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By Thomas S. Jones

This report discusses processing and use of the principal forms of manganese. The focus is on trends in the United States in the 20th century and specifics of domestic manganese material flows as of about 1990. To protect proprietary data, quantitative assessments are limited to the iron and steel industry, which accounts for about 90% of consumption. Nonmetallurgical uses are considered qualitatively. Approximate disposition of a U.S. cumulative consumption during 1901-90 of an estimated 69 million st of manganese is estimated to be iron and steel slag, 69%; nonmetallurgical uses of a dissipative na¬ture, 10%; iron and steel scrap, 9%; National Defense Stockpile, 3%; unidentified and/or including items in service, 10%. In slag from iron blast furnaces and steelmaking, manganese is present as a minor, relatively im¬mobile component, which so far has been uneconomical to recover. Construction and road building are main applications for these slags. Steel slag contains the greater amount of manganese. Studies by others of global manganese fluxes and the effect of human activities on them also are discussed. One source concludes that the main effect of human activities, via deforestation and agricultural activities, has been to increase the rate of transport of manganese to the oceans.

Jan 1, 1994

By L. G. Austin

"This paper is based on the development of the Maza-Austin technique for characterizing thousands of coal particles by approximate analysis of the major inorganic constituents Ca, Al, Si, K, Na, Fe and S in each particle. The technique has sufficient sensitivity to work on small volumes, is fast enough to handle large number of particles within a reasonable period of time, and consists of scanning electron microscopy combined with energy dispersive x-ray spectrometry (SEK-EDS). A computerized SEK-EDS system that allows the automated analysis of hundreds of coal particles per hour' is described. The analysis is based on the location and tracing of coal particles embedded in a polished specimen, the selection of sampling points on the traced particles, the collection of an x-ray spectrum from each sampled point for a defined period of time, and the processing of the x-ray intensity to calculate point composition using ZAF corrections. Procedures for correcting for dead time, background, detector efficiency and spectrum overlap are described. These corrections are essential if reasonably accurate analyses are to be obtained from unknown complex mixtures of the elements in a coal or fly ash particle. Examples are given. INTRODUCTION Coal is a complex mixture of organic and inorganic materials. The inorganic fraction is referred to as mineral matter (Gluskoter, 1978) but can occur in three modes: (i) an observable mineral species; (ii) as cations held by ion exchange to carboxylic groups; and (iii) in chelate complexes. The mineral matter content normally represents a significant proportion of a coal, with an average value of about 15% for US coals (Gluskoter, 1975). The standard methods of analysis of the mineral matter in coals are performed on a sample selected to represent the whole coal as closely as possible, and give the overall inorganic composition in the coal. Such analyses are of limited use for solving problems originating from the behavior of individual coal particles, whose compositions vary widely from the average value. This is particularly true in pulverized coal combustion, where the current methods of predicting the slagging and ·fouling potential of a coal are based on the bulk ash composition, but the fly ash particles which create the deposits originate from coal particles with large differences in mineral compo1ition. Some examples can be found where, in a comparison between two coals, the one with the smaller slagging potential according to the mean ash composition was the one that behaved worst in the furnace (Moza et al., 1980; Koza and Austin, 1983). The u1e of gravity fractionation to assess the slagging potential of pulverized coals has shown that conventional ASTM analysis is not sensitive to differences in the distribution of mineral matter when comparing coals (Borio and Narciso, 1979). Bryer (1979) concluded that coals should be examined for fouling and slagging potential by analyzing gravimetric and size-fractionated coal, preferably pulverized· and ground to the size expected at the mill outlet."

Jan 1, 1989

By T. O. Glover

The Bureau of Mines surveyed unit trainloading and storage installations in the midwestern, eastern, and southeastern coalfields. Nine individual operations were studied in detail as a representative cross section of unit train operations in these areas. Of the nine operations studied, three were in Illinois, two in Kentucky, and one each in West Virginia, Tennessee, Ohio, and Pennsylvania. Information was obtained from coal producers, coal sale agencies, railroads, construction and equipment companies, and power companies.

