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By B Levasseur, C Olsen, E Ghasemian Langeroudi, F Larachi, F Safizadeh, C Gagnon

Gold recovery by the cyanidation process is often accompanied by the leaching of other species. This leads to the depletion of the level of free cyanide and oxygen available for gold cyanidation. The largest proportion of the consumed cyanide is diverted by the cyanicides (eg S, Cu, Zn, Fe, etc) into non-valuable complexes.COREMÆs Extractive Metallurgy team has been conducting a research program on the improvement of the gold cyanidation process. As a part of this program, the current study aims to investigate the effect of certain operating parameters on the reactions involved during preoxidation and cyanidation. Flotation tailings and single mineral samples such as pyrite, sphalerite and chalcopyrite, along with their different combinations, were analysed to highlight the influence of ore mineralogy on the operating conditions. The effects of different kinds of oxidants (oxygen, hydrogen peroxide, ferricyanide and ozone) and chemical additives (ammonium sulfate) were investigated.Experiments conducted in alkaline solutions reveal that mineralogy is a key parameter since pyrite, chalcopyrite and sphalerite react quite differently during preoxidation and cyanidation. A significant increase in sulfur dissolution, especially on pyrite, was observed by applying preoxidation. H2O2 preoxidation showed a positive effect on increasing sulfate formation, a desirable by-product from the cyanide consumption point of view. Preoxidation of synthetic ores with ferricyanide resulted in boosting thiosulfate formation. Tests conducted on flotation tailings from a polymetallic mine revealed that a short preoxidation increases the dissolution of the ore leading to higher gold recovery and lower cyanide consumption. Regarding the formation of thiocyanate, the most undesirable by-product of the cyanidation, ferricyanide and ozone were found particularly efficient to hinder their formation. Finally, the addition of ammonium sulfate during the cyanidation process showed some promising results in terms of both gold dissolution and cyanide consumption.CITATION:Ghasemian Langeroudi, E, Levasseur, B, Safizadeh, F, Olsen, C, Larachi, F and Gagnon, C, 2013. Optimisation of operating parameters for cyanidation of sulfide-bearing gold flotation tailings in order to prevent the impact of cyanicides, in Proceedings World Gold 2013 , pp 111-120 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

Mining operations in the Obuasi mine of AngloGold Ashanti Limited began in 1897 using mainly gravity concentration and amalgamation to recover the gold from predominantly high-grade quartz ores. The mine is primarily an underground operation, although some surface mining still takes place. Ore is currently processed by two main treatment plants: the Sulfide Treatment Plant (STP) for underground ore and the tailings treatment plant for tailings reclamation operations. STP was commissioned in February 1994 to treat 180 000 t/m of double refractory gold ore and it hosted the then world's largest commercial scale bacterial oxidation plant which uses Gencor's BIOX« technology. Gold is recovered by gravity and flotation, with the regrinding of the sulfide concentrate before bio-oxidation to liberate locked gold in sulfi de minerals. The BIOX« product is leached using the carbon in leach (CIL) process. Gravity gold recovery is a major component of STP operations and its contribution to overall plant recovery is about ten to 13 per cent. Gravity recovery has undergone series of technological upgrading, since the very first circuit which consisted of a Knelson concentrator and a Gemeni shaking table which was incorporated into the milling circuit at the start of the plant. Presently, each of the gravity circuits which consists of Knelson concentrator(s), cyclones and Gekko InLine Reactors (ILR), are located at the Milling and BIOX« circuits. More recently a new gravity recovery facility comprising of four 48 inch Knelson concentrators and cluster of ten inch cyclones have been incorporated at the tail of the flotation circuit. An additional ILR will be commissioned in 2010 to treat the concentrate generated from the new Semi Autogenous Mill #2 (SAG 2) Knelson: concentrator tower under construction. Since the inception of STP, significant gravity recoverable gold has been recovered via Knelson concentrators and the employed circuits have seen a number of modifications and upgrades, motivated by ore mineralogical changes and recovery concerns. The pioneering adoption of the ILR technology in 2001 and 2003 was a critical factor in enhancing the improved recovery benefit of the gravity circuits. Therefore the objective of this paper is to highlight the mine's experience in the gravity recoverable gold process with emphasis on plant modifications and gravity equipment upgrade. Operational challenges and the contribution of gravity gold to overall plant recovery are also discussed.

