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By G. Adachi, K. Machida, T. Ozaki, K. Murase

The chlorination rate with CCl4 was unexpectedly slower than carbochlorination using chlorine under the same reaction conditions. Chlorination with CCl4 was topochemical and the amount of monazite reacted after different periods suggested that the kinetic control step was the reaction between CCl4 and the monazite core at the interface. The kinetic order of the reaction was 0.5. The presence of a complex former, AlCl3, promoted the chemical vapour transport of rare-earth chlorides as complexes

Jun 18, 1905

By H. L. Paterson, R. R. Keays, M. J. Donaldson, D. J. Boyack, M. F. Smith, J. J. Gresham

"Albite-rich sedimentary rocks that contain abundant Fe sulphides occur in the lower portion of the ultramafic sequence at Kambalda and their broadly antipathetic relationship to most of the nickel orebodies is well documented. These sediments generally contain less than 0.1% Ni, but nickeliferous equivalents with 0.3 to >6% Ni occur locally in close spatial association with more typical volcanic peridotite-associated massive, matrix and disseminated ores. Nickeliferous sediments have been mined at several locations at Kambalda but, collectively, they constitute less than 2% of the total Kambalda nickel reserve. The nickeliferous sediments occur both on the ultramafic-footwall basalt contact and within the lower part of the ultramafic sequence, and are usually less than 5 m thick. They are commonly finely laminated rocks with a cherty appearance, composed essentially of layers of albite+quartz±amphibole, alternating with pyrrhotite+pentlandite±pyrite layers. Some contain a minor amount of carbon. The sediments are only of ore grade (> 1% Ni) immediately adjacent to massive Fe-Ni-Cu sulphides, which are interpreted as normal magmatic ores on the basis of geochemistry and the presence of distinctive ferrochromites. The nickel content of the sediments decreases to background levels (<0.1%) within about 20 m of the massive sulphides. In most locations the massive sulphides clearly have been emplaced tectonically within or adjacent to the sediments, which are commonly highly deformed. Typical nickeliferous sediments contain about 1% Ni, 0.1% Cu, 0.1% Zn, 400 ppb Pd, <0.2 ppb Ir and 10-200 ppb Au. They have lower Ni/Cu (average 10), higher S/Ni (average 6) and higher S/Se (average 11 200) than associated massive sulphides (average 40, 4.8 and 7400, respectively). The Pd/Ir ratio of the nickeliferous sediments (typically > 1000) contrasts markedly with that of associated massive sulphides (average ca 16).The high Pd/Ir values are similar to those which have been reported for hydrothermal Fe-Ni sulphides and barren sulphidic sediments of probable volcanic exhalative origin. They preclude a direct magmatic origin for the sulphides in the nickeliferous sediments, though S/Se and S isotope data indicate a magmatic source for the sulphur. The restriction of nickeliferous sediments to within about 20 m of normal magmatic sulphides and the lack of a widespread Ni dispersion halo suggest local redistribution of originally magmatic Ni. This probably occurred by diffusion and hydrothermal mobilization during deformation and amphibolite-facies metamorphism. Although not totally ruled out, a volcanic exhalative origin for the Ni seems unlikely."

Jan 1, 1984

By S Colak, M Tunc, C Celik, M. M. Kocakerim

The most important parameters affecting the solubility of ulexite (sodium calcium borate) in H2SO4 were found to be reaction temperature and solid:liquid ratio, in that order. Dissolution increased with increase in temperature and stirring speed and with decrease in solid:liquid ratio, particle size and acid concentration, the last effect as a result of decreased precipitation of CaSO4 on unreacted particles. Optimum conditions, in which around 99.5% of the ulexite could be dissolved, were a reaction temperature of 60 degrees C, a solid:liquid ratio of 1:8 g/ml, an acid concentration of 8 mol/l, particle size smaller than 425 micrometres, a stirring speed of 52.33/s, a reaction time of 1 800 s, a calcining time of 3 600 s and a calcining temperature of 170 degrees C. These conditions, determined by the Taguchi method, are reproducible in a commercial production environment

