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By James Y. Oldshue

"Very seldom is it possible when contacting a gas with a slurry to measure the dissolved gas concentration in the slurry, and even were it possible, seldom are equilibrium data available with a suitable Henry’s law constant.In general, by assuming a reasonable value for the dissolved gas concentration in the slurry and a corresponding equilibrium gas partial pressure P*, Kga values can be calculated for the pilot plant and scaled up. Then, with the same P* value at various reaction conditions, a mixer can be designed which is quite satisfactory, having a reasonable design factor for full-scale performance.We will take as an example a slurry of a known solids composition and use a continuous 4 tank system. By assuming a percentage saturation of the dissolved gas in the first tank, the dissolved gas concentration can be obtained in the other three tanks. It usually is possible to measure the off-gas composition in each of the 4 tanks. If the top of the tanks is connected in the form of a multi-compartmented horizontal autoclave, then a modified top off-gas composition in each compartment must be used."

Jan 1, 2003

By Jonas Addai-Mensah

Despite the fact that nickel (Ni) laterites accounts for about 60 % of the world?s nickel mineralization, commercial processing of complex, low grade Ni laterite ores by conventional beneficiation (e.g. magnetic, electrostatic and flotation separation) still presents intractable challenges, particularly in heap leaching. Invariably, low grade laterite ores require aggressive hydrometallurgical techniques (e.g., highly acidic lixiviant leaching at ambient or elevated temperatures) for Ni and cobalt (Co) extraction. As a precursor to heap leaching, agglomeration of the multi-mineral phase feed particles into robust and porous granules of 4-10 m permeable bed, is essential. In the present work, several basic and applied studies of the agglomeration behavior of real Ni laterite ores and selected oxides and clay minerals (hematite, quartz smectite and kaolinite) which constitute the predominant host gangue phases of typical laterite ores are performed. Isothermal, batch agglomeration tests involving sulphuric acid solution as a binder were carried out to produce coarse, narrow-sized (5 ? 40 mm) granules which were well characterized. The influential role of feed ore characteristics (e.g., mineralogy/chemistry and primary particle size distribution) and binder composition (30 vs. 44% w/w H2SO4) and dosage (15-25 wt.%) in agglomeration behavior and granule properties were examined through several characterization techniques including granule size, compressive strength, bed percolation and re-wetting stability and 3-dimensional micro-structure analyses. Links between feed mineralogy/chemistry and size, binder formulation, agglomeration behavior, curing conditions and final granule properties and structural characteristics are established. The implications of the findings to Ni laterite plant agglomeration for enhanced heap leaching are discussed. Keywords: nickel laterite, complex low-grade ores, agglomeration, heap leaching, micro-structure

Sep 1, 2012

By G. Onal, E. Gock, H. Dincer

"During the conventional chromite dissolution process; chromite ore concentrates were ground to at least <90 µm using the ball mill and after adding Na2CO3 and leaning material (instead of CaCO3 also residues from the leaching process) at a ratio of e.g. 1:0.75:1.2, depending on the specific formulation, follows the digestion e.g. in a rotary kiln, heated in countercurrent. The reaction time is 3 to 8 h. The calcine is comminuted and leached with water or a thin chromate solution. Depending on the type of ore used, the yield is 75-85 %. The disadvantage of the above-described process is that it is impossible, using current technology, to achieve a complete digestion of the chromite ores and that the chromium-containing residues have to be disposed of as special waste, involving a large financial effort.The subject of this study was the investigation of the effect of vibratory milling on chromite dissolution. The impact stress in the vibratory mill causes the mechanical activation of chromite, which is characterised by lattice defects. The degree of mechanical activation can be quantified by measuring the relative X-ray diffraction intensities at the parent lattice planes of chromite. Each relative X-ray diffraction ratio correlates with a certain degree of digestion. As opposed to vibratory milling, a complete digestion of chromite using a ball mill is impossible, even at extremely long grinding times.In this investigation a chromite concentrate from Pulpinar/Kayseri with content of 44 % Cr2O3 and the Eccentric Vibratory Mill was used. In order to verify the effect of the vibrating grinding on chromite dissolution, reaction kinetic investigations on digestion and leaching were carried out."