Aug 1, 2010

By A Winchester, D Grant

The massive 1100 Orebody in Mount IsaÆs X41 Copper Mine has been extracted over the last 40 years form north to south utilising sublevel open stoping methods.De velopment has continually stepped ahead of production to provide access to new primary stoping blocks. The remaining secondary pillars contain stopes with one, two or three fill mass exposures and were constrained by access requirements and stope extraction turnaround time.The remaining southern mining areas consist of large 40 m wide by 300 to 400 m long east-west transverse pillars that have been left to provide access for ventilation and service requirements. Three large transverse cross-cuts or transverse pillars û 4180 x/c, 4010 x/c and the Panel pillar now remain. The 4180 x/c was the last major transverse pillar to be successfully broken.This transverse pillar is being extracted in a retreating sequence, creating 3SLOS stopes due to the surrounding backfilled stopes.In recent years the extraction of the first, and most critical, stopes in the transverse pillars have resulted in large changes to the induced stress field. This paper describes the extraction of the 1.1 million tonne stope P418 in the 4180 x/c pillar.T echnical challenges that were faced and how they were overcome to allow for the successful extraction of the stope are described.Critical to the success of the P418 stope extraction were the rehabilitation methodology used; extraction strategy modifications to address deteriorating ground; mass firings with multiple directional changes; managing the exposure of backfill of variable strengths; and geotechnical monitoring prior to, during and after extraction.

Jan 1, 2005

By P K. Seccombe

The McKinnons gold deposit is hosted by weakly deformed, Palaeozoic metasedimentary rocks of the Cobar Basin in the western Lachlan Fold Belt of New South Wales. Mineralisation comprised a largely supergene resource of 1.7 Mt of ore, grading 1.7 g/t gold, established over structurally controlled, primary gold and base-metal mineralisation in underlying, carbonate-rich meta-siltstones and sandstones of Early Devonian age. Mineralisation was associated with at least two major fluid cycles. The first cycle was characterised by four stages of vein formation. Early quartz and carbonate veins (Stages 1 and 2) and quartz-pyrite breccias (Stage-3) occurred prior to, or early in, the main regional deformation (D1). Continued D1 deformation produced syntectonic, carbonate-base-metal veins (Stage-4), primarily in dilatant zones adjacent to fold axes. The second cycle of mineralisation was an epithermal-style event, driven by a shallow, syn-D2 or post-tectonic intrusion, defined by aeromagnetic imaging. The intrusion may have exploited a jog, controlled along the basin margin by basement faults. Mineralisation produced gold-pyrite veins, associated with pervasive quartz-sericite-adularia and chlorite-sericite alteration. Highest primary gold grades are confined to quartz-adularia boiling zones. The McKinnons deposit offers an important example of mineralisation formed by multiple processes. Early-stage, base-metal mineralisation at McKinnons reflects structurally focussed, basin dewatering and metamorphic processes, typical of other deposits in the Cobar Basin. By contrast, late-stage gold mineralisation at McKinnons is magmatically driven and of epithermal style. Recognition of overprinting distinctive geological events is critical, not only in modelling ore formation, but in developing a versatile exploration concept.

Jan 1, 1999

After a short presentation of the Division of Mining at the Royal Insti- tute of Technology, Stockholm, Sweden, the author presents some of-the fill research carried out at the Division. Literature surveys and testing methods and equipment are described. The use of flocculants' in hydraulic filling has been tested both in laboratory and in mines and the results are very promi- sing. Finally compressibility investi- gations and some finite element calcu- lations are presented.

