants, because when this is accomplished the efficiencies (not relative mechanical, but real efficiencies) of different types of rock-crushing plants in any part of the world will then be comparable. For this reason it would, seem desirable that the American Institute Committee should not only consider ways and means for accom-

Jan 6, 1917

By V. S. Rood

Typical System of Workings THE general system of workings at the Utah-Apex is similar to that found in many of the western metalliferous mines. There is a vertical three-compartment shaft extending to the surface, from which the various levels have been driven to the orebodies. The 1000-ft. (305-m.) level, about ¾ mile long, was driven as a haulage and drain adit. Geology The formation is a flat north-dipping series of alternating limestone and quartzite beds. Extensive north-south faulting and-fissuring have taken place, resulting in the formation of large replacement orebodies in the crushed zones in the limestone. The orebodies are irregular in shape and size, but follow closely the trend of the mineralizing fissures. The ore consists of galena, pyrite, sphalerite and small values in silver and gold. Large masses of non-commercial pyrite are frequently found in or adjacent' to the orebodies, and more or less pyrite is found for some distance in the walls of the orebodies. Lenticular bodies of a black pyritic shale also occur in the zones where extensive faulting has taken place.

Jan 6, 1918

By S. Chander, D. W. Fuerstenau

Hallimond tube flotation, contact angle measurements, electrokinetics, and electrode potential measurements have been used to investigate the natural floatability of molybdenite. The effect of surface pretreatment and the role of hydrogen, hydroxyl, molybdate, and calcium ions on the flotation of molybdenite has been studied. The surface potential of molybdenite has been suggested to be controlled by HMoO[ ] and MoO4= surface species whose properties are strongly influenced by pH. Calcium ions, which appear to be specifically adsorbed, are able to reverse the zeta potential of molybdenite. The experimental results have been analyzed in terms of the Derjaguin model of wettability, namely in terms of van der Waals and electrical double layer interactions and hydration effects at interfaces.

Jan 1, 1973

STEPHEN TABER, Columbia, S. C. (communication to the Secretary?). -The fibrous salt crystals described by Dr. Branner are interesting, and I am glad that he has put this additional evidence on record. It confirms the results that I obtained in growing fibrous crystals in the laboratory. Much similar evidence of value to science in interpreting the laws of nature has doubtless been lost through failure to appreciate little things. Mr. Dresser points out that the boundary between chrysotile veins and massive serpentine is finely irregular 'when examined under the microscope. This fact I have observed in studying chrysotile veins and also, mode recently, in studying veins of fibrous calcite and fibrous gypsum. For the latter veins the statement holds true when the walls are of shale as well as when they are of the same material as the veins, but in no instance have I observed any evidence of replacement. The description of the vein walls given in my paper (pp. 1984 to 1985) was megascopic, not microscopic. The fact that chrysotile veins have sharply defined boundaries and are easily separated from the wall rock is evidenced by the small amount of waste adhering to the "crude asbestos" which has been shipped in such large quantities from some of the Canadian mines. Mr. Dresser has good ground for his statement that there seems to be no obvious reason why the term "mass fiber" should be restricted to anthophyllite. I have never examined the serpentine at the East Broughton mines; but in studying other serpentines under the microscope I have noted that much of the so-called "massive serpentine" is really finely fibrous (see pp. 1974 to 1975). The texture of such rock is, however, altogether different from that of mass-fiber anthophyllite, and I believe that the fibers have developed in a different way (see pp. 1981 and .1998). Mr. Graham raises certain objections on the ground that the laboratory production of fibrous crystals was limited to substances which go into solution with decrease in volume. Since my paper was written, however, I have succeeded in obtaining fibrous crystals of ammonium nitrate, a salt that dissolves with expansion in volume.

