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By T. Lux, H. -J. Krassnig, I. Filzwieser, E. Hecker, R. Degel, A. Filzwieser

Non-ferrous metals find their applications in smartphones, tablets and computers. These materials with their particular properties are the basis of our modern life. SMS group is well prepared for this huge market and for growing future challenges. A large contribution here is the new joint venture PolyMet Solutions that was founded by SMS group and Mettop, an Austrian engineering company, with the objective to develop new technical solutions for the primary copper production lines as well as for non-ferrous metals starting with the primary smelting of concentrate and ending with the electrolysis. PolyMet Solutions provides the process know-how whereas SMS group supplies the plants and equipment and Mettop the key components. SMS group and Mettop also cooperate in the field of tankhouse technology. Together with Montanwerke Brixlegg AG, Mettop has developed together with a parallel flow technology (METTOP-BRX Technology), allowing a current efficiency of above 98 % at a current density of 420 A/m², which is a milestone in copper electrolysis. For the secondary copper production route, SMS group and PolyMet Solutions developed an innovative refining furnace (PolyRefine) for the smelting and refining of copper scrap. The refined copper is directly charged to the Contirod line to produce copper rods and wires. The innovative cooling solutions of SMS and PolyMet Solutions come into play where furnaces have to stand the highest loads and stresses, for instance in areas of very high temperatures or temperature fluctuations, aggressive exhaust gases and slags, or at critical spots such as taphole areas. Custom-tailored cooling systems for furnace vessels make sure varying loads are compensated in a targeted and effective manner. The solutions include air cooling, spray cooling, cooling technologies with integrated copper elements such as CFM (Composite Furnace Modular) cooling systems, plate and finger coolers. The major innovation in the field of furnace cooling is the ILTEC (Ionic Liquid Cooling) Technology which paves the way for increased plant safety. This revolutionary, patented cooling technology is jointly marketed by Mettop and SMS group. It permits water-free cooling to be implemented and thus makes operation safe wherever it is applied. INTRODUCTION Non-ferrous metals or NF metals are changing the world. There is no modern industrial sector that can do without these valuable metals. Non-ferrous metals find their applications in smartphones, tablets and computers. These materials with their particular properties are the basis of our modern life. The importance of the non-ferrous metals market is reflected by two figures. In 2018, the production of non-ferrous metals was worth more than 237 billion Euros. This contrasts with 255 billion Euros of the value of iron and ferro- alloy production in the same year (International Organizing Comittee for the World Mining Congresses, 2018). Hence, the NF metal industry is almost as important as the iron and steel industry. SMS group is well prepared for this huge market and for growing future challenges. A large contribution here is the new joint venture PolyMet Solutions that was founded by SMS group and Mettop, an Austrian engineering company, with the objective to develop new technical solutions and to enhance customer value. The prices of nearly all metals have come under pressure during the past few years. Therefore, competitive technologies are regarded a crucial factor to achieve success in this critical market situation respectively to stabilize the market position.

Jan 1, 2019

By Hamid-Reza Manouchehri

Coarse particles flotation is controlled by detachment (particle hydrophobicity and flotation cell turbulence) For composite particles (the bubble may attach to good hydrophobic region, but the expansion of the three phase line of contact is limited. Hence, the equilibrium contact angle, characteristic of the hydrophobic region, may never be attained, and the force of attachment is decreased relative to that possible for homogenous hydrophobic surfaces.

May 1, 2013

By D. C. Treilhard

After a brief history of the mining and smelting operations of Kilembe Mines Limited, this paper outlines the smelter layout and describes . the. daily operations at the Jinja plant. Particular attention 1s paid to the details of the furnace and converter operation. A subsequent section of the paper deals with the significant developments in plant metallurgical practice, covering both smelting and converting.

