Search Documents

By A. Ghahreman, M. Oliazadeh

"Heap leaching is an attractive process for low grade deposits where the metal content of ore does not justify the high cost of milling and agitated leaching. In general, the heap leaching capital cost is low, construction is rapid, and production costs are low. The primary disadvantage of heap leaching is low recoveries (typically 65% of agitated leach recovery); thus, recovery improvements could convert more lower-grade deposits into minable reserves. This will also allow to process primary sulfide ores and result in a dramatic expansion of the technology, as ~80% of total ore types are sulfidic in nature. The old gold operations tailings are another massive source of low-grade gold material that can be retreated by the heap leach process. The major parameters affecting the recovery rates are ore characteristics (mineralogy, particles size of metal and host minerals, ore permeability), and operational conditions (segregation of ore, compaction, leach cycle time, lift height, and solution application rates). The design of a percolation leach process is based on a limited number of coarse ore bottle roll and/or column tests under ideal conditions. The economics of the projects and engineering design of the process facilities are developed based on the bench scale test work results and the application of the conventional engineering scale up factors. This paper will deal with the parameters affecting the HL efficiencies and focus on the potential improvement of gold heap leach recoveries. This would include design of heap leach operation and evaluation of processes such as fine crushing and bioleaching.INTRODUCTION Gold heap leaching is a hydrometallurgical process designed to treat amenable low-grade gold ores that contain typically 0.5 to 1.5 g/t gold (Marsden and House, 2006; Wong Wai Leong and Mujumdar, 2010). Ore is stacked by various types of equipment on an impermeable barrier, and a sodium cyanide solution is applied to the surface of the stacked ore. Gold, silver, and other metals contained in the ore are dissolved to various degrees by the cyanide application, as it percolates downward through the stack of the ore. The pregnant leach solution (PLS) is then collected at the bottom of the heap. The PLS is then sent to the gold recovery plant where the metals are extracted. The barren leach solution (BLS) is then reapplied to the top of the pad. Ore is placed on a pad or previously leached lift by various means, including ramp conveyor belts, radial-arm and self-leveling stackers, and trucks. Once trucks are used to construct the pads, the pad can be compacted and hence the pad should be graded and ripped or scarified (roughened up) with wheeled or tracked equipment to produce shallow cuts to increase surface area exposure to the leachate."

Jan 1, 2019

By Pravin Mathur

"Praxair's CoJet® technology was introduced in 1997 to effectively inject chemical energy in electric arc furnaces. Coherent jets were invented as a revolutionary means of injecting oxygen and other gases into the EAF and into converters. Today, steel makers have widely accepted this concept in over 70 EAFs worldwide. Indeed, the whole industry has shifted to this new standard for chemical energy input in EAFs. CoJet® technology has also been implemented successfully in BOF converters.This paper will review the principles of coherent jets as applied to steelmaking. The key learnings garnered from several furnaces are also reviewed. In addition, while the CoJet® program has been widely accepted worldwide, based on steady feedback received from customers and the market place, several programs are underway in development and commercialization. These enhancements and new applications of CoJet® technology are also overviewed in the paper."

Jan 1, 2004

ABSTRACT Inco’s Iron Ore Recovery Plant was operated by Inco from 1955 to 1980 near Sudbury, Ontario. As exposures to specific nickel substances have been associated with adverse respiratory endpoints it is important to understand processes giving rise to such substances. This manuscript discusses the process and equipment, the propensity for aerosol formation, and operational procedures used by Inco in roasting a pyrrhotite concentrate, reducing the nickel in the formed oxide, leaching the nickel in ammoniacal solution, purifying the resulting solution, making green or black NiO, and producing iron oxide pellets. Industrial hygiene measurements are also reported.