Jan 1, 1970

By C. W. Davis

There are four parts to this circular and, respectively, they list firms in the Eastern (pp. 5-8), Southern (pp. 9-10), Central (pp. 11-15) and Western (pp. 16-22) United States and Provinces of Canada. Before listing the laboratories and the work performed there, it is proper to make clear what is done and what is not done by Federal bureaus, States, and Territories, as well as by Canada and Mexico. FEDERAL Bureau of Mines. - The Bureau of Mines does not make assays, analyses, or tests for individuals or firms unless they be incidental to investiga¬tions that are of possible benefit to the entire mineral industry. All significant results obtained in this way are made public through published reports. Any mineral sample sent to this Bureau for simple identification will be subjected to a cursory examination.

Jan 1, 1938

By V. F. Parry, J. B. Goodman, W. S. Landers

"This investigation was conducted: under the direction of A.C. Fieldner, chief, Fuel and Explosives Branch, Bureau of Mines, Washington, D. C. The following members of a Technical .advisory Committee were helpful in advancing the investigation: L. C. Harrington, dean, College of Engineering, University of North Dakota; D. F. Pane, president, Sheridan-Wyoming Coal Co.; Carson W. Smith, president, Consolidated goal & Coke Co.; Durbin van Law, consulting, engineer, Denver & Rio Grande Western Railroad; and C. B. Carpenter, professor of metallurgy, Colorado School of Mines. Coal samples from the Northern Colorado field used in the stoker during 3 years of service were supplied through the cooperation of N. C. Brooks, secretary, Northern Colorado Coals, Inc.This report describes the development and practical tests made on a small stoker-fired system for heating service water automatically. The system was designed to take advantage of the favorable reactivity of low-rank fuels, and the objective was to devise a combination of stoker, heat-receiving, and hot-water storage system Which would be automatic for at least 30 days without attention, while heating service water at minimum cost. The system was developed to a point where coal consumption was less than 10 pounds (or less than 100,000 B.t.u.) per day. The total operating cost of hot water for an average-family-was about $1.00 per month, with coal retailing at $6.00 per ton and electric power at 4 cents a kilowatt-hour. The heating system was designed for the utilization of low-rank fuels, but the general features of the double-tank system can be 'employed fuels, either gas or liquid fuels.The Subbituminous Coal and Lignite Section of the Bureau of Mines began investigations on the utilization of low-rank fuels in domestic appliances during 1939. Tests were made on various devices to find out if they were suitable for the low-rank fuels. Most of the available appliances for burning coal have been designed for the higher-rank fuels, and they are not well-suited for burning the lower-rank coals at maximum efficiency, because subbituminous coals and lignite have high bed moisture ranging between 20 and 40 percent by weight, which lowers heating value to the range of 10,000 to 6,500 B.t.u. per pound. They are noncoking, and the ash content ranges between 4 and 6 percent, with a fusion temperature of about 2,0000 F."

Jun 1, 1946

By G. W. Jones, R. E. Kennedy

"INTRODUCTION In the manufacture, storage, transportation, and use of combustible gases and vapors, explosion hazards, which at times may be present when air becomes mixed with the gases and vapors, become of primary importance. Such conditions are especially dangerous where large volumes of gaseous atmosphere are involved, because an explosion under such circumstances is capable of doing tremendous damage to both property and personnel.Because of its interest in safety in the mining and allied industries, the Federal Bureau of Mines has investigated, and published results dealing with, the explosibility of various types of combutible atmospheres. The explosion hazards of natural gases have received attention, and results giving the limits of inflammability and ignition temperatures in air have been determined and published. 4/ Other investigations have shown how explosions of natural gas-air mixtures may be prevented by the addition of nitrogen and carbon dioxide. 5/Because of the increased demand for crude oil for war purposes, the application of secondary-recovery methods of stimulating oil production have received considerable attention during the last few years. The process consists in the injection of natural gas into partly depleted oil wells to cause the oil in the sands to flow into producing wells and so increase the amount of recoverable oil. 6/"

Feb 1, 1945

By A. W. Fahrenwald

Many factors enter into the efficient operation of the reciprocating type of gravity concentrator. Earlier investigators who studied these factor invariably used natural (crushed ore) products for their experiments, but in the present study synthetic products were used. The variables considered were (1) specific gravity of the sand grains, (2) size of sand drains, and (3) shape of sand grains comprising the table feeds. It is recognized, also, that the percentage relationship of the different kinds of grains is a factor affecting results. This factor is variable in one group of experiments but is thereafter kept constant.