Jan 1, 1966

By G. E. Agar, W. B. Kipkie

"This paper deals with the prediction of locked cycle flotation results from data developed from individual batch tests. A postulate is made that the distribution of material in a separation stage is determined by the chemical conditions and the flotation time and that this distribution can be characterized by split factors which are constants for a fixed set of conditions. With this premise, it is demonstrated that a steady state balance can be calculated for a circuit.Although the necessary equations can be solved algebraically, a computer program was written that uses an iterative tec1nique to arrive at the steady state balance. The program is written so that a variety of circuits can readily be simulated.A number of examples are examined to demonstrate the validity of this simulation procedure. The sensitivity of the material balance to changes in the split factors was examined. Data developed from different flowsheets is presented on sulfide ores, on copper-nickel separation and on silver flotation,"

Jan 1, 1978

By J. A. Meech

"The technology known as Expert Systems is being used within the minerals industry in a wide variety of problem areas. Applications include diagnosis, prediction, training, monitoring and control. Expert Systems provide a way to program computers to imitate human thinking. The construction of such systems is a straight-forward task that can be quickly learned by novices but can require a lifetime to master.To assist in the understanding and utility of this technology, a special manual bas been prepared which operates on a microcomputer under the MS-Windows environment. The manual covers all aspects of Artificial Intelligence of relevance to Expert Systems. A hypertext system allows users to probe as d•~ply as needed to achieve understanding or to simply skim the surface of the knowledge to obtain a quick overview of subjects. The manual was developed under the sponsorship of the Mineral Sciences Laboratory of CANMET and is available from the Mining and Mineral Process Engineering Department at the University of British Columbia. Annual updates are planned to keep abreast of new developments in this rapidly changing technology. RESUMELa technologie: des Systèmes Experts est utilisée par l'industrie minière pour résoudre une grande variété de problèmes. Les domaines d'application comprennent le diagnostic, la prédiction, la formation, la surveillance et le contrôle des procèdes. Les Systèmes Experts permettent d'écrire des programmes d'ordinateur qui imitent le processus de la pensée humaine. La construction de tels systèmes e:st une tâche qui peut être apprise rapidement mais qui peut prendre des années à maitriser.Pour aider à mieux comprendre et utiliser cette technologie, un manuel spécial opérant sur microordinateur dans l'environnement Windows a été développe. Le manuel couvre tous les aspects de l'intelligence artificielle qui concement les Systèmes Experts. Un système ""hypertexte"" permet à l'utilisateur d'étudier un sujet en profondeur ou de simplement couvrir une grande variété de sujet en surface. Le manuel a été développe avec l'aide financière du Laboratoire des Sciences Minérales de CANMET et est disponible au Département de Génie Minier et Minéralurgique de l'Université de la Colombie Britannique. Des mises à jour annuelles sont prévues de manière à couvrir les changements et nouveautés de cette technologie en évolution."

Jan 1, 1993

By E. Dalgaard

During linear friction welding of titanium alloy Ti-5A1-5V-5Mo-3Cr (Ti-5553), the weld zone exhibits beta (B) grain refinement and alpha (a) phase depletion that have the combined effect of deteriorating the mechanical performance of the weldment. In this work, linear friction welded Ti-5553 was subjected to pre- and post- weld heat treatments in order to determine the conditions under which a phase depletion could be mitigated in the weld zone and thermomechanically affected zone (TMAZ). The mechanical response of the welded samples to the heat treatments was determined by performing tensile testing at room temperature. While the pre-weld heat treatments had no significant effect, the post-weld heat treatments were instrumental in restoring the strength of the starting (heat-treated) material.

Jan 1, 2011

By Michael Bowker

Au/TiO2 catalysts were prepared by incipient wetness impregnation and tested for the room temperature photocatalytic reforming of methanol in aqueous solution. These catalysts proved to be more active, on a molar basis, than Pd/TiO2. The dependence on loading of gold was different from that of palladium, showing a double maximum in yield at 0.1 and 2 wt. % with low rate below 0.01% and above 10%. A model is proposed for the reaction involving band gap excitation of titania electrons which are used to oxidise the methanol via adsorbed CO. With palladium, photoreforming of CO and water can be achieved, but this is much less effective on gold, presumably due to the much weaker bonding of CO on Au.

