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By Rankin W. J

Increasing concern with the emission of sulphur dioxide from smelters and roasters has caused renewed interest in processes which can use waste sulphur dioxide, such as the sulphation of nickel laterite ores. The process described here proposes to by-pass the production of sulphuric acid and react laterite directly with a sulphur dioxide containing atmosphere. A thermodynamic analysis identified operating windows in which nickel sulphate forms while iron oxide (the major impurity in most laterite ores) remains stable. The initial assumptions included unit activity of all species except nickel oxide. The lowest possible nickel oxide activity (while maintaining selectivity) increased with increasing temperature, indicating that selective sulphation is favoured by low temperatures. The temperature of interest was found to be between 500 and 800¦C. Calculations show that a feed gas containing ten per cent SO2, five per cent 02, balance N2 requires a temperature greater than 650¦C for selective sulphation of nickel. Laboratory experiments showed that the assumption of unit activity of ferric sulphate was unrealistic above about 680¦C due most likely to the formation of solid solutions which decreased the ferric sulphate activity. Results are presented which illustrate the limiting equilibrium sulphur trioxide partial pressures at 700 and 730¦C below which selective sulphation occurs. Cobalt extraction was usually between 80 and 95 per cent under conditions yielding selective sulphation, whilst nickel extraction was about 50 to 75 per cent depending on temperature and choice of upper limit of iron extraction. An operating diagram is presented for a limonite ore and shows that the optimum reaction conditions are 680¦C and an input gas containing 20 per cent SO2. Under these conditions nickel, cobalt and iron extractions are 73, 95 and two per cent respectively.

Jan 1, 1996

By Kinsella B

Titrimetric studies have been carried out on the activated carbons Kintal 1105, Norit 2520 and Kuraray 2GA. Titration curves of the carbons before and after acid and water washing and gold loading indicate that the acid-base properties of the carbons are affected by both the method of treatment and also by the loading of gold. It is considered that the pKa values of the functional groups on the carbon surface are in the regions of 11, 7 and 3 respectively.

Jan 1, 1984

By Bearman R. A

The majority of published material regarding the operation of crushing machinery is concerned with simulation of performance rather than design of equipment. The reason underlying the bias in published material relates to why research is carried out and who undertakes the research. Two distinct types of research can be identified: 1. Internal research by crusher manufacturers - generally related to mechanical design, value engineering and to the commercial realities attached to sales demands. Any work on basic crusher geometry or rock/machine interaction is of a sensitive nature and rarely enters the public domain. 2. Academic research - mostly confined to modelling of crusher performance and simulation. This is not because of any bias, but crusher design requires access to manufacturers data or at least an in-depth understanding of crusher design, which is rarely available. The crushing of rock is a complicated problem. It involves three aspects; the machine geometry, the material composition (type of rock/feed size distribution) and the machine/rock interaction. The machine geometry is often ignored in empirical mineral processing simulations, while the response of different feed materials is only nominally addressed in machine specifications provided by manufacturers. The manner by which the machine produces a stress field and causes different types of breakage for different rocks (or the machine/rock interaction) is sadly neglected by both groups. All three aspects must be considered collectively to successfully understand and model the entire crushing process. 1. Centre for Mining Technology and Equipment, Julius Kruttschnitt Mineral Research Centre, University of Queensland, Isles Road, Indooroopilly 4068 Qld. The importance of crushing is often underestimated. In mining and mineral processing the invisibility of the crushing process is understandable as it merely provides a coarse reduction stage prior to the intricacies of mineral extraction. However in the quarrying industry crushing and screening basically provide the finished product. A brief overview of the quarrying industry shows the importance of crushing. Figure 1 gives production figures for most of the western European countries, Australia and the USA.

