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By E Oktay, I Yusufoglu, C Kahruman

Powder and spherical pellets of MoO2 were oxidised under controlled conditions in the temperature range 674-791 K at oxygen partial pressures of 8.1-30.4 kPa. Weight increase during the reaction was determined by thermogravimetric analysis. It was concluded that the reaction is 0.6th order with respect to oxygen concentation and that the activation energy is 148 kJ/mole. In experiments conducted with powder, fast transfer of reaction heat to the gas phase created isothermal conditions, but the temperature of pellets rose by a maximum of 54 K at 674 K and 105 K at 791 K. The rise in temperature caused structural changes such as sintering and crack formation, which had a considerable effect on the reaction rate. The findings should be taken into account in the design of equipment and choice of operating conditions for roasting MoS2

Jun 21, 1905

By A. J. Davidson

A Cu-conducting solid electrolyte was used to develop the sensor. Instead of measuring the potential across the electrolyte from the reference material to the Cu-containing phase, a potential was applied and the stable current measured. This gave reasonable readings for copper-tin alloys, which agreed with the theoretical calculations, but was less satisfactory in the case of mattes because the surface area of electrolyte presented to the matte phase varied from sensor to sensor. To overcome this problem the potential was applied, the current was measured and then reversed and remeasured and the ratio of the currents was calculated. The current ratio is shown to be independent of the resistance of the electrolyte and the surface area of the electrolyte offered to the melt, but strongly dependent on the activity of the copper

Jun 21, 1905

By P. A. Rossouw, G. A. Fourie

Several attempts have been made over the latter half of the twentieth century to devise a system for the classification of underground mining methods. None of these are found to be totally successful. A revised classification is suggested with three main categories being identified by reference to fill requirements, steep stopes and stratified geological environments. Methods always needing lasting mass or structure fill include methods with timber-structured stopes and those with mass-filled (or cut-and-fill) stopes. Methods associated with steep stopes are subdivided into steep-stope-specific caving and steep-stope-specific non-caving (or self-supporting) methods. Methods not in the first two categories, often used in stratified geological situations, are not necessarily restricted to stratified environments and include caving as well as non-caving varieties. This category is further divided into room-and-pillar mining, longwall and shortwall coal mining and the type of open stoping found in gold or platinum reefs comprising overhand, underhand and breast-stoping variations

Dec 1, 1996

By D. K. Bose, R. H. Rakhasia, V. D. Shah, J. C. Sehra

A series of experiments was conducted to determine the effects of roasting temperature, soaking period and quantity of soda ash added. At a laboratory scale, under optimum conditions of roasting at 873 K for 2 700 s with soda ash 10 wt% in excess of stoichiometric, molybdenum recovery was 99%. The investigations indicate the technical feasibility of producing high-purity MoO3 by combining the roasting process with carbon adsorption/desorption. The process uses low-cost chemicals, can be scaled up readily and is free of the SO2 pollution generated by conventional roasting, as the sulphur content of the concentrate is converted to sodium sulphate

Jun 18, 1905

By S. P. Mishra, G. R. Chaudhury

The adsorption of Cu2+ ions by Penicillium sp. displayed a dual rate, with an initial faster phase followed by a slower one. The adsorption rate increased with increasing pH due to chemical and biochemical reactions. The Cu-loading capacity of the biomass increased at higher initial Cu2+ concentrations. Above 40 degrees C the adsorption rate decreased which may be due to partial hydrolysis of biopolymers which are essential constituents of the cell wall. Adsorption kinetics followed the Freundlich isotherm and the equilibrium concentration that was calculated on the basis of the isotherm matched the observed value well. A series of theoretical adsorption curves were produced using mathematical correlations between the mass transfer coefficient, the Cu2+ ion concentration at equilibrium and at time t. The correlation between the theoretical and observed adsorption rates for different experimental conditions was good. It was concluded that the results from the study were best explained using a mass-transfer adsorption model

Aug 1, 1995

By J. S. Coats, G. E. Patts, N. Hughes

Conventional sampling methods are known to suffer from the variable loss of fine gold by elutriation. Freeze sampling yields representative and quantitative data that, when combined with information on the sedimentology of gravel-bed rivers, may facilitate the development of improved dispersion models for source detection. It is suggested that freeze sampling may have particular application to the orientation stage of a large gold exploration survey

Jan 1, 1991

By A. D. Mukherjee, H. N. Bhattacharya

Middle Proterozoic sulphide ore mineralisation occurs in isolated blocks of the NE-SW trending Delhi fold belt composed of Delhi Supergroup rocks. The Ajari-Basantgarh-Pipela belt forms part of the longest, widest and westernmost tectonic unit of the Delhi fold belt and consists of amphibolites, metapelites, quartzites and carbonates. The metapelite lenses and associated amphibolites host pyritic copper mineralisation. Mineralisation takes the form of sheet-like bodies consisting of ore lenses of various sizes interlayered with host or associated rocks. Massive, banded and disseminated varieties of ore are found. Pyrite is dominant with subordinate chalcopyrite and sphalerite. Pyrrhotite, galena, cubanite, mackinawite, marcasite and freibergite constitute the minor minerals. The characteristic features of the ores suggest a possible correlation with Besshi-type deposits, and the closely associated amphibolites are interpreted as low-K tholeiites of a fore-arc setting