Jan 1, 2003

By L. A. Vaisberg

"Crushing and grinding are the two most common industrial processes. These processes consume nearly 20 per cent of the entire electric power produced worldwide. This enormous amount of electric power consumed results from the fact that modern crushing and grinding machines employ the processes first introduced by the prehistoric man, namely those of compression, impact, attrition, and cutting. The material thus handled decomposes indiscriminately, and almost completely ignoring the microscopic cracks and other defects of its structure. Apart from the irrational use of the power, the crushing and grinding processes currently in use result in irretrievable loss of useful components or else in a substantial deterioration of the final products obtained, all as a result of incomplete grinding or, reversely, of overgrinding, palletizing, or fracture of particles.The principal type of equipment that has almost universally been used all over the world for more than 150 years for crushing both natural and synthetic minerals comprises unbalanced jaw and cone crushers. The driving element of crushing bodies in these machines is an unbalanced weight, which transfers the crushing body, allowing it to squeeze the material within the eccentricity value only. The maximum reduction ratio achieved by such a drive is 5, which is due to the rigid kinematic arrangement of the crusher, its dynamic unbalance, and the impossibility of increasing the number of impacts on the material being crushed. Moreover, conventional machines cannot cope with super hard materials, and their mechanism is vulnerable to damage by uncrushable objects.On the basis of fundamental research into the theories of solid body and vibration, OAO Mekhanobr- Tekhnika have developed a range of vibrating jaw and cone inertia crushers that make a reduction ratio of 30 feasible in an open-circuit operation with the reduction ratio monitored within a wide range. In these crushers, the eccentric drive is replaced with a vibrating one. In this way the rigid kinematic drive became dynamic, thus allowing pieces of material to be crushed in a thick layer due to the effect of their bumping into each other, and with the amplitude changing automatically. This results in a number of advantages as compared with conventional crushers:"

Jan 1, 2003

By Genrich A. Denisov

Principles of ecologically friendly geo-technologies construction are formulated on the basis of the works of the leading scientists in the field of rational processing of mineral resources of the Russian Academy of Sciences. One of these concepts is a new direction in rotational disintegration of mineral and technogenic raw material with the purpose of effective subsequent enrichment. A large amount of practical experience has been accumulated in the industry on selective destruction by application of vibrational method on initial material with consideration of its physical-mechanical properties and mineral structure. This method is successfully realised in a conic inertial pulverisation devices constructed by Mekhanobr Institute (St.-Petersburg). A new construction of conical-inertial pulverisation with a modification of disintegration force has been developed recently at Mekhanobr Institute. It allows, in some cases, to increase selectivity of subdivision and to avoid over-disintegration. Advantages of “wet” subdivision methods in conic inertial disintegration devices are proved. The efficiency of such subdivision can be increased due to rational use of the phenomenon of a dislocation-dynamic diffusion. Its advantage is proved by the effect on disintegrated material by frequency-modulated variable electrical fields of low power. It was shown in industrial conditions, that the productivity of the spherical mill can be increased by 10 %, and that it also prevents ecologically harmful surface active substances (SAS) in milling zone and it reduces the dust content in the air. The techniques of tentative estimation of efficiency of various proceedings technogenic materials and their classification are created. The scientific fundaments of rational, ecologically friendly technology of processing and regeneration of various kinds of technogenic raw material are developed. A number of effective technologies on processing of wastes is developed and inculcated in concentration factories and metallurgical factories.

Jan 1, 2003

By M. Salas, L. Rolf, H. Z. Kuyumcu

"Industrial use of abrasive stress takes place in the area of fine grinding and in order to clean surface contaminated soil particles. Also, at many mechanical operations abrasion emerge as an unintended side effect. At the Institute for Raw and Waste Material Processing at the Technical University of Berlin systematic investigations are carried out, to further the knowledge regarding the dependence of abrasion process on material properties and stress mechanisms as a basis for design and optimisation of the process or for its avoidance. Aim was the mathematical description of the abrasion process running with a single particle stress. For the purpose of investigations an agitation cell was used. Limestone served as material.In the presented work the influence of particle diameter, particle shape and collision energy on the mass and particle size distribution of abrasion debris was studied. The surface geometry of the particle was characterised by the particle shape factor ?x and the particle diameter dp. The particle shape factor ?x stays in direct relation with the abrasion degree x, and can be substituted by a mathematical function of x.Physically the particle shape factor ?x can be interpreted as a proportion of abrasive stresses splitting up complete crystals and crystal fragments. These two different mechanisms depend on different ratios of curvature of the surface of the stressed particle. The abrasive stress of strongly curved surface areas leads to separation of complete crystals. The abrasive stress of weakly curved surface areas leads to separation of crystals fragments. Accordingly the mass of wear mAb and median diameter of the abrasion debris d50 are different. The derived mathematical relations consider this behaviour by the particle shape factor ?x , which represents the ratio of the mixture of both stress mechanisms. The dependence of the particle shape factor ?x on the abrasion degree x with an exponent approximately to 2/3 points out that the particle shape factor ?x represents a surface area relation."

