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By \/eena Sahajwalla, Jonathan Dicker, Paul O'Kane, Cath Skidmore, James Dankwah, Magdalena Zaharia, Rita Khanna, David Knights, N Saha-Chaudhury, Somyote Kongkarat

Due to the inherent limitations of current methods of disposal of end of life polymeric materials, avenues are researched towards developing alternative, environmentally friendly and economic recycling processes. Different polymeric materials (i.e. rubber, high density polyethylene (HDPE) and polyethylene therephtalate (PET)), quite distinct in terms of chemical structure and composition, were considered in the present study as carbon resources in EAF steelmaking. Investigations were conducted in both laboratory and industrial scale steelmaking to assess the effectiveness of using these materials as carbon sources for slag foaming in EAF steelmaking. Slag foaming is important because it enhances furnace efficiency.

Jan 1, 2011

By G. C. Hambleton

"The author has had wide experience in the reclamation of coal from coal mine waste dumps in the United Kingdom.The paper includes such topics as the processing decision and factors affecting processability; method of testing and appraisal; test data interpretation; historical influences in apppraisal; special contaminants and processing difficulties; methods of treatment; review of systems in use and their comparative economics; over-all system economics including excavation, handling methods, recovery system and shale disposal; effluent treatment; environmental considerations; alternatives to processing for coal recovery; light aggregate and cement usage; burned shale heaps; land reclamation; shale deposition for encouragement of vegetation by natural or artificial means; use of tailings fines; the environmental argument for action."

Jan 1, 1972

By L. Newman, R. Wyrick, R. Berezowsky

The Stillwater Mining Company operates an integrated mines, mill, smelter and base metals refinery complex in Montana, USA for the production of a high-grade platinum group metals (PGM) bearing concentrate, nickel sulphate crystal and cathode copper from the PGM-containing nickel-copper converter matte. The complex was constructed in stages over several years, starting with the mine and the mill, followed by the smelter and finally, a base metals refinery, which was commissioned in 1996. Due to the relatively small quantity of matte production, a straightforward refinery process was initially selected to extract the base metals, which reported to a mixed nickel-copper solution for further treatment off-site, and yielded a high-grade PGM concentrate suitable for treatment in a PGM refinery elsewhere. Subsequently, as a result of increased matte production, the process was modified to separate the nickel and copper, and to produce a nickel sulphate salt and cathode copper. This paper describes the design and operation of the original and the modified processes utilized in the base metals refinery (BMR).

Jan 1, 2004

By P. T. Craddock, H. V. Paliwal, L. K. Gurjar

The Indian cultural heritage of mining, smelting and the use of minerals and metals dates back to ancient times. Although the exact date of the commencement of such activities in India is not certain, Indians are known to have been familiar with gold, silver, copper, tin and lead and to a lesser extent with iron at least since the Vedic period (Table 1).

Jan 1, 1999

By C. A. Petch

Abstract - The High Lake polymetallic deposit is located in the northern Slave province, 40 km south of Coronation Gulf, Nunavut. The main zone, the AB zone, hosts an estimated resource of 3.56 Mt grading 5.0% copper, 1.1% zinc, 0.06% lead, 1.7 g/t gold, and 18.2 g/t silver. Archean felsic metavolcanic and metavolcaniclastic rocks are the dominant rock type and are associated with lesser mafic metavolcanic and carbonate-rich metasedimentary rocks. The sequence strikes north-northeast, dips steeply to the west, and is truncated to the west by a large granodioritic intrusion. The mineralization at the AB zone is comprised of massive and stringer chalcopyrite-sphalerite-pyrrhotitepyrite± galena. At the core of the mineralized zone, intensely chlorite-altered rocks are locally metamorphosed to form distinctive zones of anthophyllite-magnetite-cordierite-altered rock. Peripheral to the mineralized core, alteration consists of sericitization, silicification, and weaker chloritization. Primary morphology and facing direction of the zone are difficult to interpret in part due to poor primary metal zonation of the deposit. However, the irregular shape of the mineralized zone and the erratic zones of zinc enrichment at the fringes are consistent with the interpretation that the zone was formed by the replacement of a porous volcaniclastic pile.