Jan 5, 1917

By W. J. Parton

D. R. MITCHELL*—The Chairman mentioned that we have had many papers on cleaning of fine coal and treatment of wash water solids. There are, of course, two reasons for that. One is that we have legislation, particularly in the east. that is making us go into these things whether we want to or not. It just so happens at the present time that I have four plants that are going up under my general direction, three new and one rehabilitation job, and in all of them, we have these problems. Therefore, I was very happy to be able to listen to these papers, because some of the things that are in them are going to help me solve some of the problems that I am facing. Of course, the second reason why we are concerned about fine coal recovery is the fact that coal has become a luxury item in a good many places, particularly in the anthracite region, so that we cannot afford to have it go to waste like we did in former years. There is a third minor reason, and that is that we are finding how to handle and use the extremely fine sizes that we did not know how to use in former years. Now, I have a couple of questions that I would like to ask. First, what are the maximum solids that you could have in a pulp going to one of these launder screens? I realize that it would be for anthracite. Second, of course the life of these screen surfaces is not very long— with brass or bronze, I believe it is a week, and with stainless steel, a month. Would it be possible to use screen surfaces like the Bixby-Zimmer round rod for the small sizes and possibly increase the life? Have you experimented with that? Another point that I would like to bring out, both in Mr. Parton's paper and in some of the others, in studying cyclones and any settling apparatus where we use orifices, the life of the orifices is very short, and that is a problem that still has to be solved. The capacity of the cyclone seems to be small, and if you have a bat-

Jan 1, 1950

By H. D. Outmans

Present first-order theory for frontal stability and viscous fingering of immiscible liquids is improved by including the nonlinear terms in the equations describing conditions at the interface of the liquids. This leads to the revision of several conclusions which were based on first-order theory. They concern the growth rate and changing shape of a sinusoidal disturbance, particularly in relation to the wave number of this disturbance. Nonlinear aspects of effective interfacial tension are discussed and it is shown that this tension is not simply a positive proportionality constant in a linear relation between pressure difference and curvature at the interface. Scaling requirements are determined from the dimensionless groups which govern fingering. Gravity and interfacial tension invalidate a previously formulated conclusion that the shape of a finger after a given displacement is independent of the displacement velocity. Also, similarity of fingering (and, hence, of sweep efficiency in case of an unstable front) requires geometrical similarity of the initial disturbance in the model and the reservoir with a scale factor which is the same as the one for scaling down the dimensions of the reservoir. INTRODUCTION The critical velocity at which the transition zone in the vertical displacement of immiscible liquids becomes unstable was calculated by ill. More recently, the same was done for nonvertical displacements and it was also shown that the stability is affected by an effective interfacial tension between the liquids. 2-4 Although in the oil reservoir a stable front is always desirable from a recovery point of view, the necessary velocity may have to be so low that the corresponding production rate is not economical. In that case, a knowledge of the fingering unstable front is necessary for predicting recovery at break- through. Studies in this direction have not gone beyond the very moment at which fingering first occurs.5,6 Conclusions about stability and fingering in these references are all based on linear theory. In this theory the nonlinear terms in the equations describing conditions at the front are neglected. The usual justification for this lack of mathematical rigor is that the nonlinear terms can be made small relative to the linear terms and, supposedly, small causes produce only small effects. It has been recognized, however, that this is not necessarily true in the nonlinear problems of hydrodynamics.7 The hydro-dynamic stability and fingering of the front between two liquids, accelerated in a direction normal to the front, for instance, is strongly influenced by the nonlinearity of the boundary conditions.8-10 Since these boundary conditions are not unlike those arising in the problem of stability and fingering of the front during a slow immiscible displacement in porous media, it was thought that there, too, the nonlinear terms should be taken into consideration. A summary of the results obtained in linear theory and a comparison with experimental data precede the nonlinear theory developed in this paper. This summary serves to introduce some quantities which will be used in the further develop ment. It should also be pointed out that the method of higher-order approximation by which the nonlinear stability problem is solved has application in other reservoir studies.11 SUMMARY OF LINEAR THEORY 1. A plane interface remains stable if its velocity is smaller than a critical velocity. vc = (p2-p1)gn/(l/A2- l/A1 .........(1.1) This equation is derived for uniform flow in a thin layer inclined to the horizontal plane. The displacement takes place in a direction normal to the intersection of this layer and the horizontal plane. The undisturbed (line) interface is normal to the velocity. Fluid 1, the upper fluid (gas), is displacing Fluid 2 (oil). (VcQS would be the injection rate in cc/

At Asarco's Mission mill. located near Sahuarita, Ariz., the 20 500-t/d (22,500-stpd) throughput of highly abrasive and corrosive copper ore can play havoc on equipment wear parts. To minimize frequent replacement work and extend life on key components, Asarco engineers have over the past five years utilized liners made of "Towniprene" in the secondary grinding and flotation area of the plant. Results to date have indicated that these liners last between three and five times longer than those made of metal or ordinary rubber.

