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By F P. Hao

Organo-sulphur-based collectors (eg xanthates, dithiocarbamates and dithiophosphates) are widely used in the flotation of sulphide minerals. Xanthates (ROC(=S)Sû), for example, adsorb strongly at sulphide mineral surfaces, in a reaction that is electrochemically coupled with the reduction of dissolved oxygen. One of the oxygen reduction products, hydrogen peroxide, reacts directly with dissolved xanthate, leading to its oxidative decomposition. Experimental work has been conducted, using ethyl xanthate, to understand the molecular mechanism by which hydrogen peroxide reacts with xanthates. A number of degradation products have been identified, some of which have not been reported previously. This oxidative decomposition reaction pathway is discussed in the broader context of xanthate decomposition in flotation systems. One of the identified ethyl xanthate decomposition products, ethyl perxanthate (ROC(=S)SOû), has been observed in the process water of a number of mineral processing operations. The interaction of this molecule with goethite (α-FeOOH) particles, typical of that found in tailings dams, has been studied in more detail using attenuated total reflectance (ATR)-FTIR. The ethyl perxanthate molecule has been found to coordinate to iron (FeIII) at the goethite surface, and undergo a surface-catalysed decomposition process. In the presence of both PbII and goethite, a ternary surface complex is formed, where ethyl perxanthate is coordinated directly to surface adsorbed PbII atoms. The results obtained give some insight into the environmental fate of ethyl xanthate in tailings streams, and a basis on which to consider the environmental importance of such species in tailings dams. Strategies for the destruction of residual xanthate levels in waste water streams are discussed in terms of the likely reaction products.

Jan 1, 2002

Comparison of Discretised Population Balance (DPB) and Finite Element Method (FEM) Methodologies for Modelling Batch Gibbsite Precipitation

Sep 13, 2010

By R H. Sibson

The gold province of Otago occupies an area of upwarped basement, the Otago Schist, comprising predominantly quartzofeldspathic and volcanogenic metasediments. This assemblage is the product of collisional tectonic deformation and associated metamorphism, mainly to lower greenschist facies, during the Rangitata Orogeny (200-100 Ma). Historically this region has produced 240 tonnes of gold, 4% (10 t.) of which was from the mining of Cretaceous goldquartz mineralised vein systems. Auriferous vein systems in the Otago Schist are mainly hosted within NW trending normal fault-fracture arrays, however NW trending reverse fault-hosted vein systems also occur. We propose that the Late Cretaceous-mid Tertiary Otago Schist structure represents a regional anticlinorium containing flexural folds of at least two wavelengths. The anticlinorium structure has been quantified by determining variations in angular discordance between schistosity and the Otago Peneplain, a Late Cretaceous-mid Tertiary erosion surface covering most of the Otago district. A structural model for the evolution of the post-collisional anticlinorium requires the cooling surficial zone (carapace) of a retrograding metamorphic belt to behave as an elastic lid. Erosion of topographic load on the carapace drove isostatic uplift, which was greatest in the tectonically thickened core of the orogen. In this way differential uplift produced flexural deformation in the elastic carapace, expressed as a large scale arching of the orogenic belt. Flexure created tangential longitudinal strains in the outer-arc, leading to extension and the formation of mineralised normal faults. These structures are separated by a neutral surface from shortening and associated mineralised reverse faults in the inner-arc. Our structural model predicts that the distribution of auriferous lodes should be localised about zones of maximum flexural curvature, where the tangential longitudinal strains are highest. As a result, NW-SE hinge regions separating schistosity dip domains in the Otago gold province may have new found significance as potential exploration targets.