Jun 21, 1905

By T. Yalcin

In the Box-Wilson method, the correlation between dependent and independent variables is represented by a polynomial response function, whose constant and coefficients are determined by applying regression analysis to the experimental data collected. The five levels used for each variable consist of a minimum, a maximum and three intermediate values. A study was carried out using Ni-Cu ore from Sudbury, Ontario, in which 15 experiments designed according to the Box-Wilson method were carried out in random order and in duplicate. The two sets of replicate data showed close similarity, with an overall variance of 0.311 for the five parameters studied. The response functions were used to optimise frother dosage, collector concentration and air flow rate and an experiment was then carried out under the optimised conditions; the results agreed closely with those predicted by the response functions

Jun 21, 1905

By M. M. Cole

An assessment of the combined application of remotely sensed satellite imagery, geobotany and biogeochemistry reveals the complementary value of these techniques in the Thalanga area. The SPOT imagery yields useful information on features of the terrain and discriminates the gossan over the ore zone. Geobotany differentiates geological units and the anomalous vegetation provides visual expression of the surface presence of the ore zone, while biogeochemistry effectively locates its concealed extension below Tertiary sediments and ferricrete

Jan 1, 1991

By B. M. England, M. V. Swain, N. Bristow, R. D. Dukino

The toughness and fracture mechanisms of ores with significantly different microstructures from Yandi, Koolan and Mount Whaleback were studied with a view to understanding their degradation behaviour. Bulk fracture toughness was determined by the 3-point single-edge notch beam test and the results interpreted using Weibull statistical analysis; indentation fracture mechanics was also used to measure fracture toughness of the different mineral forms and to understand their response to contact fracture

Apr 1, 1995

By A. S. W. Kurny, M. Z. Huq

Bangladesh ilmenite is partially altered, containing pseudorutile, rutile and haematite as well as the predominant ilmenite phase. A typical analysis is 39.45% TiO2, 24.19% FeO and 33.0% Fe2O3. Reduction of the ilmenite by charcoal was found to involve two major reactions: conversion of pseudorutile into ilmenite and rutile, and change of ilmenite into metallic iron and rutile. The first, which was much the faster reaction, was responsible for an initial increase in ilmenite content with reduction time at lower temperatures. Apart from these two major reactions, rutile was reduced to lower oxides at 1 100 degrees C with a consequent decrease in its XRD peak height

Jun 19, 1905

By G. M. Zhao

The gasification of lump coke with CO2 was studied in a fixed-bed reactor. The effective diffusivity of the gas was evaluated from measurements of the reactivity of the lump coke, produced by BHP Steel in New South Wales, and from kinetic parameters that were determined from the reactivity of fine grains. The grain model of effective diffusion in porous media was adopted to express the gasification rate of the lump coke and was found to fit the experimental data well. The relationship between reactivity and textural characteristics of the coke was examined

Jun 18, 1905

By L. R. Chimimba

"The Trojan nickel deposit occurs within a pile of ultramafic lavas subjected to a lower amphibolite grade of metamorphism. The lavas form part of the Upper Greenstones (Bulawayan Group) of the Mazoe greenstone belt. The nickel mineralization occurs as disseminated, massive and near-massive sulphides. The massive and near-massive ore occurs along the basal contact of the serpentinite units and is overlain by the more abundant disseminated ore, which occurs within the serpentinite. The main sulphide minerals are pyrrhotite. pentlandite and chalcopvrite. Minor amounts of millerite and pvrite are present. The Ni : Cu ratio in all three types of ore averages 15:1.The intercumulus nature of sulphides in the near-massive ore and similar textures occasionally seen in the disseminated ore indicates a magmatic origin of the mineralization. The basal position of the near-massive and massive ore suggests that the sul­ phides settled out under gravity during the emplacement and crystallization of a peridotitic magma. The deposit has been deformed and some of the primary massive ore has been remobilized into veins and breccias. The disseminated mineralization now occurs mainly as blebs of sulphides intergrown with silicate minerals or as stringers of sulphides between foliation planes in the serpentinite."

