Search Documents

By M. Dupuis, V. Bojarevics

It is well known that horizontal current density in the metal pad contributes greatly to the generation of MHD driven bath-metal interface wave. It is possible to compute very accurately the metal pad current density using a very detailed finite element model [1], but a MHD model must be compatible to this level of mesh refinement and to recalculate the current distribution at each time step, including the full busbar supply system. The accuracy of the instability prediction of the cell depends on the accuracy of the metal pad current density calculation. This study presents the comparison of the metal pad current density calculation of the detailed finite element model and the MHD-Valdis model for different metal pad heights and ledge thickness. It also presents the corresponding cell MHD stability predictions.

Jan 1, 2006

By R. P. Zahn

The need for quantitative mineralogical data to characterize ore types before they are processed is becoming increasingly necessary. Mineralogical data (modal abundances, grain size, liberation/locking characteristics, mineral textures and associations) can provide invaluable information to facilitate the identification of metallurgical issues that may arise during processing of a particular ore. This paper will discuss the use of QEMSCAN analysis in conjunction with bench scale flotation test work to determine metallurgical characteristics for several ore types that will be fed to the Morenci concentrator upon commencement.

Jan 1, 2007

By A Hitchen

A general outline is given for the determination of copper, nickel, cobalt, zinc, lead, cadmium, bismuth, manganese, uranium, molybdenum, vanadium, sulphate and fluoride by polarographic or amperometric methods in a variety of ores or metallurgical products. The detection of oxygen in gas mixtures by an amperometric method used as a safety device is also discussed. Introduction I N this paper, a general outline will be given of the polarographic and amperometric methods used for the chemical analysis of various ores and metallurgical products in the Chemical Analysis Section of the Extraction Metallurgy Division of the Mines Branch. The methods to be discussed will be confined to those based on the use of normal D.C. polarography and will not include those methods which utilize a cathode-ray, square wave, pulse or A.C. type of polarograph. For the sake of convenience, ? the polarographic methods will be discussed according to the type of supporting electrolyte employed, as the same electrolyte may serve to determine more than one element in more than one type of ore. Amperometric methods will be discussed according to the element to be determined rather than

Jan 1, 1965

By Jeremy D. Glennon

A number of exciting challenges, opportunities and unanswered questions remain concerning the chemistry, geochemistry, medical, industrial and analytical applications of gold and its compounds.1 Among the challenges presented is the need for extraction methods for gold, at process and indeed analytical scales, that avoid the use of organic solvents or hazardous reagents. Extensive environmental contamination has occurred in the Brazilian Amazon from the mercury-gold amalgamation process. Major problems with the cyanidation process are the relatively slow dissolution kinetics and the health and environmental problems associated with it. With innovation and technical changes, a cleaner way for solubilising and extracting this versatile precious metal can be found. This cleaner future may lie in supercritical fluid science. Interestingly, geochemical studies of gold solubility and speciation in hydrothermal solutions have highlighted the importance of supercritical conditions and sulphur species in the deposition of gold in natural environments. Gold solubility in supercritical brines is far higher than previously supposed while interest in the high content of carbon dioxide in the mineralizing fluids is growing. 2,3 In recent years, also, there has been a tremendous amount of attention paid in analytical chemistry and in industry, to the area of supercritical fluid extraction (SFE) of organic and metallic species. 4 This interest has been fuelled by the introduction of more stringent environmental control and the subsequent need for cleaner solvents and processes to replace established ones. Carbon dioxide is the substance of choice for SFE because of its moderate critical parameters (Tc = 31oC, Pc = 73atm), inertness and availability in pure form. It is an excellent extraction medium for non-polar and moderately polar species, and with careful ligand design, it can be used for analytical and process scale metal extraction from solution and solid phases. In general, the dissolution of a metal in supercritical CO2 (sc-CO2) requires that the charge on the metal ion be neutralised on complexation by the ligand or through a form of ion pairing (analogous to the situation where metal ions are extracted into organic solvents, such as methyl isobutyl ketone or toluene). In this way, then, many chelating agents such as dithiocarbamates and hydroxamic acids have been utilised to extract metal ions such as Cu and Fe into sc- CO2, the process greatly enhanced by the use of fluorinated ligand derivatives. 5-7 In this review paper, we show that supercritical conditions and complexation with sulphur donor atoms, important in the natural deposition of gold, can form the basis of a clean, eco-friendly chemistry for gold extraction. Analytical scale extractions of gold from a variety of matrices can be conveniently used to assess the efficiency of any new proposed ligand.