Jan 1, 1995

By Giles C. N, Loughnan F. C

Bentonites and active earths from N.S.W., previously analysed with respect to occurrence, mineralogy and physical properties have been evaluated for use as bonding agents in quartzose moulding sands in terms of green properties and behaviour both with and without coal dust for iron castings poured at 1400°C.INTRODUCTIONIn the paper by Loughnan .and See (Part I) the occurrence, mineralogy and physical properties of the fuller's earth and bentonites of New South Wales were discussed and it was shown that some of the materials approached the quality of Wyoming bentonite. In the present paper the same samples from Marulan (Bl), Boggabri (B2), Wingen (B3), Muswellbrook (B6), Swansea (B8), Dubbo (89) and Trida (Bll) have been investigated with respect to their potential value as bonding agents in compounded moulding sands. Inaddition, the -20 micron fractions of the Boggabri (B2t) and Swansea (B8t,> were recovered and the former converted to a sodium clay, in order to assesE; the beneficiation possibilities. A sample of Wyoming bentonite (S2) also has been included for comparison.GREEN PROPERTIES OF THE ARTIFICIAL MOULDING SANDSA quartzose base sand (Botany Dune) previously oven pried and screened to 1·65 mm., was subjected to a sieve ana]ysis in accordance with standard A.F.A. practice to yield a calculated' fineness number of 45. All tests were carried out on mixtures of this sand with2t per cent clay, since such mixtures were found most suit...

Jan 1, 1959

The current drill-and-blast method of tunnelling is cyclic and, for this reason above all others, has a future application potential which is lower than that of continuous methods. There is scope for progress in several facets of today's drill-and-blast tunnelling. But even if each of its unit operations and the synthesis of these were to be optimised, this conventional method will, in the long term, fail to be a serious competitor for tunnelboring machines (TBMs), roadheaders and the like. If its role in tunnelling is not to decline at an increasing rate, drill-and-blast will need to be transformed into a continuous system. Boring and cutting machines consume considerable energy (and expenditure) in creating rock fragments which are smaller than those required by muck-handling equipment. In this respect, blasting is more efficient. Mechanical methods are also less versatile and flexible and, when planning proceeds on a basis of meagre or inadequate geological data, cannot be costed as accurately. Currently, research gains for TBMs and roadheaders are greater than those for conventional tunnelling. If (as is likely) the disadvantages of mechanical methods continue to be reduced at a greater rate, the swing away from drilling and blasting will gain momentum.

Jan 1, 1987

Frother-Depressant Interactions in Two and Three Phase Systems

Sep 13, 2010

Innovative and Resource-Preserving Washing Processes for Primary and Secondary Raw Materials

Sep 13, 2010

The pressure of low commodity prices forced the design process for the second lift of Northparkes E26 Mine to adopt a continuous improvement philosophy. The emphasis was to minimise capital expenditure while still maintaining the excellent low operating costs achieved on Lift 1. Although the first block cave lift at Northparkes is the most productive underground mine in the world and is held up as a benchmark for the use of technology in mining, areas for improvement were identified. Every area was critically assessed and investigated for the possible application of new techniques and technologies. Key learnings from the construction and production phases of Lift 1 were captured, documented and used as the starting point for the Lift 2 design. This paper shows how and why the design parameters initially used onLift 1 were changed to become the current E26 Lift 2 developmentproposal. The main differences between the two block caves arehighlighted. The alternative techniques and equipment that wereconsidered are also discussed. * Originally published in the Proceedings of MassMin 2000,published by The AusIMM.

Jan 1, 2001

By Y Zhuang, S La Brooy

The selection of the optimum process route for a new project has traditionally consisted of investigating existing options and ranking them in terms of cost, technical risk and environmental acceptability. With the current focus on sustainable development other factors now need to be considered. Life Cycle Assessment (LCA) of the process options can be used to extend the assessment in terms of their potential for earning renewable energy credits and in judging their ability to achieve greenhouse gas emission reductions. A rigorous life cycle assessment is demanding in terms of setting the baseline for comparisons and evaluating the elements that make up the emission profiles of the process options. However, a simplified LCA can provide a useful tool for comparing different process options. This approach can be combined with traditional assessment criteria to rank the options available to the project. GRD Minproc has been intimately involved in executing LCA calculations for different municipal waste treatment options. This paper applies a similar LCA methodology to investigate the greenhouse gas implications for different options for copper processing. The process options considered are:concentrator û sale of concentrate to smelter, concentrator û on-site mini smelter, and concentrator û leach SX/EW. The paper then goes on to consider the operating cost implications that could arise with the introduction of carbon taxes or carbon credits and how these might impact on the future choice of flowsheet.