Oct 1, 2003

By Finch. J. A., C. Perez, J. M. Ortiz, G. Cortes, A. B. Yañiez, F. Coddou, P. Morales, H. Elgueta

A campaign to perform characterization tests in a TankCell®-300 flotation cell installed at Chuquicamata Codelco's concentrator was conducted. The campaign included integrated gas dispersion measurements (gas velocity radial mapping and single point gas holdup and bubble size) and determination of frother concentration. Cell streams were sampled to assess metallurgical performance at the same time. The experimental program was designed to establish the bubble surface area flux operating range and its effect on performance, and the effect of using longer residence times and of a device designed to enhance mixing in the collection zone (FlowBooster(TM)). The gas dispersion results and their relationship to metallurgical performance are discussed.

Jan 1, 2009

By Yves C. Lizotte, Malcolm J. Scobie

Blast fragmentation is affected by the physical and mechanical characteristics of the rockmass as determined by geology as well as the explosive energy, the partition of this energy, the actual amount of energy transmitted to the rockmass, the blast geometry and the detonation sequence. This paper reviews studies of the influence of geology on blast fragmentation, particularly structure, i.e. the in situ or inherent fragmentation arising from rock discontinuities. Prior structural studies have mainly been limited to comparing equivalent diameters of the in situ blocks with the size distributions of the blasted material. No criteria exist to integrate structure into blast design. This paper reviews on-going studies of the blasted fragment shape and size observed in different rockmasses aimed at analyzing geological control over blasting. Digital photoanalysis was applied {o measure size and shape distributions, to correlate results with block size distributions and shape parameters of the inherent fragmentation. An integrated and comprehensive fragmentation assessment procedure which accounts for geological control is proposed. The potential of this research is to provide a greater understanding of the true contribution of explosives to fragmentation, the effects of fragment shape on system productivity and the reduction of blast-induced damage.

Jan 1, 1994

By G. Chung, W. Petruk, D. Doyle

"A series of tests was conducted on Carol Lake iron ore, which contains about 38 wt % hematite and 19 wt % magnetite, to establish a flowsheet for high weight yield by spirals. A pilot plant was run in parallel with the IOC concentrator to simultaneously test two flowsheets on the same feed material. The IOC concentrator processes the ore by treating it directly in a spiral circuit, whereas the pilot plant used a laconite flowsheet which had a low intensity magnetic separator (LIMS) at the front of the circuit. The LIMS produced a non-magnetic (hematite-rich) product and a magnetic (magnetite-rich) product prior to treating the ore in two separate spiral circuits. The results from about 150 tests were evaluated by chemical assays and materials balancing techniques, and a selected test was evaluated by the image analysis and materials balancing technique.The image analysis and materials balancing evaluation showed that a higher hematite recovery was obtained by the hematite spiral circuit than by the IOC concentrator spiral circuit, and a slightly lower magnetite recovery by the magnetite spiral circuit than by the IOC concentrator spiral circuit. Furthermore the hematite recovery by hematite spirals was higher than the magnetite recovery by magnetite spirals. The better hematite recovery was achieved because a higher liberation is obtained for hematite than for magnetite, and the hematite in the Carol Lake ore has a narrower grain size range than magnetite. Consequently, better spiral control can be maintained when processing a hematite-rich spiral feed, than when processing a magnetite-rich spiral feed. Since the feed to the IOC concentrator spiral is a mixture of hematite and magnetite, an intermediate hematite recovery is obtained by the IOC concentrator. INTRODUCTIONA study of characteristics that affect recoveries of hematite and magnetite from the Carol Lake ores of the Iron Ore Company of Canada (IOC), was carried out in connection with a project on designing a flowsheet for maximum weight yields. A pilot plant using a taconite flowsheet was run in parallel with the existing IOC concentrator which uses a classical iron ore flowsheet. About 150 tests were run to compare iron recoveries and weight yields by the spirals in the two flowsheets. Better iron recoveries were indicated for the taconite flowsheet, but the results were not consistent and the reasons for the observed differences were not apparent. The material from one test (Test 61), which gave better iron recoveries for the taconite flowsheet, was evaluated by the image analysis and materials balancing technique. A suite of samples was taken from 5 points in the IOC concentrator and from 8 points in a pilot plant (taconite flowsheet). The samples were analyzed to compare the behaviours of the Carol Lake hematite and magnetite in the spirals of the two flowsheets. The results provided a sound basis for further tests in designing a high weight yield flow sheet."