Jan 1, 1984

By J. E. Rouse, D. L. Buchanan

"During the emplacement of the Bushveld Complex in the Potgietersrus area magma reacted with the original floor rocks— Archaean granite or Malmani dolomite and overlying Penge handed ironstone or sedimentary rocks of the Pretoria Series. The complex sequence of sulphide-rich mafic rocks that formed along the contact is known as the Platreef. Associated with the sul­ phide mineralization are important concentrations of platinum-group metals, copper and nickel. Xenoliths of Malmani dolo­ mite have been incorporated into the Platreef and previous work has suggested that anhydrite is likely to have been present in the dolomite. The sedimentarv-derived sulphur thus introduced into the magma exercised an important control on the forma­ tion of the sulphides.Petrographic studies on the Platreef rocks from the Tweefontein area indicate that the original magma reacted with the banded ironstone to form iron-rich pyroxenites. In the Turfspruit area, to the south, the footwall rocks consist of sediments of the Timeball Hill Series. Original argillaceous rocks have been metamorphosed to cordierite-, corundum- and spinel-bearing hornfelses. Graphite was present in the contact zone in both the Tweefontein and Turfspruit areas. Anhydrite-bearing hornfels rocks are also present on Turfspruit.The Platreef rocks that overlie the corundum- and spinel-bearing hornfelses on Turfspruit are peridotitie, and pyroxenites are present in areas underlain by cordierite-bearing hornfels. The absence of orthopyroxene in the peridotite is probably indicative of low silica activity in the original magma. The pyroxenites have, however, undergone silica contamination from the underlying more siliceous cordierite hornfels.Carbon isotope studies indicate that the graphite in the Tweefontein and Turfspruit samples represents organic material orig­ inally associated with the footwall sediments. Sulphur isotope determinations on the anhydrite-bearing floor rocks indicate that this phase is clearly of sedimentary origin and was probably derived from an evaporitic unit within the carbonate sequence. This provides firm support for a model of ore genesis that involved the introduction of additional sulphur into the Bushveld magma. Isotope studies on sulphides associated with the banded ironstone and graphite indicate that these units were not the source of additional sulphur. Experimental studies predict, however, that a magma contaminated with iron- and carbon-rich material would have a high sulphur-carrying capacity. Where additional sulphur is available the magma would achieve saturation early in its crystallization history and precipitate an immiscible sulphide phase. Experimental work has also shown that sulphide precipi­ tation can be triggered by the introduction of salic material into a magma close to sulphur saturation. This mechanism probably played a role in the control of the sulphide mineralization in the Turfspruit area."

Jan 1, 1984

By R. K. Zipf

The sudden, violent collapse of large areas of room-and-pillar mines poses a special hazard for miners and mine operators. This type of failure, termed a cascading pillar failure, occurs when one pillar in the mine layout fails, transferring its load to neighbouring pillars and causing them to fail in succession. Recent examples of this kind of failure in coal, metal and non-metal mines in the USA are documented. Mining engineers can limit the danger presented by these failures through improved design practice. Whether failure occurs in a slow, non-violent manner or in a rapid, violent manner is governed by the local mine stiffness stability criterion. This is used as a basis for three design approaches to control cascading pillar failure: containment with barrier pillars during pillar splitting; prevention with panel pillars of high width-to-height ratio and small-centre mining; and full extraction by retreat mining

Jun 19, 1905

By R. C. Courtney, D. J. Forrester

Modern advances have led to sweep and multibeam bathymetric surveying techniques that yield three-dimensional images of the sea floor and have also produced high-powered personal computers with which to control the data and analyse the results. At Sydney, in Nova Scotia, the topography of the sea floor over the longwall workings was observed before and after mining with a precision echo-sounder in 1987-89, with sweep bathymetry in 1993 and with multibeam bathymetry in 1994-95. The results of the latter programme produced what was probably the first observation of a complete three-dimensional subsidence trough over a longwall panel 2 500 m x 168 m. The subsidence has been quantified to a sufficient degree of accuracy to allow simple trend analysis, which has shown that the pattern and shape of movements are similar to those found elsewhere but with significantly smaller maximum subsidence. A prediction model has been calibrated