Jan 1, 2002

By Amanatidis A

In this paper, the kinetics of iron precipitation as sodium jarosite from aqueous solution is investigated. The determination of the reaction mechanism is attempted based on the experimental data of iron removal as a function of time, without using the characteristics of the precipitate.Experiments at the temperature range from 50° to 95°C were carried out with initial conditions of iron concentration IQ g/L, sodium sulphate concentration 25.44 g/L, sulphuric acid concentration 3.68 g/L, pH = 1.5 and agitation rate 600 rpm. Temperature greatly and positively influences iron precipitation from the solution and this is accompanied by pH decrease. The activation energy was determined using the maximum values of the precipitation rate, which were evaluated by polynomial fitting of the sigmoidal shape experimental curves, and it was found to be 44.37 kcallmole. The determination of the rate-controll ing mechanism was based on some criteria used for the discrimination among the three probable mechanisms of precipitation (diffusion, mononuclear nucleation, polynuclear nucleation). These criteria utilise various funetions of the recovery 'a' of iron precipitated versus time, the most important of which are the chronomals. The results of the kinetic analysis procedure showed that the polynuclear nucleation growth mechanism controls the precipitation of iron as sodium jarosite. This was confirmed by the high value of activation energy, excluding diffusion as the controlling mechanism.

Jan 1, 1993

THE Company's smelting equipment consists of three blast furnaces, supplied with blast from two sets of vertical piston blowers, each capable of delivering 8000 cub. ft. of air per minute at a pressure of 60 oz. per sq. in. Each blower is belt-driven by a 1:30 h.p. motor. The maximum speed of the blowing engine is 35 r.p.m.No. 1, the largest of the three blast furnaces, has a crucible area of 49.5 sq. ft., and measures 11 ft. 6 in. x 5 ft. at the tuyeres.From tapping floor to feed floor measures 35 ft. 9 in., and holds, when full, 100 tons of charge. Blast enters through thirteen 3-m. tuyeres at 60-oz. pressure. Working normally, this furnace is capable of treating :300 tons of charge, exclusive of returned slag and coke, per 24: hours, with an output of 100 tons of lead. Tapped slag flows into a C.l. forehearth mounted on wheels, where any lead and matte is caught, and the slag overflows into a 3-ton cast-iron pot, in which it is drawn away by an electric locomotive and poured over the dump.

Jan 1, 1918

By Jones S. C

The problem of sealing a fluid serieite zone at a hole depth of 4000 ft was overcome by using a composite non-return valve plug and rod assembly which enabled cement to be forced under pressure into the zoneà

Jan 1, 1966

By P L. McCarthy

In an environment of accelerating capital costs, limited capital availability and strongly cyclic metal prices, there is a difference between a robust mining and processing operation and one that would maximise shareholder returns in an idealised world. A higher cut-off grade policy is likely to improve operating margins and may reduce the scale of operations and thus limit capital exposure. This will leave some metal in the ground, but it is marginal material which carries the greatest cost and risk exposures. Where do we draw the line?CITATION:McCarthy, P L, 2013. Is bigger better? Building market resilience into process plant design, in Proceedings MetPlant 2013 , pp 66-70 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 15, 2013

The granulites and related "dry" igneous rocks tend to be passed over during exploration for metals. Preliminary data show that high trace concentrations of Cu, Ni and other metals of economic interest are common in orthopyroxene and some of the other granulite minerals. During retrograde metamorphism of granulites, pyroxenes are converted to amphiboles or phyllosilicates, and significant quantities of metals are released and become available for incorporat- ion into new mineral phases, or may be transported elsewhere. S--rich scapolite is the normal scapolite of granulites. Its retrogression to secondary plagioclase provides much S which scavenges Cu, Ni, etc., from pyroxenes undergoing retrogression, thus producing ore-fluids. A full analysis of a scapolite with 5.10 per cent S03 is given. Beryl is unstable in granulites but the rare Be mineral taaffeite (Al4Pf (Be,Fe)O3) with 5,50 per cent BeO occurs in central Australia as a pale green Tabular mineral easily confused for chloritoid in hand-specimen. Metamorphic differentiation and mobilization of primary ore concentrations are major factors controlling their post-granulite attitude and grade.