Jan 1, 1929

This report describes Phase I of the project --Development of a Mechanized Scaler --performed by Battelle, Pacific Northwest Laboratories for the U.S. Bureau of Mines. The objectives of Phase I were to 1) assess the needs of the industry as related to mechanized scaling; 2) conceive, evaluate and select mechanized scaler concepts; and 3) prepare preliminary designs of the selected machine concepts. To assess the scaling needs of the industry, we reviewed both U.S. and foreign literature, evaluated U.S. scaling accident statistics, reviewed existing mechanized scaling equipment, performed a series of mine visits and telephone interviews with mine operators, and assessed the applicability of a loose-rock detection system. The literature review identified over 25 scaler-related articles. However, little of the information could be used directly in the conceptualization and design portions of the project. Three articles did supply information on a number of machines used in Europe, along with statistics describing their effect on mine safety. For example, the French reported a 50% reduction in the total number of scaling-related accidents and a full 80% reduction in the number of lost-time injuries in the Lorraine mining district.

Jan 1, 1981

By J. R. Thoenen, B. H. Clemmons, A. H. Reed

"INTRODUCTION AND SUMMARYOverall red-ore reserves in the Birmingham, Ala., area were estimated in 1910 by E. F. Burchard 4/. Since then mining has progressed into areas classed by Burchard as ""unavailable for exploitation"" under conditions existing at that time. This is understandable when it is considered that red iron ore was valued at $1.19 a gross ton at the mine in Birmingham in 19102/ and by 1948 had risen 300 percent; 6/ that skips had replaced cars in slope haulage; that mechanical loading and rubber-tired haulage had replaced hand loading and mule or locomotive haulage; and that other more efficient mining methods had been introduced. Intensive study during the intervening 40 years has been given to ways and means for upgrading the low-grade ores in the area and combining or blending them with raw red and brown ores for improved blast-furnace feed.It is reasonable to expect that future progress in mining efficiency and increased knowledge of the beneficiation characteristics of marginal ores will permit extraction of red-iron minerals now considered uneconomic.The Bureau of Mines has undertaken to restudy iron-ore reserves of the Birmingham area to determine what tonnage and grades of mineral are present; what is necessary to make them amenable to mining; what further advancement is possible in beneficia¬tion methods; and where increased production may be obtained in the area if and when required. This study has been underway for the past 2 years, but research into the beneficiation of marginal ores has been in progress at the Southern Experiment Station for the past 30 years. Many results of that research have been adopted in commercial practice in the area. Other results have not been published but are pre¬sented here in condensed form as an important factor in assessing marginal deposits with respect to their importance as ore reserves.An interim discussion of the salient features of past history and progress, as well as the data developed during the years of research in beneficiation at this station and the present field investigation, will make for a better understanding of the present position as well as be useful in evaluating future potentialities. Discussion in this paper is confined to the main Birmingham Basin area, which contains the largest concentration of hematite ores in the district."

Jul 1, 1953

By A. L. Service

Idaho has nearly 6 billion tons of potential sources of phosphorite, 10 to 31 percent P2O5' above and within 100 feet below entry level, the largest potential of any State in the United States. In 1963 Idaho ranked third after Florida and Tennessee in total mine and marketable production of phosphate rock; Montana ranked fourth. This report describes phosphate deposits, mines, and prospects in 10 districts covering most of the Idaho phosphate field. All mine production of phosphate rock in Idaho comes from surface mines and is processed to phosphate fertilizers, phosphoric acid, and elemental phosphorus. Producing districts are Fort Hall (Gay mine), Trail Creek (Conda and Ballard mines), and Crow Creek (Georgetown Canyon mine). FMC Corp. and J. R. Simplot Co. at Pocatello have the largest elemental phosphorus and fertilizer production facilities, respectively, in the State, followed by Monsanto Co. and El Paso Natural Gas Products Co. (formerly Central Farmers Fertilizer Co.). The only other major phosphate processing plant in the State is the phosphoric acid and phosphate fertilizer complex at Kellogg operated by the Bunker Hill Co. In 1963 a plant was constructed and put on line at Monsanto, Idaho, to recover vanadium from ferrophosphorus produced by electric furnace operations in the area. El Paso Natural Gas Products Co. completed construction of a fertilizer and phosphoric acid plant near Conda in 1965. There is a small fertilizer plant producing phosphate fertilizers for local consumption in Soda Springs.