Jan 1, 2004

By Gordon L. Draeseke

"Before getting into more specific aspects of my talk today I should put in one disclaimer - one week in Mainland China and one day with Premier Kosygin does not make me an expert on Sino-Soviet affairs nor on Canadian-Chinese relations. Perhaps though there is a message in the fact that one meeting took place in relative openness in China and the other was at least partly in a bullet-proof limousine in Canada. I thought it might be interesting and appropriate to explain something of the forest industry to you who are engaged in the mining industry. Our industry, like yours, is based on a natural resource and the basic activity that we engage in is the extraction and conversion of that resource into saleable materials. However, the fundamental difference between our industries is that our resource is on top of the ground - easily visible and easily measurable, whereas yours is under the ground - difficult to find and, having been found, expensive to measure. A second difference is that ours is renewable while yours is extractive, and you must keep finding more to keep up reserves."

Jan 1, 1971

By A. Gronningsater

Introduction As is well known, the fight between the blast furnace and the reverberatory furnace in copper smelting during the second decade of the century ended with a victory for the latter, a result which must largely be attributed to the introduction of flotation methods. To my knowledge, no new blast furnace has been blown-in at any American copper smelter since the War. As the metallurgy of nickel, up to and including matte smelting, is generally considered a close parallel to that of copper, the introduction of reverberatory smelting in the big new smelter of the International Nickel Company at Copper Cliff, built in 1928-30, seemed a logical adherence to a well established trend. In view of these facts, considerable comment was made when Falconbridge Nickel Mines decided to retain the blast furnace in their smelter built about the same time, in 1929. A presentation of the reasons governing this choice should therefore be of interest. The basic principles underlying the Falconbridge practice, and the considerations guiding the successive steps in the operations, will be discussed in the following. To understand the problems involved, the character and mode of occurrence of Sudbury ore must be kept in mind. Large amounts of disseminated ore are generally present. Although the gangue usually runs only about 50 per cent Si02, the ore hoisted as a rule contains more silica than needed in the smelting operation; until recently this excess was removed entirely by hand picking (in later years supplemented by magnetic sorting methods), a difficult and not very satisfactory method, in which 'the border line between ore and waste is entirely arbitrary, and therefore too much depends on the judgment of the picker.

Jan 1, 1934

"In many gold deposits, a reasonable amount of the gold that remains in the cyanide leach tailing is associated with pyrite. Some gold plants have found it economical to incorporate gravity circuits on the cyanide leach tailing to recover the gold bearing pyrite before subjecting it to fine grinding, then recycling the ground pyrite back to the cyanide leach circuit. For low grade gold deposits the loss of gold bearing pyrite is exacerbated as the broader process economics normally favour a coarse grind (> 150 ?m). An option that has received attention over the last decade is to recover the gold bearing sulphides in the milling circuit by gravity, similar to the widely-practiced gravity recovery of free liberated gold. The modelling and simulation of a gravity gold circuit in a milling flowsheet is relatively simple compared with a gold bearing pyrite circuit, as the recycle advantages and breakage functions for gold and pyrite are quite different. This current work represents an attempt to simulate the gravity recovery of gold bearing sulphides in a milling circuit that also incorporates fine grinding, using relatively simple simulation models. The simulation results are further explored with reference to the economics of this type of circuit.INTRODUCTION It is well known that gold is associated with pyrite in most sulphide gold deposits and that the amount of gold associated with pyrite will vary from deposit to deposit. Most of the gold associated with pyrite is liberated in the grinding circuit during the processing of a gold ore. However, some gold remains occluded in the pyrite and is lost in the final leach tailings. Little information is available in the literature on methods to enhance gold liberation from pyrite by specifically removing pyrite, either in the grinding circuit or from the final tailings stream, and grinding it finer. One of the earliest record of this approach is described by King (King, 1949) where pyrite present in Witwatersrand gold ores was recovered by circular jigs and Johnson barrels followed by fine grinding of the concentrate prior to cyanide leaching. Dominy et al., 1970, provides information on the use of Yuba jigs to recover pyrite from the discharge end of ball mills. Again, the jig concentrate was ground to a fine particle size before cyanide leaching to recover the liberated gold. Unfortunately, no information is provided in these articles on the additional gold recovery from implementing these circuits in a flowsheet. Martins et al., 1993, provides details of a gravity circuit using Reichert cones and spirals to recover gold bearing pyrite from a cyanide leach tailings followed by fine grinding of the pyrite concentrate in a Tower mill. The ground concentrate returned to the front end of the already installed leach circuit. Overall recoveries were increased by some 2% to 4% depending on the amount of gold and pyrite in the plant feed."