Jan 1, 1973

By R Dimitrakopoulos, K Kawahata, L Montiel

A method that optimises mining complexes that are comprised of multiple processing destinations, open pits and underground operations is presented. Mining, blending, processing and transportation decision variables are simultaneously optimised while accounting for geological uncertainty. The method uses a simulated annealing algorithm at different decision levels to generate a stochastic-based extraction sequence and processing policies. A case study shows its ability to generate a higher net present value while facing a reduced amount of risk when compared to traditional optimisation methods.CITATION:Montiel, L, Dimitrakopoulos, R and Kawahata, K, 2014. Globally optimising open pit and underground mining operations under geological uncertainty, in Proceedings Orebody Modelling and Strategic Mine Planning Symposium 2014, pp 201–212 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 24, 2014

By M McGrory, A Rodolfo, J Paredes, L E. Manguba, K A Villaspir, G Webb, R Setiagani, H Cardenas

"OceanaGold’s Didipio operation has been in operation for three years. Integral to the flow sheet design is a flash flotation circuit treating a portion of cyclone underflow, consisting of an Outotec SK-500 flash rougher and an Outotec TC10 flash cleaner and a SB-2500 falcon treating flash rougher concentrate to recover fine free gold.Flash copper recovery has been holding steady at 60 per cent, while flash gold recovery at 50 per cent. Gold recovery from the gravity circuit is 22 per cent, bringing the overall flash plus gravity gold recovery to 72 per cent.Operation of the flash rougher is mainly by pulp level control. Control of copper grade in the flash cleaner is mainly controlled by air inflow and flash cleaner pulp level control drives copper recovery. Gold recovery around the circuit is mainly driven by gold head grade.SB-2500 concentrate is scalped with a 250 micron screen with the coarse fraction reporting to a SB-250 falcon, concentrate of which combines with the screen fine fraction to a Gemini table.Citation:Cardenas, H, McGrory, M, Webb, G, Paredes, J, Setiagani, R, Villaspir, K A, Manguba, L E and Rodolfo, A, 2016. Didipio Flash Flotation and Gravity Recovery Circuit, in Proceedings 13th AusIMM Mill Operators’ Conference 2016, pp 123–126 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Oct 10, 2016

By C Parihar, R Garg, A Bhandari, S Bhandari

Blasting can impact the efficiency of entire downstream mining operation. Individual technology solutions for blasting have been available in the industry for many years but all of them only cater for certain aspects of blasting. Many of them are based on individual research and/or experiences. Some of the available software solutions are not suitable to be used in the field as that they need advanced skills or tools. Also, most do not take technology advancements like mobility, advanced data analytics, web solutions and integration into consideration. Hence, no technology platform is currently present in the industry that addresses all potential needs a blaster may need in an integrated manner.This paper presents an integrated solution that takes care of all aspects of blasting – design blasts according to mine plan; collect data after drilling has been carried out (as there is often difference in designed and actual drilled hole locations in the field); predict blast results in terms of fragmentation, flyrock, ground and air vibrations, wave front reinforcement and flyrock distance; and after assessment, allows changes in charging, delay timing and sequence. The technology solution is a secure, cloud-hosted, web-based software-as-a-service solution that can be accessed from anywhere. Also it has a mobile app, which is available for both Android and iPhone/iPad. The mobile app is also integrated with the web-based solution using application programming interface calls to the central data repository.Case studies for two limestone mines are presented where this solution is being used in its initial format. This software platform enabled analysis of the outcome from a previous blast pattern and then subsequently allowed optimisation of blasting operations based on historical data. Uses of this platform have resulted in improved key performance indicators in these two limestone mines. The mobile app as part of this platform enables extensive field blast data capture and analysis and also various predictions before a blast. Data collected include blast parameters, individual hole charging, initiation pattern, videos, photographs and vibration records for analysis/reporting. The key features of the solution are a blast designer, a detailed blast data collection/analysis and a series of environmental predictors. These predictors give blast results in terms of fragmentation, flyrock, ground and air vibrations and wave front reinforcement and take remedial steps before blasting to optimise and control adverse environmental impact. Many features, such as fragmentation predictor and mobility solution, are completely unique features that are not available elsewhere in such a field personnel-friendly manner.CITATION:Bhandari, S, Parihar, C, Garg, R and Bhandari, A, 2015. An integrated technology solution for optimised and environmentally-controlled blasts, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 393–400 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By T J. Callaghan