Jan 1, 1966

By K. B. Lindsey

Geologically, the Williston Basin is a large structural depression of sedimentary rock in Montana, North Dakota, and South Dakota and Manitoba and Saskatchewan, Canada. The approximate It-mite of the basin are shown on figure 1; it is roughly circular with a diameter of about 400 miles and contains approximately 120,000 square miles. Although the petroleum potentialities in this area had long been recognized, it had not been vigorously prospected by the petroleum industry because of its geographic location, rigorous winters, depths to possibly productive zones, difficult geological problems, and the fact that more seemingly favorable areas were available for prospecting. With the discovery of oil near Edmonton, Alberta, in the prolific Devonian reefs, an incentive was given to explore for oil in the southeast extension of the same sedimentary trough, the Williston Basin. The Virden field discovery in southwestern Manitoba in January 1951 was a direct result of this southeastward movement. Discovery of this shallow field was followed soon after by discovery of' deep production on the Nesson anticline in North Dakota at Clarence Iverson No. 1 well. North Dakota then became the twenty-seventh petroleum-producing State.

Jan 1, 1954

By S. H. Ash

THE INVESTIGATION of barrier pillars in the Western Middle field is part of the comprehensive study of the mine-water problem in the anthra¬cite region of Pennsylvania by the Federal Bureau of Mines (1, 2, 5, 6, 7, 8,9,10,11,1,2,15,16).8 The Western Middle field is in Schuylkill, Columbia, and Northumberland Counties in eastern Pennsylvania. It has an area of 120 square miles, is 42 miles long from Delano on the east to Trevorton on the west, and is 2 to 5 miles wide. In the Western Middle field are 58 underground water pools containing 38 billion gallons of water (5). Some of the pools overflow to the surface, and the water from others seeps into adjacent mines through permeable barrier pillars separating them from abandoned mines. Several active mines are interconnected to workings in abandoned mines, which are partly filled with water. These mines are separated by barrier pillars that are considered effective only below the altitude of the connections. In some abandoned mines, pumping stations maintain the water at altitudes where the hydrostatic pressure against the barrier pillars is not excessive and does not endanger adjacent active mines. If water in these abandoned mines is allowed to rise to where it can overflow into the active mines, it must be pumped from the active mines at lower altitudes; this materially increases the cost of pumping. It is estimated that from 1944 to 1948 approximately 30 percent of the water pumped to the surface was from abandoned mines.

Jan 1, 1953

By M. J. Ankeny, J. J. Forbes

The United States Bureau of Mines often receives inquiries from the mineral , petroleum , and allied industries concerning the essential steps to be taken in the formation of Holmes Safety chapters and councils . The purpose of this circular is to answer in a general way such inquiries and to relate briefly the history and work of the Holmes Safety Association to the present date .

Jul 1, 1931

By Jr. Boyle

This report analyzes the availability of chromium in the form of ferroalloy products (high-carbon and low-carbon ferrochromium and ferrochromium-silicon) and chromite products (metallurgical, chemical, refractory, and foundry sands) in market economy countries (MEC's). A total of 873.5 Mmt of in situ material, containing 202.5 Mmt of chromium, in 10 MEC countries was analyzed for availability as of the January 1989 study date. Extraction and beneficiation of this in situ material would result in 475.4 Mmt of marketable chromite products. As analyzed, 288.5 Mmt of these chromite products would be available for export or for internal chemical and refractory use and 186.9 Mmt would be smelted in-country to produce 74.3 Mmt of high-carbon ferrochromium, 3.9 Mmt of low-carbon ferrochromium, and 2.0 Mmt of ferrochromium-silicon, all available for export. A network flow model, which includes centrally planned economy countries (CPEC's), was also constructed to analyze world chromium supply and demand interactions for the period 1986 through 1994 and to address a hypothetical North American embargo on direct imports of all South African chromium products beginning in mid-1990. The model shows capacity constraints developing in the MEC high-carbon ferro chromium industry in 1987 and a possible subsequent overreaction by the industry in terms of new capacity additions. The results suggest that sufficient chromium is available to North America should an embargo on direct imports from South Africa be imposed by its governments. However, the effect on export revenues in South Africa is relatively small, and timely increases to world ferrochromium, chemical chromite, and foundry sand chromite capacities would be required.