Jan 1, 1995

By Alichurch P. D

Perseverance nickel deposit is located at latitude 27¦ 491S, longitude 1200 42'E, 330 km north of Kalgoorlie, Western Australia. Gossanous outcrops were discovered in April, 1971, and after further detailed surface investigations, percussion drilling led to diamond drilling by June, 1971. Up to December, 1972, 127 diamond holes totalling 45,590 m were drilled to indicate 33 million tonnes averaging 2.2% Ni using a 1% cut-off grade. The deposit occurs in a lenticular ultra- mafic unit emplaced in metasediments locally forming the eastern flank of the Archaean green- stone belt trending NNW from Leonora to Wiluna. To the east a major strike fault separates the metasediments from gneiss; westwards there is a sequence of metavolcanics with further ultra- mafic units. Length of the lens is 3500 m and it attains a maximum width of 800 In. The eastern contact is moderately regular, but the western contact is prominently embayed. Local strikes are NNW, and dips are steeply W. A set of strike faults cuts the ultramafics and enveloping quartzites. These are normal faults, parallel to the major eastern fault, dipping 65-70¦W. They impart a serrated pat- tern to the sub-outcrop of the western contact. Massive serpentinite is the dominant rock in

Jan 1, 1973

Since its commercial in Australia at Broken Hill in the early part of the 20th century, the flotation process has grown to become the single most important minerals separation method available to mineral processing engineers. Statistics on flotation are impressive both in terms of growth of tonnages treated and in terms of the variety of separations accomplished. Because of the steady decline in the grade of ores and because many of the ores remaining are finely disseminated mixtures of minerals (many of them in a highly oxidized state) mineral processing scientists and engineers are now con- fronted with the problem of improving and modifying conventional flotation techniques so as to be able to effic- iently process these more refractory types of-ores. The flotation process did not come into being as the result of an intensive fundamental research effort but, in a similar way to so many other methods used in the processing of raw materials, it was developed over the years by the continued application of empirical methods. As a result, most of the basic research in this field has long been concerned with the problem of explaining why the existing process works so well. We are now at the stage where any further substan- tial extension of the flotation process will demand a more profound understanding of its fundamental principles. Current knowledge of flotation fundamentals is still far from the stage where processes can be designed, optimized, and controlled from first principles. The extensive

Jan 1, 1984

The introduction of large diameter drill holes and mass firings in underground metalliferous mines has led to an increase in the number of reported sulfide dust explosions in Australia and overseas. Adaptation of the coal mining technique of using limestone to inhibit or prevent dust explosions has not been entirely successful as the development and inhibition of a sulfide dust explosion is somewhat different from that of a coal dust explosion. Tests were carried out on two pyritic ore samples, sulfur contents of 41 and 36 per cent, in 8 and 20 litre explosion chambers to evaluate the effect of the addition of limestone on the maximum explosive pressures developed and rates of pressure rise. Significant values were obtained in both chambers with dusts containing 60 per cent ore and 40 per cent limestone. The percentages of limestone required to inhibit the pyritic dusts were considerably higher than those values generally accepted by the mining industry and the current methods used to inhibit sulfide dust explosions should be re-evaluated.

Jan 1, 1986

By Christie AB, Bull VH

The geological environments of gold deposits are reviewed in relation to the strong resurgence in exploration for gold since 1979. The resurgence is due mainly to New Zealand's geological endowment with gold and its history as a gold producer. Major past production was from Cenozoic placers of Otago and Westland, late Cenozoic epithermal deposits of the Hauraki Goldfield, and the respective Paleozoic and Mesozoic lode deposits of the Reefton and Otago Goldfields. These same geological environments are the targets of current exploration, mainly in extensions of previously mined deposits. On the Westland and Otago Goldfields alluvial and fluvioglacial gravel placers, mainly representing lateral and depth extensions of previously worked ground, are being mined and prospected. Gold production in 1984 was exclusively from these deposits, and the development of mobile concentration plants has resulted in a great increase in mining activity. Mineralised zones adjacent to previously mined lodes in the Hauraki Goldfield, Reefton Goldfield, and at Macraes Flat (Otago Goldfield) are being intensively explored. At Waihi (Hauraki), an open-pittable resource of about 10 million tonnes of ore has recently been delineated. Some new deposit types and little explored environments are also receiving attention. They include: gold-sulphide quartz veins hosted in an alkaline granite dike in west Nelson; hot spring type gold deposits in fossil geothermal (epithermal) systems of Northland, the Hauraki Goldfield and the Taupo Volcanic Zone; and marine placers off the West Coast where an area of auriferous gravels has been outlined near Hokitika. There is potential in known deposits and prospects currently being evaluated for a large increase in gold production by the early 1990s.