Jan 1, 2003

By John Starkey

"The development of the SAG Power Index (SPI) Test in Canada has created a new and accurate way to measure ore hardness in a SAG environment. Coupled with the standard Bond Ball Mill Work Index Test it is now possible to determine from these two relatively inexpensive laboratory tests, the amount of energy required to grind an ore from the primary crushed size to the desired liberation size. By testing multiple samples to discover where the hard and soft ore zones are located, the representative hardness distribution for the ore body can be determined and grinding equipment selected that is capable to meet production targets for all mining areas of the deposit.Previously, it was deemed prudent to select up to 50 t samples of ore for Semi Autogenous Grinding (SAG) pilot plant tests and a second 5 t sample for metallurgical pilot plant work. The methods outlined in this paper show how the 50 t sample is no longer required for SAG design because it is better to measure the representative hardness distribution of the ore body than the hardness of a “chosen” representative sample. This is demonstrated to be true by the fact that the lower horizons of an ore zone cannot initially be accessed to recover 150mm pieces, and the bulk samples taken, rarely represent the desired design hardness of the ore. Median hardness will not yield a good result in most cases and a clear understanding of the location and extent of the hardest zones is imperative to achieve a truly successful grinding circuit design.This paper discusses two plants (Kubaka and Agnico Eagle) that have been designed using SPI and Bond with no pilot plant test backup. Both have been very successful in that they can grind design tonnage on the hardest ores in the mine. This guarantees that the mine’s profitability is protected in any mining sequence. It also allows the extra power to be converted to higher throughput on softer ores if additional cash flow is needed. The advantages from the owner’s point of view are dramatic. This procedure will be attractive as well when considering the costs for test work, and the samples for testing. Existing diamond drill core is normally used and this allows the inclusion of data from the deepest regions of the mine. In addition, it is also clear that the decision to use a crusher can now be made at the design stage of a project based on measured parameters and the estimated capital costs of alternative designs."

Jan 1, 2003

By Mary Stewart, Jim G. Petrie, Geoff Brent

"Life Cycle Assessment (LCA) is gaining increasing acceptance as a decision-support tool by which to evaluate the environmental performance of a product, process or service. This is evidenced by its inclusion in international policy documents (for example in the European Union’s Integrated Product Policy) and in environmental management standards (the ISO 14 040 series of environmental management codes relate to LCA). In response to this, the minerals industry has conducted a number of commodity-specific LCAs. These include studies for global production of a number of commodities including copper, nickel, aluminium and steel. In addition, a number of minerals companies profess to use LCA as part of their suite of project and technology assessment tools. Often, this collected use represents more a situation of “we do this because we’re told it’s good for business” rather than from any demonstrable evidence of this fact. This has led to a situation of much confusion and disillusionment within the industry, exacerbated by the obvious current limitations of LCA to accurately reflect the environmental performance of minerals and metals.Our point of departure here is that LCA, conforming as it does to the tenets of environmental systems analysis, is a valuable starting point, and that there is merit in exploring to what extent the methodology can be enhanced to better reflect the environmental performance of minerals and metals. Specifically, we explore here the further development of LCA to address the following:• Land Use issues• Consumption of Abiotic Resources including metallic and non-metallic minerals, water and soil)• Human and Eco-toxicity issues relating to mobility and bio-availability of metals• Salinityand address these through selected experimental and simulation case studies relating to energy- and base minerals production. Advances resulting from the United Nations Environment Programme/Society for Environmental Toxicology and Chemistry Life Cycle Initiative are presented in that they directly affect the application of LCA to mining, minerals and metals. Comments are offered on how best the mining and minerals industry might interface with future developments resulting from this Initiative in order that the Initiative can deliver outcomes which render LCA a useful tool for decision making in mining and minerals processing."