Jan 1, 2017

By David Humphreys

It is difficult to overstate the importance of China to the future of the world mining and metals industries. In a remarkably short time, China has risen to become the world?s largest producer and consumer of steel and its second largest consumer of non-ferrous metals such as copper and aluminium. It is currently the world?s largest buyer of copper on international markets, the second largest buyer of iron ore, and the third largest buyer of alumina. At the same time, it is the world?s largest or second largest producer and exporter of tin, lead, zinc, magnesium and a host of minor metals and industrial minerals, as well as a fast-growing exporter of coal.

May 1, 2002

By François Robert

"The Eastern Abitibi Sub province (Quebec segment), contains two main types of gold deposits: the common quartz-vein type and the rare pyritic type. Both occur in areas dominated by volcanic rocks and are spatially associated with major fault zones.Quartz-vein gold deposits consist of simple to complex networks of quartz-carbonate-pyrite veins in reverse shear zones and extensional fractures. They occur in areas dominated by mafic volcanic rocks and are commonly associated with small syn- to late-tectonic porphyritic felsic intrusions. Associated alteration, which postdates peak metamorphism, is dominated by carbonatization, sericitization and pyritization of the wallrocks. These deposits formed late in the geologicalevolution of the Abitibi.Pyritic gold deposits range from deformed massive sulphide lenses to zones of syntectonic pyrite-rich veinlets and associated pyrite disseminations. These deposits occur in environments dominated by felsic volcanic rocks that are typically converted to sericite schists near the deposits. The associated pre-metamorphic aluminous alteration is now characterized by metamorphic sericite, andalusite, kyanite and chloritoid, overprinted by a late retrogression of alumino- silicates. These deposits probably represent deformed volcanogenic massive sulphide deposits, but the timing of gold introduction in these is not fully understood.The differences in geological attributes reflect significant differences in the genesis these deposits: the pyritic deposits probably have a multistage genesis, including a pre-tectonic stage, in contrast to a single stage late-tectonic genesis for the quartz-vein deposits.RESUMELa partie Est de la Sous-Province de l’Abitibi( segment québécois) renferme deux types de gites d' or: ceux de type ""veine de quartz"" et ceux, plus rares, de type ""pyriteux"". Ces deux types se trouvent dans des secteurs particulièrement riches en roches volcaniques et mantrent une association spatiale avec des zones de failles majeures.Les gites de type ""veine de quartz"" correspondent à des réseaux de complexité variable de veines de quartz-carbonate-pyrite se développant dans des zones de cisaillement inverse et des fractures de tension. Ils se concentrent dans les régions dominées par des roches volcaniques mafiques et s’associent fréquemment à de petites intrusions porphyriques felsiques syn- a tardi-tectoniques. L’altération associée ace type de glte est postérieure à la phase majeure du métamorphisme et consiste en une carbonatisation, une sericitisation et une pyritisation des épontes. La mise en place de ces gites est tardive par rapport à l'évolution géologique de l'Abitibi.Les gites d' or de type pyriteux consistent en des lentilles de sulfures massifs déformes, des zones d' abondantes veinules pyrite uses syntectoniques, et des zones de pyrite disséminée. Ces gites se retrouvent dans des empilements contenant surtout des roches volcaniques felsiques qui sont transformées en schiste à séricine pres des gisements. L’altération a l’umineuse pre-metamorphique associée a ce type de glte a donné naissance, lors du metamorphisme regional, a la sericite, a 'andal ousite, a Ia lcyanite et au chloritoi""de; par la suite, les alumino-silicates ont été affectes par une alteration retrograde tardive. Ces gites representent probablement des depOts de sulfures massifs volcan gènes déformes, mais la chronologie de la mise en place de l'or dans ceux-ci est encore mal comprise.Les caractéristiques géologiques propres à chacun de ces types de gites reflètent des conditions de formation différentes: le type ""pyriteux"" montre une histoire génétique polyphasée, incluant une étape pre-tectonique alors que le type ""veine de quartz"" s’est développe au cours d’une seule phase tardi-tectonique."