Jan 1, 1993

By J. Stumper

The control of the distribution and movement of liquid water is crucial for increased reliability and durability of PEM fuel cells: whereas the proton exchange membrane requires a minimum amount of liquid water for optimum operation, water excess in the GDL will impede reactant gas access to the catalyst layer thereby reducing performance. In order to understand the relationships between water management on one hand and fuel cell performance and durability on the other, Ballard has been developing a number of minimally invasive techniques that can throw light on the role of liquid water for both cell performance and durability. This paper introduces a novel measurement method that can provide information about the amount and distribution of liquid water under operation. It is shown how the MEA Resistance and Electrode Diffusivity (MRED) method can be used to determine i) the amount of liquid water in the fuel cell, ii) the pure ohmic cell resistance and iii) the O2 -diffusivity of the cathode. Furthermore, through a combination of the MRED method with current mapping it is possible to determine spatially resolved MEA resistance profiles.

Jan 1, 2005

By V. G. Papangelakis, G. A. Moldoveanu

"One of the major commercially viable secondary sources of rare earths elements (REE) are the ion-adsorption ores, containing 0.05-0.3 wt% rare earth oxides physically adsorbed on the surface of clay minerals formed during weathering of lanthanide-rich rocks. Although ion-adsorption deposits are substantially lower grade than other types of rare earth sources, this is offset by the easier mining and processing costs and the low content of radioactive elements. The conventional extraction route involves ion exchange leaching with monovalent cation solutions (usually ammonium sulphate) under ambient conditions; during the process, the lanthanides are desorbed and transferred into solution, being replaced by the exchange cation. While ammonium ions are known to perform best, there is increased environmental motivation to investigate alternative lixiviants in order to minimize ammonium sulphate impact via reducing its use without considerable loss in rare earth recovery.The objective of the present research was to screen various cations salts (alkaline and alkalineearth metals present as sulphates, chlorides and acetates, respectively) in order to comparatively evaluate lanthanide desorption levels and provide a theoretical base of the observed behaviour. The overall aim is to gain a better understanding of how both cation and anion may affect the overall REE recovery from ores in order to provide alternative processing routes. The distinct exchange capabilities of cations were explained in terms of differences in cation hydration enthalpy within the same group, i.e. Cs+ > NH4 + > K+ > Na+ > Li+ and Ba2+ > Ca2+ > Mg2+. For the same cation, it was determined that REE extraction efficiency follows the order sulphate > acetate > chloride, based on dissimilarities in constants of formation values. Various process implications scenarios will be described based on using mixed cations and anion matrices."

Jan 1, 2016

By A. Yousefpour, M. Hojjati, G. Chouinard

In recent years, high performance thermoplastic composites such as PEEK and PEKK have been developed for aerospace applications. These materials offer, among the other properties, high toughness and damage tolerances. These are semi-crystalline materials and their processing can lead to different crystallinity that in turn have some impact on the final properties. The effect of cooling rate on degree of crystallinity of PEEK is studied to identify the processing window for manufacturing. Samples were heated at the constant heating rate of 20°C/min up to 375°C (above melting point) and held for 10 minute. The enthalpy of the crystallization was measured at different constant cooling rates of 0.5, 1, 2, 5, 10, 20, 30, and 40°C/min. After cooling, the samples were heated at constant heating rate of 2°C/min using modulated DSC. At temperature between 90°C to 375°C, two endotherm peaks were observed. Results suggest that endotherm peaks are related to a melting and recrystallization phenomenon of one crystal morphology. However, the second endotherm peak could be associated with another crystal structure or morphology.

Jan 1, 2006

By Marcin Ziemski

This paper reports on an energy efficiency analysis completed as part of a research project looking at energy reduction opportunities in minerals processing operations. The plant discussed is a gold production facility owned by Newmont Gold in the Tanami region of central Australia. Due to its remote location, lack of nearby gas pipeline or power grid, the operation has been completely dependent on diesel fuel for its electricity generation and transport needs. The mine and processing plant use electrical power at a rate of 12MW to 18MW, resulting in a monthly electricity cost of over US$1.5M. The high cost of diesel combined with an impending power generation capacity shortage drove Newmont to undertake the energy efficiency study. An energy audit of the plant showed opportunities for significant energy savings through the strategic use of waste heat, fuel replacement alternatives and renewable energy sources.