Oct 1, 2003

By Mehmet F. Taner

"The East Sullivan Stock (ESS) is a small, composite felsic alkaline pluton of presumedlate Archean age in the Val d’Or mining district. Three main facies have been distinguished: mon-zonite sensu stricto, porphyritic monzonite, and green trachytic porphyry. This monzonitic group ofrocks is of relatively homogeneous composition with high abundances of Na2O, K2O, Ba, Sr, Rb, Zr,Mo and LREE. The alkaline ESS is distinguished from other igneous units in the Val d’Or miningdistrict, such as the Bourlamaque Batholith, by relatively high concentrations of Ba, Sr, Rb, Mo, Cuand Au. The ESS hosts many base (Cu, Mo) and precious (Au) metal occurrences, including: (1)porphyry style Cu-Au-Mo disseminated sulfde deposits, (2) Cu-Au deposits in volcanic rocks near the ESS contact, and (3) pyritic gold mineralization in east-west trending shear zones. The ESS is well defined by concentrical zoning on the aeromagnetic vertical gradient color map, and displays four linear trends, which are assumed to be structural lineaments, at 035°-055°, 320°-300°, east-west, and north-south. The main mineral occurrences related to the stock display a preferred spatial association with the east-west linear magnetic trends.The ESS is preferentially located along a major structure and was emplaced late in the evolutionof the Abitibi subprovince like other felsic alkaline plutons. This stock is similar to late-tectonic min-eralized felsic alkaline intrusions of the Kirkland Lake and Larder Lake mining districts in Ontario, and to the Allard stock in the U.S.A. which is associated with gold and base metal mineralization. Similarities also exist with younger alkaline plutons associated with Cu-Mo-Au porphyry deposits in the Canadian Cordillera, which formed in tensional tectonic environments. The felsic alkaline magmamay have formed by partial melting of deeply buried supracrustal rocks, concomitant with the development of deep fractures such as the Cadillac Fault. In such an environment, hydrothermal solutions carrying remobilized metals from deep supracrustal rocks may have deposited gold and base metals in structural traps. Plutons similar to the ESS should be good targets for mineral exploration. Copyright © 1996 Canadian Institute of Mining, Metallurgy and Petroleum."

Jan 1, 1996

By Bradley Stoughton

It is very easy to reduce iron ore at a temperature well below its melting point and produce a more-or-less-pure metal which can be used directly for implements, tools, or machines. This simplicity has been the cause of much money loss by persons who were so satisfied with the successful operation of a process that they paid all too little attention to the commercial aspects of it. How easy a direct process is may be gleaned from the fact that it was practised with some -success by primitive man, and has been in almost continuous operation in one form or another for a period of probably 4,000 years. The production of steel in ton lots, beginning about 1860, brought a new phase into the economic situation, which, however, had been already greatly modified in 1784 by Henry Cort's invention of purifying pig iron. Direct processes survived both of these revolutions, under special geographical conditions, even up to the last few years of the nineteenth century, but ceased to have any general use as the basis of supply for structural, machine, or tool industries even in countries which could have manufactured iron by a direct process, but, instead, imported the product of established iron and steel processes. And this is still the situation today, notwithstanding the invention of an incredible number of 'new' processes since 1900, most of which are abandoned, and only survived as along as their financial backers were willing and able to Jose money. Probably none of these processes failed to work pretty well, and all seemed to show a handsome profit on paper.