Jan 1, 2003

By Stephen Gay, Dewetia Latti

"When improving a plant a mineral processing engineer would like to know the mineral composition distribution. In order to assess this distribution in particles, as compared to the corresponding distribution in particle sections, a procedure needs to be applied to the observed particle sections. Such a procedure is called a stereological correction. There exists many stereological correction procedures, but one group of such procedures is based on using those stereological equations that do not require making assumptions regarding particle shape or texture. These equations are called geometric probability equations.Davy derived a geometric probability equation to estimate the covariance of mineral composition distributions for particles from both particle sections and linear intercepts. This covariance can be used to measure the variance of the particle composition distribution of each mineral. The equation as presented by Davy requires textural information; however the equation was modified by Gay to be more directly applied to particle sections and linear intercepts. The variance obtained from applying this equation is fundamental to the binary stereological correction procedures developed by Gay and his colleagues; the covariance is fundamental to the multiphase stereological correction.Thus far, validation of both the binary and multiphase stereological correction has been achieved using numerical simulation. This paper shall present results comparing the covariance (and variance) estimates from Gay’s equation with actual three-dimensional information obtained from serially sectioning particles. This involved mounting a set of particles and continuously sectioning all particles uniformly so that the three dimensional structure of the particles could be obtained.The mineralogical data to which the equations described above were applied were derived from two individual size fractions from a hard-rock titanium deposit. The deposit contains a range of minerals and of mineral textures and the two size fractions selected were:"

Jan 1, 2003

By Elzbieta Mielczarski, Jerzy Mielczarski, Jan Drzymala, Yann Duval

"The monoalkyl ethers of polyethylene glycols are universal flotation reagents because they can be used as collectors, frothers, surfactants, and depressants. Their collecting power was demonstrated for different minerals including coal and quartz.It was confirmed in this work that monoalkyl ethers of polyethylene glycols could be used as collector in flotation of quartz in a monobubble Hallimond cell. Since feldspar does not float in the same cell, it was also shown that selective separation of quartz and feldspar in the Hallimond tube is possible. However, a trail to use the monoalkyl ethers of polyethylene glycols compounds for separation of quartz and feldspar by flotation of mixture of these minerals in a Mechanobr laboratory flotation machine was futile, indicating that these reagents required special environment for flotation.Most probable parameter responsible for a decrease in quartz flotation in the flotation machine is the hydrodynamics of process, and different adsorption/desorption conditions. To prove this, another series of experiments was carried out to separate quartz and feldspar, in which a laboratory flotation column was utilized. The performance of the flotation column was in between that of in the Hallimond tube and flotation machine. These experiments confirmed that the hydrodynamics of flotation plays a vital role in flotation of quartz with monoalkyl ethers of polyethylene glycol compounds."

Jan 1, 2003

By Kari Moen, John Rasmus Leinum, Jarle Hjelen, Terje Malvik

"Industrial minerals may contain the same elements in approximately the same amount. In these cases backscatter electron imaging or chemical analysis are not sufficient to identify the minerals. Another problem arises when micro textures are not detectable in traditional imaging or the grain size is smaller than the X-ray spatial resolution.As a supplementary technique in these cases, application of crystallographic information by electron backscatter diffraction (EBSD) in the scanning electron microscope (SEM) may be a suitable method. The technique has been demonstrated on three Norwegian mineral raw materials and one Italian marble and shows that it has some advantages compared to traditional techniques.• quantitative measurements by ebsdCommon automatic techniques describing the mineral contents and the occurrence of minerals in free and locked particles, are based on optical-, backscattered electron (BSE)- or X-ray-signals. There are various commercial software systems on feature analysis by backscattered and X-ray signals in combination with image analysis (e.g. Oxford Inca Feature, CSIRO QemScan).Especially in silicates, the occurrence of similar elements in the different minerals is common. Sometimes the various minerals not only contain the same elements, but also approximately the same amount of each element. In these cases BSE imaging and chemical analysis are not always sufficient for identification."