May 1, 2007

By C. B. Webber

"Sherritt Gordon's experience with rubber mill liners began in 1964 at the Lynn Lake Farley Mine and continued at the Fox Mine in 1960, and the Ruttan Mine in 1973. This paper describes the history of the performance of rubber mill liners at the three mine operations.LYNN LAKE - FARLEY MINEThe Lynn Lake Farley Mine, which ceased production in 1976 due to exhausted ore reserves, was a 3500 T.P.D. copper-nickel operation; consisting of two parallel rod mills followed by three stages of ball mill grinding. A circuit modification in 1964 necessitated one of the tertiary ball mills to be used as a pyrrhotite regrind mill. This 8' x 5' Hardinge conical mill drawing 225 HP was initially installed with steel liners and lifters. After several months of operation a routine inspection revealed severe channeling and washing behind the liners which was threatening to erode the ball mill shell. It was thought that the highly acidic condition in the mill, due to grinding 100 º6 pyrrhotite, was accelerating the wear of the steel liners. At this time it was decided to reline the mill with rubber liners to see if the wear problem could be relieved, and in December 1964 a set of Skega rubber liners were installed."

Jan 1, 1981

By R. Hans

Removal of toxic anions from aqueous solution was studied using a Magnetic Ion Exchange (MIEX) resin which is a polyacrylic, strong base resin. Gravity based settling is made more efficient due to the magnetic nature of the resin which is advantageous over conventional ion exchange resins. In addition, the magnetic microspheres of MIEX have larger surface area in comparison to conventional ion exchange resins. Over the years MIEX has been successfully used and has gained significant popularity for efficiently removing dissolved organic matter from wastewater and groundwater. In the present study the efficiency of the MIEX resin was tested for the removal of chromium(VI), molybdenium(VI), vanadium(V) and arsenic(V) anions. Effects of pH (2-10) and temperature (25oC-55oC) were examined. In general, low solution pH values were favorable for anion uptake by MIEX. Except for chromium(VI), the metal ion uptake was significantly increased by the increase in solution temperature. The adsorption data were analysed on the basis of chemical speciation and heterogeneous kinetic models.

Jan 1, 2014

By Gonzalo Díaz, Diego Mesa, Willy Kracht

"It is well known that frothers affect the amount of water that is transferred to the froth, which has an effect on both the froth stability and the water recovery. On the other hand, since non-selective recovery by entrainment is directly related to water recovery, it can be said that frothers have an indirect effect on flotation selectivity. Recent research on this subject has shown that the non-selective recovery by entrainment, which is characterized by the entrainment factor, is frother dependent. In other words, the entrainment factor is not unique, but depends on frother type.Having different entrainment factors implies that for the same water recovery, the amount of undesired particles reporting to the concentrate may vary if one changes the frother type, which suggests, as a possible explanation, that it is not only the amount of water in the froth what is affected by frother type, but also the froth structure.The purpose of the current work is to study the effect of frother type on foam structure (two phase froth). A quasi-2D cell operated with a slot sparger was used to study the foam structure in the presence of three different frothers: Methyl Isobutyl Carbinol (MIBC), OrePrep®549, and Octanol at the same gas flow rate and reagent dosage. The foam structure was studied using image analysis, and an algorithm based on textural analysis was developed to classify the foams. The results show that it is possible to classify foams according to the frother used, which proves that frothers have an effect on the foam structure.INTRODUCTIONFrothers are usually dosed paying attention to froth stability, condition that is commonly estimated by sight, according to the operator's criteria and experience. This happens because there is not an established procedure or technique for frother characterization, generating qualitative descriptions such as “powerful” or “selective” frothers, which lack of scientific thoroughness and remain under subjective factors. Nevertheless, several works have been done in this line of research. Moyo et al. (2007) classified frothers based on their water-carrying capacity, proving that this characteristic is related with gas holdup and frother type. Previously, Trahar (1981) had related water recovery and gangue particles recovery, defining the entrainment value (ENT). Nowadays it is known that entrainment affects both hydrophilic and hydrophobic because it is not a selective process. In the last decade some studies (for example the one of Konopacka and Drzymala (2010)) delved into different entrainment behaviours dependent mainly on the flotation type (batch or continuous, agitated or columnar, etc.), but there were no studies on the effect of frother type regarding entrainment, since Rahal et al. (2001) argued that the ENT factor was independent of the frother type and concentration, and froth height."