Jan 1, 1930

By T. S. Li, D. Ilievski, I. Livk

Micromixing of the fluid and the particulate phases in a continuous gibbsite precipitator was investigated for three different micromixing states, namely maximum mixedness (MM), complete segregation (CS), and maximum mixedness of the fluid but complete segregation of the particulates (MMF-CSP). The influence of the micromixing on continuous precipitation of gibbsite was studied at different precipitation conditions via simulation. Three different cases were considered with respect to the precipitation kinetics: (1) gibbsite secondary nucleation is favoured with slow crystal growth and agglomeration rates; (2) gibbsite crystal agglomeration and growth are dominant mechanisms with secondary nucleation suppressed; and (3) gibbsite crystal growth is the only relevant phenomenon. Simulation results for the cases (1) and (3) showed that the crystalline products for both the MM and MMF-CSP micromixing states were very similar, but the product obtained from the CS micromixing state was considerably different. This indicates that at those precipitation conditions the fluid micomixing has the dominant effect on the product properties, and the particulates micromixing effect is insignificant. However, when operated under the conditions of fast crystal growth and agglomeration kinetics, i.e. case (2), both the fluid and the particulates micromixing were found to affect the precipitation process, resulting in a significantly different product. Computational Analysis in Hydrometallurgy 35th Annual Hydrometallurgy Meeting held in conjunction with the 44th Annual Conference of Metallurgists ofCIM Calgary, Alberta, Canada Edited by

Jan 1, 2005

By Haruka Takeura, Tomoaki Murata, Kazunari Yoshida, Masato Adachi

"Pure magnesium is a material with high functionality, however, the cold drawing of this material is very difficult, that is why, until this day there are no optimal cold drawing conditions. Furthermore, cold drawing of pure magnesium wire shows a problem with internal defects that occurs under certain conditions. In this research, the aim is the suppression of internal defects, and final target is to create the optimal cold drawing conditions for pure magnesium wires. The first step is the investigation of the drawing limit by using 250°Cannealed wire. As a result, reduction of 10% per pass was chosen for stable wire drawing. However, in this case, it was found that internal defects occurred at total reduction of over 45% during drawing. Investigation of intermediate annealing conditions that can suppress internal defects, and influence on internal defect that the die half angle and reduction per pass. As a result, it was found that the drawing condition capable of suppressing internal defects most efficiently was 13% reduction drawing by using under 6°half angle die. Consequently, it’s possible to manufacture a cold fine drawn pure magnesium wire of 100µm, without defects in the center of the wire and hindering its mechanical properties.INTRODUCTIONMagnesium is a light and high functionality material that has high vibration absorbency, heat dissipation, electromagnetic wave-shielding and recycling efficiency (Conruy, 1989). However, proper cold wire drawing conditions haven’t been established, that is why warm or hot processing is commonly used (Oishi, Mori, &Kawabe, 2005). As a result, strength improvement of the wires is not possible, that is why the production of medical tools is disregarded. If it was possible to cold draw magnesium wires, the applications for material products would expand. Further, in wire drawing such difficult processing material, if appropriate processing conditions are not selected, defects will be generated inside the drawn wire."

Jan 1, 2017

By Perry L. Christian

"Mana/ta Coal Ltd. 's Costello Mine, located seven kilometres east of Estevan, Saskatchewan, has been operating at the present location since 1960. During the past twenty-three years, annual production of lignite coal has averaged 590 000 tonnes. The coal is used for power generation and for industrial and domestic use. Markets, operating techniques, facilities in place and reclamation are discussed. Introduction The Costello Mine (formerly the Klimax Mine) is located in southeastern Saskatchewan, approximately 210 kilometres southeast of Regina and 5 kilometres from the United States' border, as shown in Figure 1. The present mine, 7 kilometres east of the city of Estevan, has been operating since 1960. The history, however, of the Costello Mine and of the Estevan Coalfield dates from the initial settling of the area in the 1880s. Mining initially consisted of burrowing into the side of the Souris River Valley or other hillsides where the coal seam was exposed. Eventually, slopes were put down in the Estevan/Bienfait area and vigorous underground activity existed. In the late 1920s surface strip mining was introduced. The use of strip mining progressed to the point where it completely replaced underground mining in the 1950s and it is the only method in use today. During the past 23 years annual production has averaged 590 000 tonnes. The lowest production was in 1960 when the mine was starting up at 167 000 tonnes and the highest production was in 1977 when production was 1 509 000 tonnes. The Costello Mine controls approximately 11 400 hectares of mineral rights in the Estevan area. This is made up of 4 900 hectares of freehold coal and 6 500 hectares of leases. The area forms a large, irregular shaped configuration. Most holdings are contiguous and adjacent. The mine also owns some 8 400 hectares of surface rights. The lands under the Costello Mine's surface rights control, which are not being used in the mining operation, are leased to local farmers and ranchers. This ensures that the land is used to its full potential, both before and after mining."