Jan 1, 2013

By J. Cueto, M. Torres, J. Fernandez, J. Nuñez, C. Salgado, G. Zarate

Anglo American has used the extractant M 5640 in all the Divisions, which is an aldoxime modified with TXIB formulation, except in Los Bronces, where an aldoxime modified with tridecanol (TDA) formulation is used. It is a well-known fact that the aldoxime degrades while the modifier does not. With time the aldoxime/modifier ratio decreases significantly depending on the operating conditions of each plant. In order to evaluate the effect of this increasing modifier content in the organic of the plant, especially in the organic losses, a complete metallurgical test work program was started at laboratory and pilot plant scale. Results showed that the addition of aldoxime without modifier does not affect the chemical performance of the organic phase, but there is a significant decrease in the viscosity and density of the organic phase. Based on the results obtained in the metallurgical program, it was decided to run plant scale tests at both SX plants, Mantos Blancos and Mantoverde. In these tests, instead of adding the usual formulation of aldoxime modified with TXIB to maintain the organic inventory, CuPRO MEX™ 3406 which is an aldoxime without modifier is going to be added until the original aldoxime/modifier ratio is reached. The plant tests started in April 2013 at Mantos Blancos and in June 2013 at Mantoverde and will last 18 months. The results obtained at the laboratory and pilot plant scale, together with the preliminary plant test results, are discussed in this paper.

Jan 1, 2014

By J. C. White

"This paper was prepared for and presented at a lecture series on ""Materials Randling"" at McGill University. The development of trackless mining at Gaspe Copper Mines, Limited is described, showing the changes in mining method and the part played by the mobile equipment in the evolution of this highly mechanized underground operation. Comparisons of loading and hauling machines are given and an attempt is made to predict some possible future developments.INTRODUCTIONTHE PROPERTY OF GASPE COPPER MINES LIMITED is located in the Gaspe Peninsula of the Province of Quebec, 60 miles west of the village of Gaspe and 25 miles south of the St. Lawrence River. The original discovery of low-grade ore was made at Copper Mountain in 1921. Subsequent exploration revealed the richer Needle Mountain orebodies, and eventually in 1951 the decision was made by Noranda Mines to build the mining, concentrating and smelting complex (Figure 1). Construction and development of the mine was commenced in 1952 and production started in 1955."

Jan 1, 1968

By R. Matusewicz, A. Kaye

Ausmelt Top Submerged Lancing (TSL) Technology has gained widespread commercial acceptance in non-ferrous applications, including the processing of lead and zinc primary concentrates and secondary (post-consumer) materials. TSL is highly flexible and efficient, and is one of the few technologies which can process primary and secondary feeds, and use varying fuels, to deliver high recoveries and excellent environmental performance. With the recent high value of both lead and zinc, and an escalating awareness of the sustainable use of resources, focus on the processing of secondary feed material sources has surged. Ausmelt Technology has proven to be well suited to the economic recovery of values, with twenty-two (22) Ausmelt furnaces processing lead and zinc bearing feed sources now in operation, under design or construction. This paper describes Ausmelt's progress in the fields of lead and zinc processing, and developments in new processing areas such as EAF dust processing and linking to innovative hydrometallurgical technology. Ausmelt has recently committed to the Whyalla Zinc project as the owner/operator of a facility for the treatment of zinc bearing secondary feeds. This project is due for start up in the first quarter of 2008.

Jan 1, 2008

By Adam Jordens

Along with gravity separation and froth flotation, magnetic separation is one of the most common techniques for separating minerals. Minerals are separated by a magnetic force that is dependent on a combination of the applied magnetic field, the magnetic field gradient and the magnetic properties of the minerals themselves. Minerals may be classified as diamagnetic, paramagnetic or ferromagnetic based on the way they interact in a magnetic field. The magnetic susceptibility of a material may be determined by using a vibrating sample magnetometer to determine the magnetic moment of the material in an applied magnetic field and then converting this measured moment into the material?s magnetic susceptibility. In the case of rare earth minerals, magnetic separation is commonly used to remove ferromagnetic iron-bearing gangue minerals and to concentrate paramagnetic valuable minerals such as monazite and xenotime. These magnetic separation steps are frequently preceded by a gravity separation step as many iron oxides and rare earth minerals have specific gravities that are much larger than those of typical gangue minerals. By varying the magnetic field intensity it may be possible to use magnetic separation to selectively separate the paramagnetic and ferromagnetic minerals that report to the concentrate after gravity separation. Test work on a Canadian rare earth ore has shown that a gravity concentration step using a Knelson concentrator was able to selectively concentrate heavy magnetic minerals as evidenced by increased recoveries, relative to the Knelson tailings and fresh feed, after processing through a wet variable intensity magnetic separator. Mass pull to the Knelson concentrate was 4.5 % and the magnetic recovery of this concentrate, at 0.94 T, was approximately 40 % higher than the magnetic recovery from the Knelson tailings (70 % versus 30 %). The products of the wet high intensity magnetic separation were also analysed using a vibrating sample magnetometer to determine the magnetic susceptibilities of the various concentrate and tailings products.