Jan 1, 2003

By Benoit Clermont, Jan Lux

"Magotteaux and Anglo Platinum started a co-operation program with the main aim of establishing the optimum milling configuration measured in terms of throughput, fineness and energy consumption.For this purpose, a fully instrumented pilot milling plant, supplied by Magotteaux (Pty) Ltd, and equipped with a 0.9 x 1.0 m ball mill, was erected at Frank concentrator (Merensky Pt ore). The primary ball mills at Frank concentrator were surveyed in order to set the conditions for the base case. This data was then replicated in the pilot mill under the same configuration. Thereafter, a series of different parameters were varied in order to attempt to optimize the milling system.Only grate versus overflow discharge and open versus closed circuit will be discussed in this paper.It should be noted that this paper does not attempt to give a universal solution as to what milling configuration is optimum in all cases. The conclusions apply for this particular case and probably most others, but it would be advisable to consider each case on its own.CONCLUSION• Overflow versus grate dischargeAn overflow mill has a “pool” of slurry around the toe of the ball charge, which creates a counter lever to the ball charge. This will reduce the absorbed power in the range of 10-15% (depending on the case) and will consequently result in a coarser grind. The tests found a 4% gain in grinding efficiency (Wio) with an overflow mill but this is probably not significant.This lower absorbed power and coarser grind can be counteracted by increasing the ball charge (if below maximum) and/or by increasing the mill volume when removing the grate discharge (a typical grate takes up about 300mm of the mill length).• Open versus closed circuit"

Jan 1, 2003

By Jochen Petersen, David G. Dixon

"Although heap leaching may be perceived as a somewhat low-tech route for the extraction of low-grade minerals, the underlying physical, chemical and biological processes are in fact extremely complex. There has been increased interest in heap leaching of sulphide minerals in recent years with the advent of controlled bio-heap leaching, and the need to mine more marginal ore deposits.A detailed investigation into the dynamics of heap leach processes has provided much insight into the underlying complexities, and has led to the development of a sophisticated modelling tool, HeapSim. Some of the sub-processes that are modelled include mineral kinetics, particle size effects, bacterial growth, oxidation and adsorption, gas adsorption, pore diffusion, bulk advection, gas balance and heat conservation. The interplay of these various sub-processes is illustrated in the paper.Two case studies are presented which illustrate specific features of the model for different applications and how these have helped to identify key areas of concern. The first is focussed on chalcocite heap bioleaching, which shows that by nature of the reaction the process is strongly dependent on the initial supply of acid to the mineral site. In heaps this acid supply can be severely limited by the rate of diffusion from channels of flowing solution into stagnant zones of the heap, whereas in narrow-bore laboratory columns this effect is not observed."

Jan 1, 2003

By Rob Morrison, Andrew Scott

"Long before a modern mine commences operations it has already become a wealth of information. After start up, it can generate enormous quantities of data – especially with semi-automated data acquisition by instrumented mine equipment. Much of this data is of limited use for evaluation of (potential) performance unless it links in some way to the site business model.An underlying reason for this waste of data is that the different cultures, financial, technical, community, environmental, etc, not only have many areas of interest but also have very different conceptual models by which they evaluate performance.It is too ambitious to attempt to bring all of these cultures together – in a single step. However, the success of the Mine to Mill ™ project has demonstrated that substantial operational value can be added by using a more integrated approach to comminution. The next logical step is to integrate measured data and then to track performance from ore body model to saleable product and waste disposal.The path from resource to product also represents a path from very sparse, highly variable data to much more detailed measurement and more representative sampling. However, in both cases the data collected is usually strongly focused on the technical requirements – not on the business model.This paper emphasises the difference between data and information. There is considerable potential for confusion between the two as both data and information are often expressed as numbers. For the purpose of this paper, data and information are distinguished by their uses.A data point (or datum) is a measurement. By way of contrast, information provides a basis for decision making."