Jan 1, 1985

By Bruce W. Smith

Non-contacting, radioisotope density and level gauges are discussed. The characteristics of the more commonly used isotopes, the techniques of detection and the methods of presenting information are reviewed. The gauge parameters of accuracy, response time and long-term stability are tabulated with reference to calibration techniques and operating requirements. Automatic control systems, both pneumatic and electrical, are used in conjunction with density gauges on filter feeds, and in thickener underflow and heavy media processes. These systems are described. Procedures for installation, start-up and operator training are outlined, along with considerations of preventative maintenance and service requirements. Typical gauge system costs, including capital expenditure, installation, start-up and service, are presented, wherever possible, in order to provide a basis of comparison with more conventional systems.

Jan 1, 1964

By M. F. Almeida

"Due to the randomness of all factors influencing the sintering operation, a two-stepped procedure is proposed to find the best way of using stocked fines at a plant producing Fe-Mn alloys for the steelmaking industry. The approach is based on the following: (1) predict the result of the sintering operation by establishing the best multilinear regression model using some of the characteristics of the loaded material; and (2) find the best solution under a minimizing cost criteria by solving a linear optimization problem using the regression equation plus constraints on the feed and product. IntroductionSome tests carried out using 20% to 30% of sinter in the material loaded into a 60 000 KVA Tysland-Hole electric furnace producing Fe-Mn alloys for the steelmaking industry indicated: (1) a meaningful decrease in the off-gas temperature and, consequently, a better energy use due to the material higher porosity; (2) more uniform heat distribution as a consequence of the electrode reaction zone enlargement; (3) an improved furnace control resulting in a smoother operation; and (4) a decrease in gas production facilitating the off-gas treatment. For some years, this plant used only the coarse fraction of the Mn ores, thus stocking all the received and own-generated fine particles. In view of the mentioned results, a strategy for increasing the use of stocked fines was formulated, including a step where it was necessary to decide which components and respective quantities should be used in the blends to be sintered (Almeida, 1984).It is well known that several factors affect productivity and energy consumption in sinter production, also influencing the product quality. Raw materials characteristics, namely chemical and size composition, affect permeability to gases and may or may not allow a deeper bed. In general, finer ores decrease permeability, increasing electricity consumption by fans, but due to their higher specific surface area, react more completely with other components in the mixture. For coke granulometry, a compromise must be obtained in order not to burn it too quickly nor to widen the flame front, therefore decreasing productivity. Decreasing coke in the blend also acts in sinter bonding, decreasing its consistency and increasing crushing and return fines. Moisture addition also influences components mixing, pre-agglomeration, bed permeability and, consequently, sintering productivity. Therefore, optimum conditions must be established for both a given sintering plant and the components in the feed (Dawson, 1993)."

Jan 1, 1998

By F. Baerhold

Recycling of hydrochloric acid from the pickling of mild steel using pyrohydrolysis is a state-of-the-art technology. Recent developments have focused on the production of a high value iron oxide by-product, where the chemical purity and physical properties are the main issues. New processing routes, especially for TiO2 and Ni production, use leaching operations with hydrochloric acid. The feasibility of those processes depends on the availability of an economic and reliable process for the recovery of the acid. Depending on the level and type of impurities and the required specification of the by-product, pyrohydrolysis in a fluid bed or in a spray roast reactor can be the ideal solution. In stainless steel annealing and pickling lines, a mixture of nitric and hydrofluoric acids is used to remove the scale from the surface after heat treatment. Nitrate emissions from the pickling and the rinsing processes have to be avoided because of more stringent environmental regulations. An annealing and pickling line that is totally wastewater-free was developed, where not only the nitric/hydrofluoric acid but also the rinse water, is completely recycled. New developments to increase the HNO3-recovery rate and to obtain a metal oxide by-product that is easier to recycle are presented.