The Avebury nickel mine in Western Tasmania is a disseminated nickel sulfide deposit hosted in intensely metasomatised Cambrian ultramafic resulting from later Devonian granite related hydrothermal activity.Variable metasomatism of the ultramafic has formed two distinct gangue mineral assemblages. Less metasomatised ultramafic is comprised of fine grained black antigorite with minor disseminated chromite, magnetite and pentlandite. Intensely metasomatised ultramafic is altered to a pale grey or green, coarsely crystalline tremolite/actinolite and diopside assemblage with minor magnetite, chromite and sulfides. Both gangue mineral assemblages are frequently intermixed in ore grade mineralisation.The bimodal gangue of either serpentinite or metasomatised ultramafic presents challenges to drilling, mining, resource estimation and mineral processing as they possess very different physical properties. Mineralised serpentinite has a mean bulk density of 2.8 g/cc and the ultramafic skarn a mean bulk density of 3.2 g/cc. Physically, the ultramafic skarn is hard to break percussively creating difficulties in the crushing circuit and reducing mine development rates. However, it is non-abrasive and grinds readily, resulting in increased diamond drilling rates and increased mill throughput. Conversely the serpentinite gangue is softer and breaks easily resulting in accelerated development rates and crushing circuit throughput. However, its fibrous nature reduces grinding efficiency, increasing bond work indices and reducing diamond drilling rates.Predicting the ratio of serpentinised to metasomatised ultramafic is possible through use of the resource blockmodel, assisting mine scheduling, predicting mill throughput rates, energy consumption and grade control drilling rates.CITATION:Callaghan, T J, 2017. Challenges of bi-modal gangue mineralogy in mining geology, in Proceedings Tenth International Mining Geology Conference 2017, pp 23–26 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 20, 2017

By M D. Taylor, G Duclaux, K Atkinson, L A. Fisher, A R. Latham, M F. Gazley, S J. de Beer, C M. Tutt

Geological logging by mine and exploration geologists involves the application of a logging code that requires a geologist to make a subjective decision to classify a particular rock unit. This will most likely result in inconsistencies in logging that will be difficult to monitor or assess over time. A potential solution to this problem is to have an objective method to determine the true nature of a given rock unit. This can be achieved using portable X-ray fluorescence technology (pXRF), as large geochemical data sets can be collected rapidly and at low cost. Plutonic Gold Mine (Plutonic), Western Australia, has a growing data set of more than 150 000 pXRF multi-element analyses from core and underground face samples, reconciled to Au fire-assay concentration, and logging codes. This study investigates and statistically validates the consistency with which the logging codes have been applied at Plutonic for the last four years, with respect to both Au distribution and other elements. In doing so, we have developed a schema that allows objective logging to occur once core has been sent for assay and analysed by pXRF. While far from replacing the geologist in the field, this is a complementary method that adds significant value to a data set.CITATION:Gazley, M F, Tutt, C M, Latham, A R, Duclaux, G, Fisher, L A, Taylor, M D, de Beer, S J and Atkinson, K, 2013. Objective geological logging using geochemical multi-element data - Plutonic Gold Mine, Western Australia, in Proceedings World Gold 2013 , pp 455-462 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By Schaap W

A test on Taylor's rule of mine life using published data on open pit porphyry copper mines confirmed that mine life is, on average proportional to the fourth root of reserve tonnage. Deviations from this rule-of-thumb occur to a large extent as variations between regions that are qualitatively explained in terms of differences in grade, infrastructural needs or special taxation effects.

Jan 1, 1984

By J P. Jona, S R. Poulson, C H. Gammons

Spatial and temporal trends in water chemistry in the acidic (pH ~2.6) Berkeley Pit lake, Butte, Montana, can be explained by a newly developed iron-cycling model. Key elements of this model include: subaqueous oxidation of pyrite and other metal sulfide minerals by dissolved ferric iron, producing Fe2+ as a by-product; re-oxidation of Fe2+ to Fe3+ in the epilimnion, assisted by A ferrooxidans; precipitation of secondary ferric minerals (schwertmannite, jarosite) in the epilimnion; and replenishment of the Fe3+ concentration of the hypolimnion by seasonal lake turnover and gravitational settling and re-dissolution of ferric precipitates. Pyrite oxidation rates were approximated by using published rate laws and information on the Fe3+ concentrations (~5 mmol) of the Berkeley Pit as a function of depth. The results indicate that subaqueous pyrite oxidation may be releasing as little as 6 + 106 or as much as 600 + 106 moles of H+ each year to the lake; the large range reflects uncertainty in calculation of the specific surface area of pyrite in the flooded pit. This helps to explain the observation that the pH and metal concentrations of the Berkeley Pit have not improved with time since mine flooding began in 1983. Vertical cycling of ferric iron in the pit lake permits pyrite oxidation to continue in deep water, even in the absence of dissolved oxygen. This hypothesis is supported by preliminary stable-isotope data.