Jan 1, 1986

By Hutchings SG, Skimmings T

This paper describes the results of the field application tests at Miike Colliery on the integrated automatization of the longwall mining system for medium thick coal seam. The purpose of the research is to develop an automatic longwall mining system which can be controlled accurately from outside of the face, and the ultimate goal is an eliminate of men from the face. Presently, the field test is being conducted in Yotsuyama mine following to a success in the performance test on surface. Remote Batch Control System for shield supports has been adapted to operate all supports from the control panel located at the entrance of the face. Remote monitoring and control system of the drum shearer has also been tested. The system makes it possible to operate the shearer either at the main gate or full automatic. Productivity and safety will be substantially improved as those systems enable to eliminate all workers from the face under the severe working conditions with high ground pressure and hot and humid atmosphere due to increasing mining depth. So far, we have been satisfied with the results of the field test and those system will be an effective countermeasure to operate the face with a high risk of rock-burst.

Jan 1, 1987

By G J. Corbett

Magmatic-related low sulfidation hydrothermal ore systems at plate margins exhibit distinct spatial and temporal zonations which can be used to aid mineral exploration and development. Low sulphidation systems at all crustal levels exhibit the same paragenetic sequence of events: early breccia formation, followed by quartz - secondary feldspar sericite/illite veining, then mineralisation, and final argillic overprint. This sequence of events is interpreted to reflect the initial emplacement of melts at high crustal levels, and the progressive cooling of that melt and release of magmatic constituents into a circulating hydrothermal system.   Low sulphidation systems in the south-west Pacific region exhibit a vertical zonation in deposit types: from porphyry copper-gold at deep levels, quartz-sulfide-gold at mesothermal to deep epithermal levels, carbonate-base metal gold at mainly epithermal levels, and epithermal quartz silver-gold at shallow levels. It is interpreted that the characteristics of each of these styles of deposits is produced by mixing with circulating waters of different physio-chemical compositions.

Jan 1, 1995

By Bawden WF, Paynter JT

This investigation involves laboratory testing and stability analysis of paste fill at the Golden Giant Mine. Site-cast samples are tested in unconfined, confined, and consolidated-undrained triaxial compression. Pore pressures during shear and consolidation characteristics are measured to determine both drained and undrained shear strength parameters and assess the potential for undrained loading. Liquefaction potential is also considered. A limit equilibrium solution is used to obtain factors of safety against failure of the fill during mining of adjacent stopcs

Jan 1, 1998

The Mt Whaleback open cut mine South Wall is, in part, developed as an unbenched dip slope. The remainder of the rock slope consists of asymetrical overturned folds which have been locally truncated by major low angle faults. The Mt Whaleback orebody is structurally controlled and therefore extensive structural geology input has gone into the final rock slope design. The design is based on normalised 40 m geological cross sections, but the inherent complexity of the geological structure of the orebody yields a high degree of uncertainty within that interval. There- fore, the final slope bench face and the penultimate bench faces are mapped in detail to accurately establish the geological contacts and struc- ture. The knowledge of accurate geology of final and penultimate faces plays a very important role in the design of controlled perimeter blast- ing. Accurate geology is established mainly by face mapping, and by hole geological evaluation of blastholes to locally refine the current Geologi- cal model.

Jan 1, 1989

THE auriferous sulphide ores of the eastern end of Gippsland, and notably of the Cassilis and lVIitta districts, are amongst the most complex and refractory in Victoria-perhaps in Australia. The minerals occurring in these ores are pyrite, arseno-pyrite, zincblende, galena, and (in smaller amounts) some of the copper, sulphides, as chalcopyrite and covellite; and some of the antimonial minerals, notably stibnite and jamiesonite. In the oxidized portions of the lodes, the oxidized lead and iron minerals, and small amounts of the hydrated arseriiate of iron, are found.In the Cassilis mine, near Omeo, copper is present usually in quantities of under 1 %. The magnetic sulphide of iron is of fairly common occurrence. In, the upper levels of the Cassilis mine tin was usually present, the amount going up to 3% in some samples of concentrates. These minerals occur sometimes banded, but usually as an intimate mixture-pyrite and arseno-pyrite predominating. The gangue is usually quartz (blackened by enclosed particles of sulphides). Calcite, magnesium silicate and felspar are also present in varying amounts.