Jan 1, 2006

By Saikat Chatterjee, Xintong (Brett) Liu, Kinnor Chattopadhyay

Magnesia carbon bricks are commonly used in BOFs and are generally pre-heated before the BOF goes into service. Owing to very stringent emission regulations, the BOF pre-heating process need to be controlled and optimized so that, the emission standards are met. One of the major concerns in organic emissions are its stringent limits on emission rates and total volatile emissions. In the present work, an attempt has been made to integrate CFD and Thermodynamic models to predict the emission rate of volatile organics during the pre-heating process. A one dimensional heat transfer model was developed using visual basic and then integrated with thermodynamics calculations using FactSage 6.4. The parameters that affected organic emissions were the pre heating procedure, gas composition of the burner, heating rate and type of the burner. Typical composition of MgO-C bricks and binder materials were obtained from literature and vendor data sheets. Chemical reactions between organic materials, refractory and burner gasses were considered. The model predictions indicated that certain burner conditions could destroy all organics before it exits the vessel while other conditions needed the use of an after burner at the mouth of the vessel. The model was also able to predict the organic emission rates based on the chosen pre-heating profile. This kind of predictive model will be very useful for the steel industry and enable them to justify permit limit applications and stick to the limits by fine tuning their pre-heating process.

Jan 1, 2015

By Iain Sommerville, Hugh Mountford, Dawid D. Smith, Claude Dube, Brett Hixson

JW Aluminum use lean and Six Sigma techniques to continuously improve their target of reliable, repeatable and reproducible (3R) manufacturing. Six Sigma’s second stage gate, known as "Measure" involves identification and qualifying appropriate measuring systems. Metal quality (inclusions) are known in the industry to be an important element in 3R casting. The measurement of inclusions at JW Aluminum historically depended on outside vendors. In order to establish real time inclusion measurement ability within JW Aluminum, inclusion measurement systems in the marketplace were investigated. The qualification of a MetalVision MV20/20 ultrasonic inclusion analyzer are discussed as well as the subsequent application of the system in melting and casting improvement projects.

Jan 1, 2015

By H. Zhu, Q. Jiang

The leaching kinetics of iron during the atmospheric direct leaching (ADL) of marmatite concentrate was studied under the following conditions: reaction temperature of 343-383 K, slurry pressure of 0.3-0.7 MPa, particle size of (-74 ?m, +63 ?m), (-63 ?m, +44 ?m), (100%-44 ?m). The statistical effects of reaction temperature, total pressure and particle size of concentrate on the extraction and the leaching rate of iron were analyzed. The results show that reaction temperature is a significant factor while slurry pressure and particle size are not statistically meaningful with respect to the extraction or the leaching rate. The extraction of iron fits better to the mixed-controlled shrinking core model and the apparent activation energy was calculated to be 37.66 kJ/mol. The leaching of iron is mixed controlled by the interfacial chemical reaction and diffusion across the product layer.

Jan 1, 2014

By Sherwin F. Kelly

With the progressive exhaustion of ore deposits easily discovered by surface prospecting, the attention of scientists is being turned more and more to the employment of mechanical means for the location of ore bodies whose outcrops are not visible. The dip needle, the Eotvos Torsion balance, and various methods of electrical prospecting are illustrative of the modem tendency. Interest in the possibility of applying electricity to the solution of many of the prospector's problems dates much farther back than is usually realized. The first person to notice an abnormal intensity of electrical activity in the region of certain ore bodies was an Englishman, R. W. Fox, who experimented on the Cornwall copper and tin veins about 1830. Dr. Barus, in the United States, carried the early experiments a step further in his work on the deposits of Eureka, Nevada, about 1880. He made the very definite suggestion that the phenomena noticed would be of material aid to the prospector. Not until Professor Schlumberger, of the Ecole des Mines, Paris, took up the matter, shortly before the war, was any definite effort made to put electrical prospecting on a commercial basis. His work resulted in the establishment of sound principles and practicable field technique, for two distinct methods of prospecting.