Jun 19, 1905

By A. E. Tercan, D. Mamurekli

Ordinary kriging on the assumption of a gaussian error distribution and indicator kriging were used to derive the probability that a given calorific value would or would not be exceeded by coal from an area of a deposit. The two techniques led to similar probability maps despite local differences; the lack of an absolute reference makes it impossible to judge which method is better for this particular application

Jun 19, 1905

By J. A. Finch, Zhenghe Xu, Z. A. Zhou

Whether the microscopic bubbles generated by the high energy dissipation and high feed-slurry velocities in new flotation cells are stable in solution and what roles they play in particle collection are of great interest for the flotation of fines. Experimental work has shown that, with fast flow of liquid through an orifice, stable microscopic bubbles can form in flotation systems by hydrodynamic cavitation in the absence of gas supersaturation. The minimum flow rate at which bubble formation is initiated varies from 8 to 15 m/s, depending on the design of the cavitation tube, which is within the range of feed slurry velocities of some newly developed cells. Feed aeration enhances the formation of micro-bubbles by hydrodynamic cavitation. The study suggests that the fast flotation kinetics of some new cells may be attributed in some degree to the formation of microscopic bubbles

Jun 21, 1905

By L. J. Cabri, J. M. D. Wilson, R Lastra

An image analysis program can search for gold minerals in polished sections by scanning about 100 x 100 back-scattered electron images at a magnification of x400, allowing gold grains as small as 1 micrometre in diameter to be detected. Typically, a c.15 h overnight search of a product smaller than 45 micrometres will scan c.1 500 000 particles, providing data that are not easily obtained through manual operation of an optical microscope. The program locates grains of the correct brightness, acquires gold X-rays from them by wavelength-dispersive spectrometry, filters the data to remove artefacts and record the images and stage locations for subsequent retrieval. At the end of the run, the program allows the operator to verify and identify the grains found. Industrial studies at Canmet have included determining the nature of gold in cyanidation tailings, checking the mineralogy and size of gold grains in samples from an Indonesian Cu-Au concentrator and locating and measuring gold liberation and grain sizes in an ore

Jun 21, 1905

By M. R. Smith, H. Kanli

The impact crusher is a popular device for producing crushed aggregates from non-abrasive rocks such as limestones, offering the advantages of high reduction ratios and relatively low installed costs. To extend the application of a process-flowsheet simulator to the quarrying industry, a mathematical model of an impact crusher was therefore developed using the general crusher models of Andersen and Whiten as a basis

Aug 1, 1995

By F. M. Vokes, P. M. Ihlen

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. Ore deposition was related to three major stages: continental rifting and separation (Vendian-Late Cambrian), convergence (Late Cambrian-Early Silurian) and collision (Early Silurian-Devonian). The first stage included deposition of volcanogenic massive sulphide Zn-Cu and stratabound or stratiform Fe and Zn-Pb(-Cu) on continental margins, as well as less economic Nb and Fe in carbonatites, U, Mo, Ni and V in Alum Shales and orthomagmatic Cr, Fe-Ti and Ni(-Cu). The numerous volcanogenic massive sulphides formed during convergence included Early Ordovician Cu-Zn, mature-arc Cu, Zn, Pb and Fe-oxide deposits, Besshi-type deposits dominated by Cu or Zn in gabbro-intruded sediments and minor Cu-Ni(-PGE), Cu-Mo and skarn deposits. The collisional stage is represented by epigenetic deposits including sandstone Pb deposits (Pb, Zn, Ba, F and Cu) and minor vein deposits with variable Au, Ag, Pb, Cu, Zn, Fe, As, Sb, W and Mo

Jun 19, 1905

By R. J. Pine, J. S. Coggan

Distinct-element modelling has been used to study the mechanisms associated with observed deformation of the western face of the quarry. A complex failure mechanism involving distinct planar surfaces that was proposed for a slope failure in 1967 has been modelled and shown to be plausible. In addition, deep-seated flexural toppling may contribute to the slope instability. Modelling has confirmed the detrimental influence of a raised water-table on the stability of the slope and also indicates that the observed cyclic opening and closing of tension cracks may be attributed to seasonal rise and fall of the groundwater level

Apr 1, 1996

By J. D. Appleton, J. Ridgway, K. B. Greally

Paper presented at the 28th International Geological Congress held in Washington DC, July 1989 (International geochemical mapping sessions). The results suggest that meaningful geochemical maps can be produced from very low-density surveys, and that existing data sets could perhaps be incorporated into such a map series with the use of a system such as Uniras software. There are still many problems to be resolved, however, including the compatibility of data derived from different analytical methods, and the precise methods to be employed will necessarily require international agreement. Sampling densities should be chosen on the basis of the scale of the geochemical and geological features to be distinguished and will vary from region to region. Reanalysis of selected samples from archives to increase the range of elements determined or to unify analytical methods is only likely to be effective if the original survey was at quite a low density