Aug 1, 2013

By V. L. Eardley-Wilmot

Diatomite as prepared for the market is a fluffy, white powder, remarkably light in weight-it weighs only 10 to 15 pounds per cubic foot, or one-tenth as much as sand. Being extremely porous and inert, it is in large and increasing demand for insulation and filtration purposes, as general filler, and for many other uses. Structure Structurally, diatomite is quite different from any other known commercial material. It is composed of myriads of microscopically small, siliceous shells of diatoms which belong to a group of flowerless aquatic plants called algae. When these plants die, the siliceous remains sink to the bottom of the water and form beds of diatomite. Over 8,000 species of diatoms are known, named, and tabulated. The intricate scroll-work and patterns on many of these are one of the marvels of nature, and yet so small are they that from 40 to 70 million separate diatoms may be contained in one cubic inch of material. However, the size and shape of these diatoms, which vary greatly (compare Figures 5 and 6), have an important bearing on the commercial use of the diatomite. The diatoms in the majority of the known deposits are so typical of that deposit that, after a micro-examination, an expert can usually tell not only from what part of the world, but also from what particular deposit, the sample has come.

Jan 1, 1931

By A. Zrimsek, G. Vingas, R. Wolke

IN 1952, prompted by the great demand of the Canadian drilling and foundry industries for sodium bentonite, the Geological Department of Magnet Cove Barium Corporation, Limited began an extensive search for bentonite deposits throughout western Canada. Their efforts were rewarded in 1958, when substantial deposits of high quality material were found approximately 100 miles southeast of Edmonton, Alberta. The bentonite material, a part of the Edmonton formation in the Upper Cretaceous, is located approximately nine miles south of the town of Rosalind. The land where the bentonite lies has in places .been eroded by stream and glacial action to form a wide gully, convenient for strip mining methods (see Figure 1). The bentonite bed is almost flat-lying, dipping to the southwest at approximately 12 feet per mile. The main bed is 8 to. 10 feet thick and is covered with 15 to 25 feet of overburden. Before stripping, the area is drilled and sampled to evaluate the quantity and quality of the bentonite.

Jan 1, 1962

By A. Hayatdavoudi, K. G. Sawant, F. Boukadi

"In this work, we found that contact between shale and water results in development of micro fractures. Based on results of experiments on Pierre shale, we conclude that appearance of micro fractures begin with saturation of capillaries, ionic and diffusive transport of water into the shale clays and once capillaries are saturated, the cause of micro fracture propagation is the conversion of ionic activity/exchange to excess pressure that did not exist before fracking. Based on these findings, the spread of micro fractures appear to be a time-dependent phenomenon which has not been addressed in the existing macro/micro fracture models.INTRODUCTIONShale has often been involved as a hazard in drilling operations. This hazard can be defined as “destabilization” of shale. When contacted with water-based drilling fluids, some shales readily swell and sometimes, cause the wellbore to cave-in, slough, wash-out, close, and pack-off, impeding the drilling by sticking the drill-pipe. However, once drilling reaches the desired depth or length, the casing is set, cemented, and perforated, and then actually we wish to initiate fractures and destabilize the shale formation, using hydraulic fracturing.Clays constitute a major portion of minerals in shale. These clays contain a large amount of free energy which is the main factor for “slick” water adsorption/absorption. In fact, the reason for using “surfactants” in hydraulic fracturing fluids is to make the penetration of the fluid into the capillaries much easier, thus water meets with less resistance to enter the small capillaries. Also, the result of high capillary suction pressure is due to small Angstrom size capillaries, smaller pores and presence of ions and hydrateable metal atoms. The free energy is thus, related to all the above mentioned and other affects. Capillary pressure, osmotic pressure and other pressures are responsible for creating the micro-fractures in shale, thus, increasing the network of micro-fractures which leads to more gas production. The objective of this study is to evaluate the pressures of the individual ions which are released by the diffusing “slick” water into shale. These pressures would be added to the above mentioned capillary pressure, osmotic pressure, bacterially-induced pressures, chemically-induced reaction pressure, pressure due to exchangeable ion-transport, pressure due to release of free energy of solvation and eventually to the pore pressure as suggested by Terzaghi’s equation."