Jan 1, 1924

By O. P. Garg

Based on improved methods of collection and analysis of geotechnical data, slope angles have been steepened in some mines of the Iron Ore Company of Canada at Schefferville, Quebec. This paper describes the slope design case history for Fleming NO.3 mine and illustrates the application of modern techniques. The new design has resulted in significant financial savings due to a reduction in required waste stripping.

Jan 1, 1978

By S. R. Stopic

The EU-financed INTREAT Project (Integrated treatment of industrial wastes to¬wards prevention of regional water resources contamination) addresses the environmental pollution associated with solid and liquid wastes/effluents produced by complex sulphide ore mining and metallurgical activities. The results concerning the electrolytic recovery of cop¬per from effluents formed after mixing of streams from Copper Refining, Precious Metals Plant and Electrolyte Regeneration in the Balkan Area will be shown. The waste water is characterized by low pH values and high contents of heavy metals, such as Cu, Ni, Bi, As, Sb. The majority of these waste water flow untreated into the natural water streams and through the network of existing rivers, which end up in the river Danube. The influence of current density and flow rate on the deposition rate, the quality of copper and the process efficiency will be presented. The full continuous process is based on cells with rotating disc cathodes and represents a pre-treatment step before common neutralisation in a cascade line

Jan 1, 2007

By C. Joulian, A. G. Guézennec, A. Chmielarz, Y. Ménard, M. Hanke, P. d’Hugues

"The copper concentrate used in this study is produced by flotation of a black shale organic rich ore. This resource is a carbonate-rich, polymineral concentrate. In the last 5-6 years, ore characteristics changed and the concentrate grades degraded. This study evaluated bioleaching of the concentrate in stirred tank reactors as an alternative to the pyrometallurgical technology that is currently applied, and which may no longer be feasible in future given the concentrate chemistry.The first part of the study focused on testing non-traditional operating conditions during continuous bioleaching experiments: high solids concentration (> 20% solids), reduced agitation and aeration rates. For the same residence time, bioleaching performance at high solids loading (25%) was the same as that reached during previous bioleaching experiments at 15% solids. No mixing or microbial issues were encountered. The bacterial consortium used in the experiments demonstrated a high copper tolerance.The second part of the study was devoted to technology development for metal recovery from copper bearing solutions obtained during bioleaching experiments. Due to the high copper concentration of the leachate, solvent extraction prior to electrowinning was not necessary. After iron removal, high quality copper cathodes (morphology and composition) were obtained from the PLS by electrowinning."

Jan 1, 2014

By Tony Breuer

Can international development NGOs and the mining industry find common ground and work together in the Third World? The Canadian Hunger Foundation/PARTNERS in Rural Development (CHF-PARTNERS) has, over the past forty years, implemented more than 800 rural community development projects in some 38 countries of Africa, Asia, and the Americas. Working with or for the Canadian mining industry offers both opportunities and risks. We can help a mining company ensure that the workers, their families and communities share adequately in the economic and social rewards from a mining operation in their area. We can contribute to the provision of sustainable livelihoods when an operation winds down. The company?s reputation as a good corporate citizen can be enhanced. On the other hand, mining companies and NGOs have generally very different values and missions. The risk of misunderstandings from conflicting motives and work practices is correspondingly high. Both partners must state their values and expectations clearly at the start of collaboration. The NGO must ensure that the company abides by acceptable ethical standards. It must not directly or indirectly subsidize a private company from its charitable donations. The mining company must satisfy itself that the NGO has the capacity, resources and experience to produce the results expected.

May 1, 2001