Jul 1, 1991

By A. K. Tripathy, P. K. Pattnayak, H. S. Ray

The effects of water addition on the solid-state reaction between Cr2O3 and Na2CO3 at low temperatures (up to 873 K) were investigated to determine its possible influence on the reaction rate and the degree of conversion to soluble chromate. Experiments at high temperatures were conducted for comparison. It was found that adding water to the mixture before roasting enhanced both reaction rate and yield significantly. The reactions followed the Lesokhin-Tempelman equation at low temperature and the Ginstling-Brounshtein equation at above 973 K; the respective activation energies were 95 and 22 kJ/mol

Jun 19, 1905

By A. M. Tunstall, N. Djordjevic, H. A. Villalobos

The damage zone behind a typical smooth-wall blast in the open pit was assessed by visually examining diamond drill core to identify blast-induced cracking, mapping core rock quality designations to identify changes in fracture frequency and conducting uphole seismic testing to determine changes in rock mass characteristics. The results from the three techniques show reasonable correlation. They suggest that major damage, in the form of fracturing of intact rock, occurs at least 7 m behind the smooth-wall blast and significant damage, in the form of opening and extension of calcite-filled fractures, at least 12 m from the blast. At greater distances the dominant damage mechanism is the loosening of existent joints within the rock mass. In the trachytes at El Soldado these damage mechanisms correspond to peak particle velocities of 2 000, 900 and 500 mm/s respectively

Jun 19, 1905

By A. H. G. Mitchell

Most, if not all, of the six recognised post-Cretaceous, predominantly andesitic mineralised belts in the region are now thought to be subduction-related magmatic arcs. The Inner Carpathian arc and the Eastern Bosnia or Drina-Rhodope arc host numerous vein and replacement deposits with epithermal features and Zn-Pb+/-Ag as the predominant economic minerals. In contrast, the south Apuseni Mountains have produced over 1 600 t Au from epithermal veins but very little Zn-Pb. Recent age determinations and geophysical data from the Baia Mare district of the Inner Carpathians suggest that mineralisation succeeded volcanism by 1-2 m.y. and accompanied crustal extension and the cooling of a large, mushroom-shaped pluton whose boundaries define the mineral district. In the south Apuseni district, mineralisation can be explained by mixing of meteoric with low-salinity metamorphic water expelled during intrusion of mafic rocks into the middle or lower crust. The more continental or cratonic crust in the Drina-Rhodope and Inner Carpathian arcs precluded the input of low-salinity, Au-bearing metamorphic water; the Zn-Pb deposits formed where convecting meteoric water mixed with saline water, possibly introduced through carbonate rocks in the basement

Aug 1, 1996

By G. Zhan, P. Mousset-Jones, G. Danko, J. J. K. Daemen, C. Mezei

Paper presented at the conference Risk assessment in the extractive industries, held in Exeter, 23-24 March 1994, and first published London: IMM, 1994, preprint volume. 18pp., 12 refs. (Originally entitled: Tunnel roof diagnosis using a robotic sensor test bed.) An integral roof diagnosis method is proposed to assist in assessment of risk regarding the stability of an excavation. A Robotic Sensor Test Bed (RSTB) is being developed for the characterisation of roof stability. The sensor test bed consists of a sonic/ultrasonic wave response sensor, a laser surface profiler and a surface temperature sensor. These sensors are mounted on an articulated robot manipulator for performing remote-controlled or fully automated diagnoses. A number of laboratory and field sonic/ultrasonic tests were conducted. A high-energy ultrasonic transducer and an impact device were used to resonate rock slabs. The fracture depths of the slabs were found to be inversely related to the measured resonance frequencies. The agreement between identified and actual dimensions was acceptable. Field tests also showed that loose rock on the surface can be clearly distinguished from solid formation by comparing their wave responses. The robotic laser profiler part of the RSTB was used to measure surface geometry. Different scanning methods are being developed to achieve the fastest and most precise measurements and to provide pertinent information about rock joints and major fractures

Dec 1, 1994

By B. M. England, C. Y. Yang, L. T. Matthews, J. Y. Yin

The domestic concentrate used by the Shanghai Meishan Metallurgical Corporation in Nanjing contains significant siderite, magnetite and haematite, the siderite having a substantial influence on its sintering behaviour. On the basis of experimental findings and published information it is proposed that siderite decomposition starts at c.400 degrees C and results in the formation of CO and/or H2, which then reduces the haematite to magnetite prior to the initiation of high-temperature sintering; inter-mixed particles of Australian haematite and pisolite ores also undergo significant reduction. As the gaseous reduction process is so effective, low-temperature forms of silico-ferrite of Ca and Al (SFCA) cannot form even at high sinter basicity. The bench-scale results were confirmed in a pilot-scale facility whose sinters consisted mainly of magnetite, high-temperature SFCA and glass, which is typical of sinters formed from mixes with high magnetite levels

Aug 1, 1995

By R. H. . T. Garnett

Contributed remarks on paper published in the Transactions, Mining industry section, vol. 100, September- December 1991, A121--45

Jan 12, 1992