Jan 1, 2015

By J. Lipp

The lion share of lithium produced globally originates from South American salars. The standard operation for lithium production utilizes an array of evaporation ponds. This process consume vast areas and is either very slow when relying on solar evaporation - roughly 18 months of residence time; or with very high energy consumption since over 90% of initial water volume needs to be evaporated. A new technology, based on solvent extraction was developed. Results indicate a distribution coefficient up to 30, and selectivity greater than 1,000 towards Na extraction. The loaded solvent is stripped using a strong mineral acid, and the product solution is the lithium derivative of that stripping acid. Utilization of this new LiSXTM technology results in reducing the area needed for a commercial plant as well as reduces the residence time. In addition applying different stripping acids can diversify the product line of such facility.

Jan 1, 2014

By Dharmendr Kumar, Pradip, Beena Rai, Venugopal Tammishetti

"Due to rapid depletion of high grade Indian iron ores, there is a need to utilize low grade fines and slimes. However, these fines and slimes, in their current form, cannot be utilized in steel making due to their high alumina (6-10%) contents. Several beneficiation strategies such as gravity separation, magnetic separation, flotation and selective flocculation are currently being explored for the upgradation of low grade fines and slimes. In our previous work density functional theory simulations were employed to come up with selective flocculants for beneficiation of iron ore slimes. Our simulation results suggested that starch and guar gum are more selective towards iron minerals than other minerals present in the sample. Grinding of iron ore fines becomes necessary in some cases to achieve adequate liberation for removing alumina impurities in Indian iron ores. We have thus investigated effect of grinding of iron ore fines on its selective flocculation-separation.In the present work, we have taken natural iron ore fines from one of the Indian iron ore mines and ground it to -400 mesh (<37 microns) in dry and wet conditions. X-ray diffraction study confirmed the presence of minerals hematite, goethite, gibbsite and kaolinite in the sample. The fine ground samples were used in selective dispersion-flocculation study with corn starch and guar gum flocculants. It is interesting to note that even though the dry and wet ground samples possess almost similar particle size distributions, significant differences were observed in yield and grades of the concentrates thus produced. These differences may be arising due to the coating of alumina containing minerals on iron minerals. We have also studied the effect of addition of dispersant while grinding. Our study suggests that grinding conditions determine the efficiency of the separation process."

Jan 1, 2016

By E. A. Roux

As the first mine-to-metal zinc operation utilising atmospheric leaching, solvent extraction and electrowinning, Skorpion Zinc faces unique challenges and opportunities. One of these challenges is found in the solvent extraction circuit, in which di-ethylhexyl phosphoric acid (D2EHPA) is used as the organic extractant. Although D2EHPA is an excellent extractant for zinc, it suffers from the co-extraction of ferric iron, which is produced during leaching and by the corrosion of the grinding media. This situation is partially mitigated by iron precipitation in the neutralisation step prior to solvent extraction. Unfortunately, some ferric iron still reports to the solvent extraction process. This leads to a slow build up of iron in the organic phase. Chemical stripping is used to maintain the Fe concentration at an acceptable level. In this paper, the efficiency of the iron removal process is discussed.