Jan 1, 1990

By G. J. Kipouros, N. Dadvand

"In recent years coatings of alloys have been produced for a wide range of applications including many for wire bonding application. The main characteristic of the baths of electroless plating is the presence of sodium hypophosphite as a reducing agent and also as the supplier of phosphorus. In the electroplating of alloys the Watts bath is predominantly used. This presentation compares the two techniques, electroless plating and electroplating, and discusses the possibilities of cross utilization of sodium hypophosphite in an attempt to formulate baths that eliminate the waste disposal issue related to some components.INTRODUCTIONThe importance of surface characteristics and the linkage of surface coating process to surface characterization has given rise to the evolution of surface engineering. Not only the surface preparation and morphology has become very important to the coating technology but also the knowledge of surface area exposed to the process of coating or corrosion is absolutely essential in ascertaining the behaviour of coatings and their adherence to the substrate. The above concepts are not unknown to researchers involved in the protection of surfaces, particularly metallic, from corrosion and/or erosion corrosion. However, the complexity of the surface defects, roughness, porosity, interconnected porosity and other related factors have contributed to the uncertainty of the true surface area versus the nominal surface area. Therefore critical parameters such as current density and chemical surface intensity although have been studied extensively at the atomistic level by carefully prepared surfaces are very difficult to be determined at the practical scale required during the coating processes.The most pronounced case calling for an understanding the relationship between the surface area and the effective protection is the coating of surfaces of items produced by compression or consolidation of powdery materials. With the advent of nanomaterials and the additive manufacturing through 3D metal printing this issue is becoming more important. Certain experience in this field come from the accumulated knowledge resulted from the attempts to characterize the electrochemical behaviour of powder metallurgy metals and alloys. Powder metallurgy has been a well-established process for half a century on basic metals such as iron, copper and their alloys. Recently the development of powder metallurgy process for aluminum, titanium and attempts to develop powder metallurgy processes for magnesium and its alloys has brought to light another important issue that of the development of coatings on difficult to plate reactive metals such as aluminum and magnesium. Despite of many successes in the development of powder metallurgy alloys the exact characterization of the corrosion behaviour of the coatings and the substrates is difficult to determine because of the unknown morphology of the exposed area i.e. the exact morphology and area of the exposed surface (Samal, 2007)."

Jan 1, 2016

By Tamas Kekesi, Gergo Rimaszeki, Tibor Kulcsar

The efficient purification of soldering waste material can be achieved in a single operational step by the electrolytic refining in pure hydrochloric acid - tin-chloride media. The complex formation of the ionic species may offer a beneficial level of natural inhibition. Using the PCR (periodic current reversal) technology, is efficient in affecting the morphology of the cathodic deposit. In order to optimize the process, the investigation of the solution stability and the electrode reactions is essential. The natural tendency of the Sn(II) oxidation and precipitation can be overcome by properly controlling the concentration of the main components and the ratio of Sn(IV)/Sn(II) in the electrolyte solution. Polarization curves were obtained for different concentrations tin and hydrochloric acid. Conclusions referring to the electrode reaction were derived from the overvoltage - current plots. The morphology of the deposit can be correlated with the exchange current density, also determined from the polarization curves. The cathodic current efficiency and the morphology of deposited metal are affected by the distribution of tin species and the principal electrolysis parameters.

Jan 1, 2011

By W. D. Sinclair

"Between 1934 and 1956, nearly 31 million grams of gold were produced in the Matachewan area from deposits on properties belonging to Young-Davidson Mines Limited and Matachewan Consolidated Mines Limited. In 1979, production from these properties was renewed by Pamour Porcupine Mines Limited.Most of the gold produced has come from relatively lowgrade deposits (3.4 gl t or less) that occur in an east-trending belt of dykes and irregular bodies of trachytic syenite. Although small by comparison, these deposits have some of the characteristics of porphyry copper-molybdenum deposits. The mineralized syenite contains up to 5 per cent disseminated pyrite and is highly fractured and cut by quartz and quartzcarbonate veinlets. Gold occurs as native gold along fractures, in quartz veinlets and as minute inclusions in pyrite. Minor chalcopyrite and trace amounts of scheelite, molybdenite and galena are also present. Mineralization was accompanied by potassic alteration, consisting mainly of potassium feldspar.Some gold was also produced from small, but higher-grade, deposits in volcanic rocks. These deposits occur near the syenite-hosted deposits and consist of quartz veins and stringers mineralized .with pyrite and gold. Minor gold is present in some low-grade, porphyry-type copper-molybdenum occurrences and, locally, in large, isolated quartz veins.Lead isotope analyses suggest that the gold deposits were formed at about 2700 Ma and were locally remobilized at approximately 2400 Ma, following the Kenoran orogeny. The deposits appear to be genetically related to felsic magmas emplaced in an epizonal environment and deposited from hydrothermal solutions relatively concentrated in S and K20."