Jan 8, 1978

By J. L. Huiatt, G. M. Potter, R. B. Tippin

The US Bureau of Mines and Great Salt Lake Minerals and Chemical Corp. have developed a froth flotation process for concentrating potassium salts from Great Salt Lake solar evaporites containing about 6% K2O. The crude evaporites, which were predominately halite (NaCl) with smaller amounts of kainite (KCl.MgS0, 2.7Hp0) and schoenite KeS0,MgS04.6H,0), were conditioned in a saturated brine solution., thus converting nonfloatable kainite to the floatable mineral schoenite. Schoenite was then selectively floated with a medium-molecular-weight fatty acid. Continuous small-scale pilot-plant testing indicated that 80% of the potassium could be recovered from the crude evaporites in flotation concentrates assaying about 13% K2O.

Jan 1, 1976

THE opening session* was held in the hall of the Franklin Institute, on Tuesday evening, June 20th, President Holley in the chair. The President introduced. Mr. Franklin B. Gowen, who addressed the Institute as follows MR. PRESIDENT AND GENTLEMEN : It has been made my pleasant duty to welcome you to the city of Philadelphia, but in so doing I shrink, with some natural reluctance, from appearing before an audience so much better fitted than I am to cope with the subjects which are usually presented to your association, and I can assure you that no trembling neophyte, first venturing within the groves of the Academy, or walking, with sacred reverence, in the gardens of Plato, felt more natural dread at the consequence of his own temerity than I do in appearing before an audience composed of gentlemen belonging to a scientific society of which I am but too sensible that until now I have been a member only in name. In olden times, upon entering a temple sacred to the worship of any deity, it was customary to lay some offering upon the altar, and, in following this custom, it will be my duty, before entering upon the more pleasant part of the task which is assigned me, to call your attention to a subject with which I have been somewhat familiar, and which is entirely within the scope of your investigations, in the belief that I may throw out some hints or some suggestions of a pro¬cess that may be fully developed by some of you, and eventually lead to the introduction of that which may be of service to the human race. The satirist who described the philosopher whom he met, as engaged in the process of extracting sunbeams from cucumbers, * A joint discussion of the subject of Technical Education, by the members of the American Society of Civil Engineers and the American Institute of Mining Engineers, was held in the hall of the Franklin Institute, on Monday evening, June 19th, and Tuesday morning, June 20th. This discussion has been printed in a separate pamphlet by both societies.

Jan 1, 1877

By Hannon, J. W. G.

Silicosis is today's most important industrial disease and probably dates back to the Stone Age. Since the industrial revolution, increasing attention has been paid to those occupations where mineral dust is present in the air breathed by the workers. For many years it was assumed that the inhalation of all mineral dusts was hazardous. but investigations conducted in several countries pointed the statistical finger of guilt at free silica in any of its numerous physical forms as a dust of outstanding toxicity. Recognition of silica as the chief hazard has resulted in widespread use of the term "silicosis." Depending upon the concentration of finely divided silica dust to which the individual is exposed and the duration of exposure, silicosis may become a disabling condition in from one to thirty years. The structure of the lung and respiratory passages is such that only minute particles of silica can gain entry to the air cells in the lung (5 microns or under are most toxic). When these minute particles gain entry to the lung tissues they stimulate certain protective cells in the lung to multiply at an excessive rate. The cell's undergo inflammatory changes which result in nodular scars and a low-grade inflammation of the lung tissue. These progressive changes in the lung structure gradually encroach

Jan 1, 1949