Jun 19, 1905

By P. J. Baguley

The model has been developed on the basis of the observation that the partitioning behaviour of a particle is related to its calculated terminal velocity. It utilises a theoretical calculation of the terminal velocity of each particle class. This is then correlated with the observed partition data for a plant separator using empirically-derived functions of operating conditions which take into account effects such as bath turbulence, holes in drum lifters and feed arrangements. The model successfully decouples the effects of medium density and viscosity and is appropriate for any bath-type separator. The correlation between calculated terminal velocity and actual partitioning behaviour was established and modelled using data obtained from two Wemco drums treating Fe and Mn ores. The model can be used to predict the prevailing size-by-size partition curves and the separation (product grades/recoveries) given the washability of the feed and operating conditions. Simulations are used to show that, for the treatment of Fe ore, there is a maximum medium density beyond which product grades fall and that this maximum decreases as the proportion of magnetite in the medium increases. This is attributed to the dominant effect of viscosity at higher medium solids concentrations

Jun 18, 1905

By D. J. Burdon, Anthony Caplan

"(1) The radiological appearances of pneumokoniosis on the Kolar Gold Field is described in detail. The characteristic abnormality is the. presence of a diffuse, fine annular and punctate mottling. (2) The frequency of symptoms could not be determined with any degree of accuracy, but it is believed that symptoms are absent and there is no incapacity until profuse radiological mottling is present, i.e., after long exposure to dust. (3) There is an increased predisposition to tuberculosis, which, if it occurs, affects the prognosismost unfavourably.(4) Pathological examination shows that the radiological mottling is due to the presence inthe lung of numerous small dust-cdll aggregates (up to T5 mm. in dia.) deposited around the smaller bronchioles and blood-vessels.(5) The dust-cell aggregates are relatively acellular but when tuberculosis is superadded thereis an excessive cellular and fibrotic reaction.(6) The difficulties of defining the radiological and pathological appearances of early pneumokoniosisare discussed.(7) The incidence of pneumokoniosis in 7,653 workmen with 5 or more years’ undergroundservice was 43-75%, but it is suggested that in future the incidence will be appreciably lower.(8) The methods of- dust production and the chemistry of mine dust are described. It isshown that the free silica-content of air-borne mine -dust is relatively low.(9) The aetiology'of the pneumokoniotic lesion is discussed."

Jan 1, 1947

By R. K. Dunham, D. J. Reddish, X. L. Yao

Paper presented at the conference: Risk assessment in the extractive industries, held in Exeter, UK, 23-24 March 1994, and first published London: IMM, 1994, preprint volume, 10pp., 10 refs. The integrated approach combines a powerful ground movement prediction program with a knowledge-based expert system. ESDAS (Expert Structural Damage Assessment System) was developed to evaluate mining subsidence damage in the form of risk and in terms of the three vital contributing components (mining factors, site factors and structural factors). Using a certainty factor risk assessment technique, the system can be used to predict the likely damage to a particular structure subjected to mining subsidence. A previously developed powerful ground movement prediction program, SWIFT (Subsidence With Influence Function Techniques), has been combined with the expert system to allow the mining factor to be more accurately determined in a broader range of mining layout. Since SWIFT can be calibrated to any particular coal field using local subsidence data, it is believed that the integrated system could be used in any coal field worldwide for the assessment and control of mining subsidence damage risks

Dec 1, 1995

By H. K. Taylor, B. Denby, L. D. Smith

Contributions by H.K. Taylor and G.A. Davis discuss the three papers published in Transactions IMM A, vols. 103 and 104, with responses by Smith and Dowd