Jan 1, 2003

Developments in mining technology are outlined which point out that longwall face technology has the capacity to produce 20,000t/d on a regular basis. The optimum length of longwall faces is about 250m. Developments of headings and gate roadwyas require radical changes to meet longwall developments. New conceptual models are outlined to meet the challenge.

Jan 1, 1988

By Willis GM

The matte-metal-equilibria in the system Pb-Cu-S have been studied at temperatures between 720 and 920¦C by direct sampling and D.T.A. methods. These results are compared with those of other workers. The applications of such data to a continuous copper drossing process, and to a number of other metallurgical processes are discussed.

Jan 1, 1975

By R Berry, S G. Walters, J A. Hunt, D Collett

The texture of an ore type is fundamental in understanding the metallurgical behaviour of an ore. This study will show examples of how quantified textural attributes (mineral shape, grain size and mineral association) can be obtained from automated and scanning electron microscope (SEM)-based microscopy and utilised using advanced image processing techniques. Examples will be shown of integrating quantified and semi-quantified meso- and macro-scale textural attributes as well as how they relate to texture-based visual logging systems. The implications of texture for processing behaviours such as comminution, liberation and recovery will be discussed. This research is part of a major collaborative geometallurgical project undertaken at the Centre of Excellence in Ore Deposits (CODES, University of Tasmania) and the Julius Kruttschnitt Mineral Research Centre (JKMRC, University of Queensland). The authors wish to acknowledge financial support and permission to publish from the sponsors of the AMIRA P843 GEMIII project.

Jan 1, 2008

By West Coast Staff

Attention to the design of facilities for drainage, of both surface water and seepage, made it possible to attain, for a qam impounding residues from a concentrating mill, a more stable sand wall which can eventually be carried to a greater height.EXPERIENCE WITH No. 1 DAMResidue from the lead zinc concentrating mill, which treats the ore from the Rosebery and Hercules Mines, was pumped 3,600 ft. through a 5-in. diameter woodstave pipeline to the site of the dam. It was formerly delivered through a 4-in. steel pipeline.State laws prevent the residue being discharged to waste into the Stitt River. Furthermore, as a pyritic residue it is a potential source of sulphur.Between 1936 and 1956 more than 1,000,000 tons. of residue was paddocked. The run-of-mill product was roughly classified at the dam in a 6-ft. diameter cone classifier and the sand fraction was pumped by a 3-in. pump to the front wall of the dam across a shallow valley. The overflow gravitated to the rear of the dam (Fig. 1). Typical sizings were:

Jan 1, 1958

By C K. Boafo, J Visser

Obuasi Mine in Ghana, with more than 100 years of mining history, developed from a surface operation into a deep >2000 m underground gold mine. The challenge is to extract value from narrow veins left after extensive mining in the wider ore zones of the mine. Since the merger of AngloGold and Ashanti Goldfields in 2004 the mine strives to achieve optimum extraction through an integrated Mineral Resource management process from geological modelling, resource evaluation to mine design and scheduling. The shear hosted gold deposit displays complex secondary shears of variable thickness and continuity. There is an ongoing process of changes taking place in the way that geological modelling and resource estimation is done. Recent developments include the use of computerised systems that support the whole resource management chain from resource modelling to reserve optimisation. The change in thought and technology now allows for targeting narrow veins previously ignored in optimisation and mine design since moving into mechanised mining. The increased knowledge and confidence in the resource models now allows for flexibility in mine design, selection of mining method and scheduling and extraction of the reserves. The focus area for change is the way the orebody is evaluated and extraction designed. Since 2005 major changes were made to the process. This paper considers the historical approach of resource management. It looks at the individual process changes and qualifying the way ahead.