Jan 1, 2006

By W. G. Worcester

Generally speaking, the term &apos;clay&apos; appears to convey but little to the average layman other than of a sticky substance to be rigidly avoided when making a cross-country drive in the family ark- especially so if the chains have been left behind. On the other hand, the technical ceramic; engineer, though his chariot be bogged in the self-same mud-holes, will, more than likely, be planning on ways and means for the conversion of the troublesome gumbo into paving bricks over which all might ride with pleasure and security. However, to come to the point, the term &apos;clay&apos; bears much the same relation to the ceramic world that the term &apos;ore&apos; does to the metallurgical; in other words, as there are many kinds of ores, so also are there many kinds of clays, and it therefore becomes necessary to classify and sub-classify them previous to a discussion of their relative values and importance. Hence, a brief digression will be made from the main topic of this paper in order to enumerate and classify a number of the more important types of clays. By so doing, the relative position of Saskatchewan clays, later discussed, will be better understood.

Jan 1, 1929

By J. B. Mawdsley

Introduction The writer was instructed to visit the Chibougamau region during the field season of 1927 and report on the mineral discoveries that had been made there since 1911. lt was deemed advisable to obtain detailed information regarding the rocks underlying the area in the vicinity of these recent discoveries. Accordingly an area 60 square miles in extent was mapped. The outcrops were studied along the water courses and along bush traverses spaced at half-mile intervals between these water courses. The completion of the rest of the summer&apos;s programme allowed only three weeks for this work. lt is from this small, mapped area, and this necessarily cursory survey, that the material for this paper was obtained. Location And Means Of Access The name Chibougamau district is applied loosely to an ill-defined area of about 1,000 square miles lying mostly north and west of Chibougamau lake in the Province of Quebec. The lake is approximately half way between lake St. John and James bay. It lies 150 miles north of the Canadian National railway and 40 miles south of Mistassini?lake.

Jan 1, 1928

By S. Power Warren

Introduction It is generally conceded by flotation men that the condition at the surface of a particle of mineral or gangue is the most important factor controlling its behaviour in a flotation cell. Much research work has been devoted to the study of the forces that are active at the surface of the particle and of the effect of the surrounding solution upon these forces. Study of the relationship between mineral or gangue particles and gas bubbles indicates that, in the main at least, flotation is a physical phenomenon. The important factor, that of mineral-gas-bubble attachment, is unquestionably physical; however, modifications may be effected by chemical means, whereby the nature either of the surface of the particle or of the surrounding solution may be changed. For example, the coating of lead sulphide that forms on lead-carbonate ore particles when sodium sulphide is added greatly aids the flotation of the carbonate particles. Without going into the question as to why, under certain surface conditions, mineral particles will attach themselves to gas bubbles whereas under other conditions they will remain unaffected, it may be stated that there are three general conditions in a flotation pulp which control the attachment of the particle and the gas bubble.

Jan 1, 1933

By A. H. Anderson

THE travelling grate coking process was developed by Shawinigan Chemicals, Limited, at their Shawinigan Falls plant. The first production unit went into operation a month prior to the outbreak of the war. Since then a substantial part of the coke used in the manufacture of calcium carbide has been produced by this process. In the following will be given a short account of the development work, a description of the process and the equipment, a discussion of the properties of the coke, the economics of the process and its future possibilities. EXPERIMENTAL WORK The carbide industry is a large consumer of coke, one ton of commercial carbide requiring for its production 1,200 lb. This coke must meet certain specifications in order to be acceptable. It should have a low ash content, preferably below 8 per cent, and the sulphur and phosphorus content must not be above specified limits. The size of the coke is also important. If it is too large it has to be crushed before it can be used in the furnaces, and if it is too fine it may have to be screened and briquetted. In addition, it must be dry. Although it was generally possible to purchase coke, including petroleum coke, and coke fines, in the quantities required, it became increasingly more difficult as time went on to obtain coke of a suitable quality at an attractive price. It was therefore natural for us to look to coal carbonization as a means of basing the supply of the fundamental raw material for carbide manufacture on something more solid than the shifting conditions of the coke market.

Jan 1, 1944

By J. D. Wilkins

"Ore outcrops were first discovered in the area in 1911. Following various periods of exploration by private interests and Cominco Limited, the Coast Copper Company, Limited property was brought into production in August 1962. Subsequently, Cominco explored the adjacent Quatsino Gold Mines property and is currently developing, and producing from, what is now known as the Benson Lake Mine.The Benson Lake Mine was developed using a conveyor-equipped decline and trackless LHD equipment. The operation produces 800 tons per day of copper-iron ore, copper being the main product. Copper and iron concentrates are trucked 25 miles to storage and shiploading facilities near Port McNeill to await shipment to Japan."