Dec 1, 1995

By S. P. Singh

The purpose of the cut is to provide a free face to which the remainder of a development or breasting round can break. The results of field testing in drifts and at a quarry face were used as a basis for a description of the rock breakage and flushing mechanism in the cut. It was concluded that the important features of a cut design are proper hole spacing, sufficient relief volume, drilling accuracy and relief holes slightly longer than the planned length of the round. The void space provided by the relief holes should be about 15% of the cut volume, with more required in weak, highly fissured rocks. The importance of drilling accuracy increases with round length, an error being magnified by the small blasthole spacing. The first hole pulls only about 20% of the round length, 4-6 holes having to be fired before the cut is pulled close to its design depth. The first four blastholes should be fired with a minimum inter-hole delay of 100 ms to provide progressive relief of burden and avoid the superimposition of ground vibrations. The earliest-firing charge should be closest to the relief area and act laterally, while the first of the vertically-fired charges to be detonated should be the uppermost. Problems during cut-pulling include sympathetic detonation, dynamic pressure desensitisation, charge disruption and freezing of the cut

Dec 1, 1995

By R. J. Pine

Procedures are described for the application of risk analysis or probabilistic methods to mining geomechanics. The methods are widely applicable to existing mine design models. Detailed examples are given of plane slope failure and of pillar design based on displacement-discontinuity stress modelling and empirical strength assessment. The modelling techniques assessed are the Latin hypercube sampling method, incorporated in a spreadsheet environment, and the general point estimate method (GPEM), programmed in TurboBasic. An example GPEM program listing is included. Both methods are very convenient to use. Probabilistic acceptance criteria for slope stability after Priest and Brown are examined and alternatives are proposed where output distributions of factor of safety are approximately normal or lognormal and output distributions of safety margin are normal. The reliability index is included as a useful measure of variability with proposed acceptance criteria.

Jan 12, 1992

Further discussion at the North of England Institute of Mining and Mechanical Engineers' general meeting held in Newcastle-upon-Tyne, 3rd June 1916, on the paper published in Trans. I.Min.E., vol.L, 1915, p.179, consisted of the author's written response to Mr. Hare's comments at the April meeting

Dec 1, 1916

By A. F. Neil, A. S. Bahaj, P. Watkins, P. M. Hyslop, C. E. Kirby, P. A. B. James

The results of initial work indicate that for 3 of the 5 quarry sands bioleaching reduces the iron oxide content to a commercially acceptable 0.035 wt% Fe20 3, although the time taken to achieve this is 14-22 days against a target leach time of 7 day. Subsequent work has identified strains of Aspergillus niger that are more efficient at producing the array of complexing agents for iron and is yielding excellent and rapid reductions in Fe levels. Potentially, bioleaching offers a more environmentally friendly and energy-efficient process for the removal of Fe from glass-making sands than conventional routes but the production of organic acids by fermentation must be achievable with low-cost substrates such as sugar-beet molasses and lactose permeates for bioleaching to offer a commercially viable alternative to treatment with hot mineral acids. Silica sands usually contain three groups of Fe minerals: iron oxyhydroxides, which comprise crystalline types such as goethite and limonite tending to occur as thin, discontinuous coatings and in cracks and crevices on the surface of the quartz; the assemblage of heavy trace minerals, which include ilmenite, rutile, leucoxene, chromite and haematite, commonly present at levels of 0.1 wt% or less as discrete grains or sometimes cemented to the quartz; and clay minerals cemented in pits on the surface of the quartz and in association with weathered, discrete feldspars. The response of the assemblage of iron minerals to short periods of exposure to hot inorganic acids is broadly related to which group they belong to, those that form coatings being accessible to acid and tending to react rapidly whereas the trace minerals are usually resistant and react very slowly, if at all, and the clays are probably digested. The note reports on a preliminary study of the use of microorganisms to develop an alternative clean technology that will give results comparable to those achievable with hot inorganic mineral acids but with more environmentally acceptable procedures. Various fungi and bacteria produce organic acids when grown in certain media. When these acids come into contact with Fe-stained sand grains the iron is removed as soluble complexes. Several strains of Aspergillus niger have been found to produce organic acids from sugar, predominantly citric, gluconic and oxalic acids, their relative yields depending on cultivation medium and conditions. Sand samples were prepared from five quarries in the UK: Levenseat, Lothian; Redhill, Surrey; King's Lynn, Norfolk; Chelford, Cheshire; and Oakamoor, Staffordshire; ranging in iron oxide content from 0.035 to 0.153 wt% Fe203

Jun 18, 1905