Jan 1, 2003

By N. Raeis Hosseiny, S. H. Bassir

"Chador-Malu iron ore is one of the most important iron mines of Iran.About 98 percent of Fe in the ore is in shape of Magnetite, Hematite, Martite, aqua oxide of Iron and the other irons are with ferrous silicates, actinolite, cholorite and ferrous dolomites. 1% of Fe has replaced in pyrite. The phosphor distribution in the ore is non-hemogenous and its average in the whole of the deposit is 94%. It is in shape of Apatite.This mine contains considerable phosphor, which makes it useless for metallurgical uses. At this mine the phosphor is reduced in the iron ore at two steps. At the first step, magnetic part of the ore is separated from the gangues and phosphors by magnetic separator. At the second step, the ore is enriched by the flotation methods. Experimental flotation methods to obtain the optimum conditions are as follows:• Effect of Starch as Hematite depressant with ATRAC as Apatite collector• Effect of Sodium silicate as Hematite depressant with ATRAC as Apatite collector• Effect of ASAM as Apatite collector with Sodium silicate as Hematite depressant• Effect of ATRAC (BEROL) as Apatite collector with Sodium silicate as Hematite depressant• Effect of ASAM & ATRAC mixture as Apatite collector with Sodium silicate as Hematite depressant• Effect of Kcarbonate as pH-modifier• Final test to Optimize pH, Collector, DepressantAt this research we have found the optimum circumstance of the flotation of Chador-Malu iron ore in order to decreasing phosphors of iron oxide and floating of Apatite to make pure Hematite.To reach the optimum conditions, some tests were done with different amounts of pH, collector and depressant. The results are as follows:"

Jan 1, 2003

By Malcolm Mudge

"One of the oldest mining areas in the World exist in Africa and the Middle East. This area is being exploited by foreign and local mining entities. Several large plants, both foreign and local as well as small operators, conduct their mining business on a scale which would be could be prohibited in any other part of the world. Relatively recent European disaster with tailing disposal and breakout has highlighted the problem.More important to the author is that the presence of foreign entities in zones which have not remedied the situation but has heightened the concern due to those entities using similar outrageous methods in treatment of waste. The abject misuse of technology cannot be permitted to continue and the lack of any metallurgical knowledge in the treatment of gold ores is considered deplorable for the majority of third world countries.The destruction of cyanide is simple and straightforward and requires no special skills. In South America, we developed a system that is modular, compact and can be operated in batch mode to cater for several clients, as required. Larger installations would require a separate module, as treatmentwould be on a continuous basis."

Jan 1, 2003

By Gurubasayya Swamy

This paper presents the performance study of sag mill in the processing of gold ore. Deterioting ore grade and high demand of metals has tremendously influenced the SAG mills. Today?s high capacity Semi-autogenous grinding (SAG) mills expand vast amounts of energy and in doing so consume tons of shell liners and steel balls, while processing ore. Semi-autogenous (SAG) mill performance is influenced by ball charge, feed properties, shell, grate, and pulp lifter design. In the performance study of SAG mill, based on the results obtained it can be observed that SAG mill performed better at feed size +4 inch and grinding media consumption 0.90kg/mt. In the present study the effect of crusher bypass on SAG mill performance, an immediate drop of throughput ranging from 10-20tph is observed. Keywords: sag mill, pulp lifters, grinding media, energy, consumption, throughput

Sep 1, 2012

By Hiroshi Sasaki, Herman D. Mendoza

"The surface-chemical property of nickel slag fiber was modified in aqueous media in order to act as an active and efficient collector of colloidal amorphous silica from geothermal effluent. Colloidal amorphous silica (0.05 µm) from geothermal wastewater causes operational and ecological problems. It clogs geothermal pipes and waterways, and when disposed to the environment poses hazardous effects on both the flora and fauna ecology. Because colloidal amorphous silica is extremely fine and remains in suspension in aqueous media, conventional solid/liquid processes to remove colloidal silica from its bulk liquid are rendered ineffective.A rapid separation technique is then developed to remove effectively amorphous colloidal silica from its bulk liquid by attaching the extremely fine particles of silica onto a nickel slag fiber coated with magnesium hydroxide, Mg(OH)2. The nickel slag fiber has the following characteristics: a high surface area and predominantly possesses negative charge in aqueous media with an iso-electric point at pH ~2.5. When soaked and saturated with Mg(OH)2 solution, the surface of the nickel slag fiber becomes coated with fine and compacted Mg(OH)2 precipitates. This modifies the surface- chemical property of nickel slag fiber transforming the negatively charged surface into a positively charged surface in aqueous media with an iso-electric point of around pH 11.8, which corresponds to the iso-electric point of Mg(OH)2. When geothermal effluent containing negatively charged colloidal amorphous silica particles (i.e.p. of silica is pH 2) is passed through a column-bed packed with surface-chemically modified nickel slag fibers under natural pH conditions, the colloidal amorphous silica particles are recovered by attachment onto the surface of the surface- modified nickel slag fiber. The recovery of colloidal amorphous silica by attachment is 97-99%, resulting in the production of a relatively clean and silica free output. Aluminum hydroxide, Al(OH)3, was also used to modify the surface –chemical property of the nickel slag fiber. In the same way, it also exhibited a positive response with the collection of colloidal amorphous silica from its bulk liquid, but yielding a lower recovery of 90%. This may be attributed to the lower surface potential and iso-electric point of pH 9.3 for Al(OH)3. The separation process was evaluated and analysed using existing potential energy theories. Figure 1 shows a micrograph of the surface of an unmodified and the Al(OH)3 –modified surface of nickel slag fiber."