Jan 1, 1971

By R. L. Bruening, L. Navarro, Izatt. S. R., R. Adiga, R. M. Izatt, N. E. Izatt, A. Sharma, N. R. Patel, B. V. Rao

Bismuth is a notorious contaminant in the electrolytic refining of Cu that can cause cathodes to fail to meet ASTM International standards and not be suitable for use in Cu rod and other downstream products. Bismuth can significantly decrease electrical conductivity, decrease the mechanical strength of the annealed wire, retard recrystallization, and sometimes induce hot shortness during the hot rolling process in the production of rod. As a result, the control of Bi in the refinery tankhouse must be carefully managed. This paper describes how SuperLig® Molecular Recognition Technology (MRT) is being used for Bi removal at the Birla Copper Dahej Copper refinery. The operation of the SuperLig® MRT Bi removal plant is described and data on Bi removal efficiency are presented. INTRODUCTION Hindalco’s Cu division, Birla Copper, operates one of the largest Cu refineries in the world at Dahej, Gujarat; India. The main feed for this refinery is produced at the company’s smelter. Due to its massive production capacity, this operation mainly relies on imported Cu concentrates resulting in a variety of metals being carried out as impurities in the Cu anodes because pyrometallurgical technologies alone are not enough to remove them to the extent required. Metal impurities found in Cu ores include Fe, Zn, As, Pb, Bi, and Sb. During electrorefining, less noble metals dissolve in the electrolyte gradually increasing their concentrations creating the need for electrolyte control mechanisms that remove these impurities with varying degrees of success (Wang, 2004; Navarro et al., 2013.) Bismuth is one of the most significant impurities in a Cu refinery because it has the lowest ASTM product specification. This situation is critical because the Bi potential is very close to that of Cu making it possible to plate in the Cu cathode directly. Also, Bi can precipitate at high concentrations causing floating slimes and reduction of current efficiency (Ballinas, San Miguel, Munoz, & Gyves, 2003). Production of high purity cathodes from feed stock containing a diverse range of metal impurities becomes a major challenge in the refining of Cu (Izatt et al., 2015). In this work, the purification strategy followed by Birla Copper for the removal of Bi using a separation process based on MRT is presented, outlining the loading and stripping performance of SuperLig®83 and the benefits of using MRT over other lower selectivity methods where hazardous materials are produced instead of high purity products.

Jan 1, 2019

During heap leaching of secondary copper sulphide ores operated at low heap temperatures and high levels of leach solution salinity, copper recovery is usually unsatisfactory, due to a slow chemical and bacteriological leaching of the covellite minerals either formed from leaching of chalcocite or naturally occurring in ores. A laboratory test program was conducted to investigate the effect of leach solution temperature in the range of 20 to 50°C on copper extraction during stirred reactor, bottle roll, and short column leaching of fresh or heap leached secondary copper sulphide ores. It was demonstrated that increasing heap temperature is an effective approach for improving recovery of copper from secondary copper sulphide ores. A review of the technologies available for heating heap leach solution or decreasing solution salinity to improve copper recovery from secondary sulphide ore indicates that an integration of copper concentrate pressure leaching with heap leaching is potentially a cost-effective approach. A copper flotation concentrate sample was tested through pressure oxidation with the use of heap leach solutions of varying strengths for the repulping of the concentrate in order to examine its effect on pressure oxidation performance. The test results indicate that use of heap leach solution of high salinity in the pressure oxidation process does not cause a negative impact on the process performance for copper extraction, sulphide oxidation, and recovery of gold (if present) from pressure leach residue, and has additional advantages of removing the bacterially inhibitory aluminum from heap leach solution and generating more acid and ferric iron in the pregnant leach solution. A flowsheet configuration for full integration of the copper concentrate pressure oxidation with heap leaching of secondary copper sulphide ore is proposed and discussed.

Jan 1, 2014