Jan 1, 1911

By Harrison AT, Smart RM

Backfill systems using unconventional cementitious hinders have been successfully used in relatively deep and hard rock tabular mines for longwall, scattered stoping and shaft pillar removals. Two unconventional cementitious systems are discussed: 1. A ground granulated blast furnace slag (GGBS) with an activator containing lime. This has been used with a total tailings 'stable' slurry at a relatively low dosage of less than seven per cent, by mass, based on dry solids. The room and pillar stopes supported with this fill were up to 20 in high and the tailings were relatively high in pyrite. .\ GGBS binder plus a silicate based activator and gelling agent that virtually eliminated all water drainage (and hence post filling shnnkage). The system used a slurry, but the addition of the ;iutivator created a final placed product that had the behaviour of a paste. The system has been successfully used for almost ten years in the following applications: ò sloping widths (mining heights) above 1.6 in; and ò shaft pillar removals in seismically active areas at the end of the life of the shafts. \This paper discusses the technical merits and costs of the systems and compares them to other fill systems (including true paste systems).

Jan 1, 1998

Developed and built in 1982 for simultaneous bathy-metric and reflectivity mapping of the deep ocean by the Hawaii Institute of Geophysics, SeaMARC II was a breakthrough in sea-floor mapping technology. The design was developed cooperatively by industry and academia, and the system has served as a prototype for a new generation of mapping tools for operation in both shallow and deep water.Research programs using the SeaMARC II system have focussed on basic research into the geophysical evo-lution of the Pacific, ranging from intra-atoll mapping to surveys of the deep-sea trenches. During the past few years most work has been concentrated on detailed investigations of the morphology of mid-ocean spread-ing centers, seamounts, and the subduction zones which surround the Pacific. The detail provided by the high resolution, 10-km wide side-scan sonar images of fault and fold structures, combined with the swath of bathy-metric information obtained simultaneously, allow previ-ously unattainable analysis of seafloor morphology and are leading to development of detailed models for ocean crust genesis and deformation.

Jan 1, 1990

Traditionally, the Lead Lode at Broken Hill has been represented on presentation plans, cross sections and diagrams in scientific papers as a solid black mass, around which the more 'interesting' and 'structurally useful', wall rocks appear to wrap. Structural analysis of the Broken Hill orebodies has usually turned to these wall rocks to determine the structural history of the mineralisation.This tendency to represent the orebody as a massive single entity is incorrect and the aim of this paper is to illustrate that sulphide orebodies (in this case Lead Lode), are a dynamic part of the mine stratigraphy. They can preserve a great deal of useful structural information that can be recorded with detailed internal mapping.Three main categories of ore type are recognised in Lead Lode; Stratiform ores, Mobilised ores and Metasomatically altered ore. The ore types in these categories occupy or have formed in distinct structural and stratigraphic positions and have clearly recognisable inter-relationships.

Jan 1, 1993

By Barnes R. G, Agostini A, Lewis P. C

The Mineral Resources Audit is a five-year Program established to produce a comprehensive and objective assessment of the mineral resources of New South Wales, including prospective resources. The goals of the Program are to improve planning and land use decision-making; attract exploration and minerals related investment; help the Department to identify and fill gaps in knowledge; and develop methods to identify and quantify resource potential and prospectivity. To achieve the goals of the Audit it is necessary to assemble and enhance a large amount of information and it is necessary to spatially analyse this information using computer-based Geographic Information Systems (GIS) which allow the collection, storage, transformation and display of large quantities of spatial data. An extensive range of both map-based and textual data can be employed in spatial analysis and resources and geoscience modelling. In order to use this information, data sets have to be corrected and standardised. Many data sets need to be classified. An objective of the Audit Program is the spatial analysis of the State, region-by-region, and the release of cleaned-up multiple digital data sets as packages which include upgraded mineral deposit information, 'seamless' geological map layers showing lithology, structures and stratigraphy, and processed and classified geophysical map layers. These regional packages are important reference sets for the mineral resources industry and will assist delineation of regional exploration targets.

Jan 1, 1995

This paper describes the principle of cut-and-break rock excavation, in which rock is first undercut, and the undercut material is subsequently broken free by a wedging action. The current work on cut-and-break using the large rock cutting test rig at the Centre for Mining Technology and Equipment (CMTE) is outlined, and suggestions are made as to the potential advantages of cut-and-break roadheading, particularly in excavating short tunnels in hard rock in an urban environment.