Jan 1, 2016

By M. Connell, S. Bedrossian

Alkali cracking followed by chloride-based leaching is one of the prominent methods for rare earth element processing. Regeneration of the leach lixiviant, namely hydrochloric acid, is a critical operation in the process. A number of different process routes are available for recovery of hydrochloric acid from chloride solutions. The objective of this paper is to discuss various recovery routes and analyze the impact of several input variables on the variable operating cost.

Jan 1, 2014

By Jochen Petersen, Caroline Muzawazi

The technical feasibility of ammonia leaching of PGM bearing Platreef flotation concentrates was investigated as an alternative method for the recovery of base metals prior to precious metal recovery. The composition of the concentrates includes 2.02% Cu and 3.17% Ni, and the major base metal minerals are chalcopyrite and pentlandite. Optimal leaching conditions were initially established in shake flask experiments to be a solution containing 4 M NH4OH, 4 M (NH4)2CO3 and a pH range between 9 and 10. These were used as base case conditions in column and batch stirred tank reactor tests, where the effects of total ammonia concentration and operating temperature were explored further. At optimal conditions nearly 100% Cu and Ni extraction were obtained in the batch stirred tank reactor, and 95% Cu and 60% Ni extraction was obtained in columns. The activation energy for chalcopyrite and pentlandite was 36 kJ/mol and 16 kJ/mol, respectively, in both reactors, indicating different reaction pathways for the two minerals. Gas-liquid mass transfer appears to be the limiting reaction step in columns much more than in tanks, and the degree of ammonia loss to air is significant. This initial test work indicates the feasibility of using ammonia leaching for this and similar materials as an alternative route to conventional smelting and refining prior to PGM recovery, but a number of technical challenges still need to be overcome.

Jan 1, 2014

By R. B. Allen, B. S. W. Buffam

"The property of Chesterville Mines, Limited, is in McGarry township, Timiskaming district, Ontario, about 25 miles east of Kirkland Lake. It consists of a group of fifteen claims that extend northeast from the KerrAddison mine for a distance of 2 miles.In June, 1906, two groups of prospectors left the town of Chesterville, Ontario, to prospect in northern Ontario. Silver had been discovered 3 years before at Cobalt and the large profits of this young mining camp were the principal incentive to extending the field of exploration northward. One group consisted of Dr. Reddick, Edward Flynn, John Hummel, William Knott, and Colin Cameron. The other group comprised J. T. Kearns, Herman Hummel, W. G. Barkley, and J. Elliott.The two groups travelled north by train to Haileybury and thence to Larder lake by canoe. Camps were pitched on the northeast arm of the lake, and within a short time a discovery was made by Edward Flynn of the first party, who found gold on the property now owned by Kerr-Addison Gold Mines, Limited. Herman Hummel and J. T. Kearns shortly afterwards made the second discovery, on what is now the Chesterville property. These discoveries, made some years prior to those at Porcupine and Kirkland Lake, are believed to be the first in that part of northern Ontario.The Hummel-Kearns claims were incorporated in the following year under the name of Chesterville Larder Lake Gold Mining Company, Limited. It was not, however, until 30 years later, in 1936, following the increased premium on gold, that sufficient capital was placed in the treasury of the Company to carry out an extensive diamond drilling programme. This exploratory drilling was started early in 1937 under the direction of Leo. J. Kearns, and a large body of ore was intersected in the first drill hole. Underground work was started in 1938, a mill was built, and the first gold brick was poured on July 29th, 1939."

Jan 1, 1954