Jan 1, 2008

By P Stoker

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. Mining and exploration properties have a unique set of technical risks. Privately-owned companies considering investing in the resources sector can optimise their investment decisions by adopting a systematic technical assessment of acquisition assets, similar to the approach commonly adopted by public financial institutions and publicly-listed companies.Technical due diligence provides a process to identify key geological, mining, geotechnical, metallurgical, environmental and social risks and opportunities and determine the most likely business case and valuation of assets. Technical due diligence is commonly carried out in parallel with legal, commercial and financial due diligence, often involving the acquirer, to maximise the understanding of the investment.There are significant advantages in investors conducting a comprehensive technical due diligence, which typically involves site visits and project assessment to international standards by an independent, multidisciplinary team of experts. The outcomes provide the opportunity for the investor to make early, informed decisions and to understand and manage risks.Technical due diligence may be carried out at several stages: when considering and weighing up a number of investment options, prior to and during a transaction or immediately post-transaction. In the first stage, the outcomes will inform the choice of investment and, more particularly, whether there are any fundamental flaws in the projects being considered. In the second stage, due diligence outcomes can inform the level of investment and approach to risk management and planning. In the third stage, risks and opportunities can be investigated in more detail, allowing the investor to consider the best options to reduce risk and maximise the benefit of the investment.This paper presents a summary of the technical due diligence assessment process, its benefits to investors, common risks in mining and exploration projects known to cause mining asset write-downs and principal technical due diligence approaches.CITATION:Keogh, A, Stoker, P and Thomas, M, 2015. Benefits of due diligence in private equity mining investments – maximising value and unearthing common risks , in Proceedings PACRIM 2015 Congress, pp 115–126 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By B Roache

Ground support installation into the face of development headings has become an accepted practice at many Australian hard rock mines. Ground support is installed in the development face to reduce personnel exposure to rockfall while conducting work tasks such as marking up, installing lifter tubes, charging, and face sampling. The ground support system installed in the face is typically friction bolts and mesh. This support system can be effective at reducing rockfall occurrence, but it also increases the cost of development per metre, in terms of capital for the ground support, jumbo and operator capital allocation and the installation time slowing each drill and blast cycle. Other issues associated with meshing and bolting the development face include management of rock bolts and mesh sheets in the fired dirt of every cut, damage to services such as vent duct, geometry issues when installing ground support onto irregular development profiles and operator error. Fibrecrete installation onto the development face for support is an option considered by many mines, but it can be difficult to manage due to the removal of visual indications of misfires and slowing the mining cycle due to the wait time for fibrecrete curing. The use of Thin Spray Liner (TSL) products in underground hard rock mines has been relatively infrequent in the past, mainly due to issues with cost, health and safety, and liner strength. Kanmantoo Mine investigated the use of TSLs for the purpose of development face support, while collecting data on the costs and practicalities associated with their use. Several TSL products were trialled and a preferred TSL product was selected for use as face support. Cost savings, drill and blast cycle timing improvements and other benefits were achieved while meeting the requirement to reduce rockfall risk.

Mar 29, 2023

By Manlapig EV, Lawson F, Clarkson CJ

A low grade middling sample from Mount Isa, Australia, assaying 31.7 per cent zinc, 12.9 per cent lead and 14.5 per cent iron was leached under atmospheric pressure in sulphate and sulphate-chloride solutions with ferric ions as oxidants. About 96 per cent of the contained zinc was dissolved into a 0.5 M H2SO4 - 0.5 M Fe2(SO4)3 solution at 90¦C within three hours from a five per cent by weight slurry density mixture. The leaching process is very temperature-dependent, suggesting a surface chemical control. In the latter stage, the leaching rates levelled off and the leaching was most probably controlled by both surface chemical reaction and diffusion processes. The addition of chloride ions in the leach solution resulted in an increase in the leaching rate. About 95 per cent of the lead sulphide contained was converted to lead sulphate which precipitated and remained in the residue. Essentially no lead remained in solution and the low chloride concentration did not affect the precipitation of lead sulphate. Half of the iron orginally present remained in the residue as pyrite although essentially all the cadmium and 90 per cent of the copper initially present were dissolved. Some three per cent of sulphide sulphur was oxidised through to sulphate, about 67 per cent was converted to elemental sulphur which can be recovered by solvent extraction, the rest remained in the residue mainly as pyrite. Ferric sulphate and sulphate-chloride solutions can be used to effectively leach finely ground lead-zinc middlings and other bulk sulphide concentrates. A complete separation of zinc from lead and silver has been demonstrated.

Jan 1, 1993