Jan 1, 1993

Limnological processes are often overlooked when trying to assess the long-term water quality of pit lakes. It is essential to deal with these aspects, since they determine the geochemical and redox conditions around the submerged reactive rocks. Underground mining at East Sullivan (northwestern Quebec, Canada) stopped in 1966. Two adjacent stopes, 91 and 106 m deep, were left open to the surface, with roughly circular apertures of about 7700 and 18 000 m2. Water filling of the two glory holes went on over three decades and overflow began in 1999. Surface water pHs values were near neutrality as late as 1994 (6.3 - 7.0) but had become acidic by 1999 (2.6 - 3.5). Limnological processes were investigated in late-1999 and early-2000, with temperature measurements at 1 m intervals and sampling of the water columns before and after the late fall density inversions. A strong chemocline-thermocline was observed at 15 m. Above the chemocline, the water had low pH (3.2), no alkalinity, and low Na, Ca and sulfate. Below the chemocline, the concentrations of these parameters and the pH increased, with pH at 5.5 - 6. Consistent with the low pH values present in the upper 15 m, the concentrations of Al, Cd, Cu, and Zn were high near surface, and decreased below the chemocline. Dissolved oxygen concentrations as well as Eh decreased with increasing depth. Alkalinity integrated over the entire water column below the chemocline was at least six times larger than the acidity inferred from Fe2+ and Fe3+ concentrations. The temperature survey showed that seasonal density inversions do occur in the water column. The inversions do not involve the entire water body, since the surface to depth ratio is too small for a complete overturn. Oxygen from surface waters is carried to the bottom where it oxidises sulfides, until its depletion. Residual Fe2+, stable under anoxic conditions, is displaced upward by the next dense water incursion. It eventually reaches the thermocline, but only after many successive incursions. There, its oxidation to Fe3+ allows hydrolysis, which consumes dissolved and wall-rock alkalinity. It is only in 1999 that alkalinity was finally exhausted and that the pH shifts to acid values. The low pHs in the surface waters allow a build up of Fe3+ and Al3+, and desorption of metals from colloids. Buffering is assumed to be controlled by wall-rock oxyhydroxides in surface waters, and by carbonate minerals in the bottom waters. Because the seasonal overturns are far from being complete, the large amounts of alkalinity acquired from the wall-rock in the bottom waters cannot balance the acidity of near surface waters. Hence the surface water is acidic.

Jan 1, 2003

By Totterdell JM

The Permian-Triassic Bowen Basin and the Jurassic-Cretaceous Surat Basin evolved in a backarc tectonic setting behind an active convergent plate margin in eastern Gondwana. Several extensional (Early Permian; Eocene) and contractional (mid- Permian; Early Triassic; Middle-Late Triassic; early Late Cretaceous) intraplate deformational events are recognised in the basins. These can be correlated with similar events in the New England Orogen that was being deformed in the Late Permian- Late Triassic as a foreland thrust belt. The intraplate deformations were probably the consequence of plate interactions, including the accretion of terranes, at the ancient active plate margin, remnants of which now occur in New Zealand.

Jan 1, 1995

Every text book for blasting in Japan says that Hauser's law can be applied for practice. But recently it came true that there was no historical record about him and no actual datum of his own or other's to testify. According to his theory, the funnel ratio N = r/W in crater test is inversely proportional to the rock strength and proportional to the explosive amount: where r is the radius of crater and W is the burden. But experiment showed the opposite result, and revealed new information. Two kinds of experiment, crater test and boulder blasting of mortar, were carried out to investigate the effects of rock properties on blasting. The material used for test 1 and test 2 was a mortar block (60cm)3 cube, 4 vertical faces of which were used for crater test. The results from Test 1 and test 2 were summarized as follows. The funnel ratio ranges between 2.5 to 4.5 in proportion to rock strength and burden. The standard ratio of 1, reported by Hauser, was not observed in any instances. It was also noted that the funnel ratio is independent of the explosive amount. The material used for boulder blasting, test 3, was a mortar block (40cm)3 cube, in the middle of which was located a vertical borehole for the explosive charge. The results of test 3 were as follows. The necessary explosive amount for boulder blasting is in inverse proportion to the mortar strength. Fragmentation and throw are proportional to the mortar strength.

Jan 1, 1990