Jan 1, 1982

By C. M. Diaz, P. J. Mackey

Since its inception, in 1987, the Copper-Cobre series of conferences has established itself as the prime world forum for discussing advances in copper process metallurgy, in particular copper sulfide smelting, copper recovery by leaching and electrowinning and copper electrorefining. All copper producing countries have actively participated in the pyrometallurgy symposia held in the framework of these conferences. In 1999 and 2003, the close to 100 pyrometallurgy papers that were presented had to be accommodated in two volumes. In the present paper, the authors firstly provide a brief historical sketch of the Copper-Cobre conferences and then focus on providing a retrospective look at the dramatic changes that have taken place in copper smelting in the last few decades, primarily as discussed in the Copper-Cobre and precursor conferences pyrometallurgy proceedings. Topics include: the development of autogenous, increasingly more intensive, environmentally sound and energy efficient smelting processes; significant improvements in Peirce-Smith converting practice and at the same time the commercialization of alternative continuous converting routes; the consequent expansion and modernization of smelters; the increasing compliance with strict government environmental regulations in most copper producing regions of the world; the realignment of the copper smelting industry throughout the world; and trends in copper smelting R&D. A look at the future closes these reflections on the contribution of the Copper-Cobre conferences to the advancement of copper smelting technology.

Jan 1, 2007

In order to avoid impurity problem and enhance absorption/desorption kinetics of Mg-based compounds, nanostructured Mg-based compounds were synthesized from Mg, Ni and other elemental nanoparticles produced by hydrogen plasma-metal reaction. XRD and TEM results demonstrate that homogeneous nanostructured Mg-based compounds with less impurity were successfully synthesized by this method. DSC in hydrogen atmosphere, pressure-composition isotherm and the kinetics of hydrogen adsorption/desorption were investigated at different temperatures. The results show that the nanostructured Mg-based compounds can absorb hydrogen in a high speed at a low temperature.

Jan 1, 2005

By B. Currie

Maintenance of quality electrowon copper requires an electrolyte which has suitable chemical and physical characteristics. The proper design and operation of the solvent extraction plant is essential to the quality of the electrolyte sent to electrowinning. An aspect that is not well appreciated is that the return electrolyte can have negative effects on the operation of the solvent extraction plant. Poor SX plant operation creates below optimum electrolyte conditions. High Eh in the return spent electrolyte can degrade the SX reagent with large decreases in copper transfer capacity and increases in internal entrainment. The synergistic interaction of the SX and EW plants needs a single-source design approach to address the interactions. The design elements in the SX and EW plants required to manage the electrolyte conditions are discussed.

Jan 1, 2014

By C. T. Harper, B. J. Fryer, R. P. Taylor

"IntroductionThe Maurice Bay deposit is one of a number of uranium deposits that have been found in recent years in the Athabasca Basin of northern Saskatchewan (Tremblay, 1982). This deposit, along with the others, belongs to the unconformity type deposits (Beck, 1977). They are, for the most part, polymetallic, being characterized by a suite of metals which include U, Ni, Co, Cu, Pb, Zn, Mn, V, Ag, Au, Pt-group elements, S, As, Bi, Se, Te, and Mo, some of which, besides U, are present in economic concentrations (Amok, 1974; Ruzicka, 1975; Tapaninen, 1976; Hoeve and Sibbald, 1978; Dahlkamp, 1978). The Maurice Bay deposit was known to be a small low grade deposit in which the ore was essentially monomineralic, consisting mainly of pitchblende (Harper, 1978). However, the occurrence of trace amounts of some of the elements common in the larger polymetallic ore bodies (e.g. Key Lake, Cluff Lake D) was anticipated. Thus a lithogeochemical sampling project was undertaken in 1979 across part of the Maurice Bay deposit (Harper, 1979). Major oxides (SiO2, Al2O3, FeO, Fe2O, MgO, CaO, K2O, Na2O, MnO, P2O5, and TiO2) and a group of the most common trace metals (U, Ni, Co, Cu, Pb, As, Au, V, and Se) were analyzed to determine whether any elemental patterns (halos or depletions) could be detected which would reduce the number of pathfinder elements needed for exploration purposes. In addition to the above metals, Th was also checked because some conglomerate strata in the Maurice Bay area are known to be thorium-enriched (Harper, 1978). Only the trace metal distributions will be discussed in detail in this report.General GeologyThe Maurice Bay area is underlain by three major groups of rocks, the White Lake metamorphic complex, an unnamed granodiorite complex, and the Athabasca Group, described previously (Fig. 1; Harper, 1979). Table 1 summarizes the stratigraphic features as deduced by geological mapping and the examination of drill cores."