Jan 1, 1969

Study on Basic Theory of the Grain Settlement in Fluidised Bed This paper takes thick goal grains (less than 1.5 cm) as research object. According to different densities and particle sizes, thick goal grains are divided into 20 kinds of narrow density and narrow size level average grains. Free settling and hindered settling tests are respectively carried out in ?100 fluidised bed thick goal separators. Hindered settlement includes hindered settling velocity test and measurements of suspension density. Results show follows. (1) Fluid state in separator belongs to transition region. Alien's law is the appropriate formula of thick coal particles free settlement terminal velocity. (2) The main factors affecting hindered settling velocity are the number of solid particles in medium and the structure feature of the particle group. The bigger volume fractions of solids ? is, the smaller decreasing velocity coefficient of particle hindered settlement ¯ becomes. In the organism from bottom to top, density of suspended particles in fluidised bed gradually decreases, but near the top of the suspended particles, the density increased slightly. With increase of density and size, suspension density reducing extent increases from bottom to top of separators.

Sep 13, 2010

By O Haavisto, N Khajehzadeh, L Koresaar

Online analysis of metal content can be used to optimise the grade and recovery of a flotation circuit. Compared to conventional laboratory analyses, the benefit of an online analyser is the speed of the measurement, therefore disturbances (eg changes in feed grade and decrease in recovery) can be reacted to in real time by an operator or automatic process control system. In some cases traditional X-ray fluorescence analysers can be applied to silica analysis in iron ore when the SiO2 grades are high enough and have a negative correlation with iron; however, generally a laser-induced breakdown spectroscopy (LIBS) analyser is more suitable for low Z elements.The Outotec Courier 8® analyser is a LIBS based analyser able to measure elements starting from lithium (Z = 3), thus being able to measure impurities; eg silica and aluminium directly in iron ore slurries. Besides online elemental analysis, the analyser can be combined with optical measurements for rapid continuous measurement of each sample line. Laboratory testing has also shown potential for mineralogical analysis using the combination of LIBS and reflectance spectroscopy.CITATION:Koresaar, L, Khajehzadeh, N, Haavisto, O and Timperi, J, 2017. Online elemental and mineral measurement of slurries in iron ore beneficiation, in Proceedings Iron Ore 2017, pp 561–566 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By A Vickerfält, J Huss, J Martinsson

The European Union has listed vanadium (V) as one of the critical raw materials for the transition to a future green society, as stated in the Critical Raw Material Act, written by Grohol and Veeh (2023). In the steelmaking industry based on V-containing iron ore, V is a possible by-product from the slag. A requirement for slags to be suitable for V extraction is a V content preferably above 8 wt per cent as V2O3 and a phosphorus (P) content below 0.1 wt per cent as P2O5. Hence, it is important to keep V in the slag phase while the P is moved to the metal phase during the steelmaking process.

Aug 21, 2024

Assessment of the Consistency Between Different Laboratory Froth Stability Measurements

Sep 13, 2010

It is now becoming mandatory in Australia to rehabilitate ponded fine grained coal mine tailings, which may well have been deposited initially with no consideration as to how or whether this could be done nor to the costsinvolved. Of prime importance to the rehabilitation of tailings ponds are the bearing capacity and deformation characteristics of the tailings. Since the tailings are fine grained, time effects will govern the self-weightdeformation of the tailings initially deposited as a slurry and the subsequent deformation of the deposit under the weight imposed by rehabilitation fill. The engineering properties of a particular deposit of ponded tailings havebeen investigated and its response to the placement of fill monitored and analysed.

Jan 1, 1987

Modelling and Simulation to Design a Flotation Circuit for Gold Concentration

Sep 13, 2010