Jan 1, 2003

By Zhu Yangge, Zheng Guibing, Hu Xiaoxing

"Because of the similar crystal structure and surface properties, it is very difficult to realize the efficient separation of magnesite and dolomite by flotation, which is the main reason restricting the utilization of magnesite resources with dolomite symbiotic. To deal with a magnesite resources with high content of calcium impurity in northwest China, a novel decalcification technology by combining flotation with leaching is proposed in this paper. In flotation process, a novel flotation collector with good efficiency and low temperature resistance was developed, and the depression effect of sodium hexametaphosphate was investigated. In leaching process, the leaching rate difference of calcium and magnesium was observed. By industrial test, from the magnesite ore with MgO content of 43.96%,the grade and recovery of obtained concentrate ( calculated by MgO) are 47.28% and 67.68% respectively, at the same time, CaO content decreases from 3.91% to 0.30%, which means that more than 95% of CaO impurity is removed.INTRODUCTIONMagnesite is one of the main raw materials for the production of refractory materials, and it is widely used in metallurgy, chemicals, ceramic, construction and other industries. China is the most important supplier of highquality magnesite resources, accounting for about 60-70% of the world's identified supply of magnesite products is provide by China (Jewell, 2014). In recent years, high-quality magnesite ores can be directly used are going to run out in China, and the utilization of magnesite resources with high impurity content have drawn more attention.The main purpose of purification for magnesite is to remove SiO2 and CaO impurities which affects the strength of the refractory material. Flotation is the commonly used method to remove impurities in magnesite ore. Reverse flotation with cationic collector is usually adopted to remove silicon containing impurities, and a great deal of literature has been reported (Santana A. N. and Peres A. E. C., 2001; Wang and Sun, 2008; Zhu et al, 2014; Wu et al, 2015; Ivan B. et al, 2017). But when the major gangue component is dolomite, it is very difficult to realize the efficient separation due to the similar crystal structure and surface properties between magnesite and dolomite. To solve this problem, researches have studied the surface properties of magnesite and dolomite, such as wettability, electrical property, solubility and solution chemistry (Nermin and Nurgul, 2006; Nermin 2006; Ozbek and Abali, 1999; Lacin et al, 2005; Bayrak et al, 2006; Bakan et al, 2006; Chen G. and Tao D., 2004), but the commonly studied direct flotation using oleic acid as collector is still hard to receive an ideal effect."

Jan 1, 2018

By Gabriela Pino, Maurício Torem, Lorgio V. Gonzales

It has been long known that many microorganisms are able to interact with mineral particles to obtain a concentrate; thus, one possible technique is flotation and its related process. Biological process have been attracting attention in mineral processing due to lower operating cost and their possible applications to process low-grade and fine ores. The adhesion of microorganism to surface of mineral particles can alter the hydrophobicity of mineral markedly. Such surface modifications modify its hydrophobicity or hydrophilicity will be used to flotation of cassiterite fines. The major difficult to float fine particles is attributed to the low probability of bubble-particle collision, one characteristic of electroflotation process is the ability to create very tiny bubbles, which is known, improve the collision efficiency and flotation performance of fine particles. In this study, the electroflotation of fine particles using Rhodococcus opacus strain as bioreagent was investigated. Electroflotation experiments were carried out using particles of cassiterite around 8µm of mean diameter the adsorption of R. Opacus onto cassiterite particles was confirmed by Fourier transform infrared spectroscopy (FTIR), electrokinetic and contact angle analyses. The measurement of bubble size by laser diffraction showed a mean bubble size of around 26 µm, current density and bacteria concentration appear to be the main parameters affecting the mean diameter of bubbles, electroflotation tests reported recovery around of 64.5 % at pH 5, concentration of 2,87 x10¹² cells/ml (50 mg/L) and current density of 51,4 mA/cm2.

Jan 1, 2014