Jan 1, 1986

"THE CONCEPT of energy as a commodity, while not entirely new, is not as widespread as the importance of the idea to this modern world would lead one to expect. The growth in the supply and use of energy over the past years has been tremendous, but our very closeness and familiarity have somewhat distorted the viewpoint, particularly of the younger generation. To many of us who remember the wonderful satisfaction of our first responsibility for directing two horsepower hitched to a farm cart or hay wagon, there still arises a feeling of some awe at the casual flick of the switch with which our sons and daughters summon to their convenience the service of some one hundred or more horsepower.Energy is the vital component of our existence and, no matter what contempt our day-to-day familiarity may •breed, it is wise to .pause from time to time and consider our national energy standing. Have we still capital in the bank? Are our expenditures wisely •conceived and well directed? Is provision being made for the years •ahead for the needs of our children and our children's children?"

Jan 1, 1953

By N. Coli

The exhausted Santa Barbara open pit mine (Tuscany, Italy), owned by the main electric power company in Italy (ENEL S.p.A,) extracted lignite as a fuel for the Santa Barbara thermoelectric power plant. The mining activity led to the excavation of a wide slope (with maximum height of 200 m and a planar extension of about 1300 m x 500 m) in the Shale Limestone Chaotic Complex (SLCC) (Figure 1). Since the beginning of its excavation the slope underwent rotational landslides and diffuse instability phenomena. From a geotechnical point of view the SLCC represents a typical bimrock (block-in-matrix rock) (Medley 1994, Medley 2002, Medley 2007) characterized by a mixture of a highly sheared, scaly-fabric, clayey matrix and calcareous blocks ranging from a few millimetres to tens of metres in size. Since the geometrical properties of blocks (grain-size distribution, shape, orientation and volumetric proportion) have been proved to influence the mechanical behaviour of bimrocks (Lindquist & Goodman 1994, Goodman & Ahlgren 2000, Kim et al. 2004, Sonmez et al. 2006), the aim of the present study is to investigate the geometrical properties of calcareous blocks in order to properly characterize the mechanical behaviour of the SLCC bimrock and to further assess the stability of the slope. Block size-distribution and shape were investigated by means of advanced image analysis techniques of SLCC pictures taken in the field. Geostatistical semivariograms and variographic maps were also used in order to investigate the anisotropy of block spatial distribution. Finally, in-situ large sized sieving tests were carried out to investigate the volumetric block proportion within the clayey matrix.

May 1, 2009

By J. E. Dutrizac, J. M. Zinck

Ferrihydrite is often the initial precipitate resulting from the rapid neutralization of Fe(III) sulphate solutions, and it seems to be a major constituent of zinc plant neutral leach residues. The most important parameters affecting ferrihydrite precipitaton are temperature, solution pH and the neutralization rate. Low temperatures and rapid neutralization rates yield poorly filterable ferrihydrite, whereas higher temperatures and slower neutralization rates produce readily filterable precipitates; in all instances, however, the precipitates are two-line ferrihydrite. Significant amounts of Zn are incorporated in the ferrihydrite precipitates, and the Zn contents increase with increasing Zn concentration, pH or temperature. Generally, the sulphate contents of the precipitates decrease as the Zn contents increase, and this may indicate that the Zn is adsorbed on the ferrihydrite. Discrete Zn phases were not detected. Neither Cd nor Tl is precipitated with ferrihydrite, although thallium jarosite co-precipitates with ferrihydrite at high Tl concentrations and elevated temperatures. Virtually all of the Sn added to the solution precipitates with the ferrihydrite, but the tin is believed to be present as intimately admixed amorphous SnO2.nH2O. Although selenite extensively precipitates with the ferrihydrite, selenate remains mostly in solution, likely because of the close similarity of the SeO4 2- ion to the SO4 2- ion which is present in high concentrations and saturates the available sites for anion adsorption.

Jan 1, 1998