Jan 1, 1993

By W. W. Adams

Reports received by the Bureau of Mines, Department of Commerce, from State mine inspectors, for November, 1930, showed that 219 men were killed in the coal mines of the United States during the month, an increase of 25 over the previous month and 33 over November, 1929. On the other hand the production of coal decreased, the output of 43,329,000 tons in November being 8,397,000 tons less than in October and 9,005,000 tons less than in November a year ago. The larger number of fatalities accompanied by a smaller output of coal resulted in a higher death rate4 per million tons in November than in the same month last year or in October, 1930. The November rate was 5.05, as compared with 3.55 for November, 1929 and 3.75 for October, 1930. The increase in the rate for the industry as a whole was chargeable entirely to bituminous mines,, as the anthracite mines had fewer fatalities in November than in either of the previous months to which reference has been made. Reports for bituminous mines alone 'allowed that accidents at class of mines resulted in a death rate of 5.12, based on 195 fatalities and a production of 38,122,000 tons. This rate indicated an increase of 55 per cent over the rate for October, of the same year, and 72 per cent over the rate for November, 1929. The October record was 146 fatalities and 44,150,000 tons, and that for November a year ago was 138 deaths and a production of 46,514,000 tons. Twenty-four deaths occurred at anthracite mines in November, 1970: the output of coal was 5,207,000 tons, hence the rate was 4.61 per million tons. During the corresponding month a year ago there were 48 deaths and 5,820,000 tons of coal produced, which indicated a death rate of 8.25. In October, 1930, the death rate was o.34; based on 48 deaths and 7,576,000 tons.

Jan 1, 1930

By Linneas Laage, Thomas Weber, William Pomroy

"Underground mine fires can significantly influence mine ventilation airstreams, in some cases throttling or even reversing airflows. As a result, the performance of a metal and nonmetal mine stench fire warning system, which depends on the ventilation to carry the vital warning signal, under fire conditions is different from performance under nonfire conditions. The safety of underground miners can be jeopardized if the warning signal is delayed. This Bureau of Mines report describes research to investigate fire and stench warning system interactions. A computer model is presented that permits quantitative analysis of stench warning signal delays as a function of fire location and intensity. The results of a case study involving computer simulations of stench distribution in a hypothetical mine network subject to various fire exposures are also discussed. This case study illustrates a technique for identifying the areas within a mine that are subject to unacceptable warning signal delays, thereby enabling preemptive action by mine personnel, such as redeployment of stench injectors. INTRODUCTIONFires are an ever-present threat to the safety of underground miners. Since the smoke and toxic gas produced by a mine fire can be spread rapidly by the mine's ventilation system, mine evacuation must be accomplished as quickly as possible in the event of fire. In metal and nonmetal mines, the most common means of passing the fire warning signal to each miner is the stench system. The typical stench system utilizes ethyl mercaptan, a highly odoriferous organic compound, injected on the surface into the compressed and/or ventilation airstreams. Upon smelling the stench, workers evacuate the mine according to an emergency preplan.Although the stench system has been used successfully for over 60 yr, it has several serious shortcomings, owing to certain chemical properties of ethyl mercaptan and to certain performance characteristics and limitations of present injection systems.Recent Bureau research succeeded in upgrading the overall safety and effectiveness of the stench system through the use of a superior stench odorant and the development of improved stench injection equipment (1).4 This research has also investigated a specialized computer simulation model capable of calculating the precise concentration of stench in any mine ventilation network branch at any time after stench release (2). An adaptation of the computer model now enables the analysis of stench system and ventilation system interactions under the influence of a mine fire."

Jan 1, 1987

Domestic Production and Use: In 1976, 12 companies operated 31 primary aluminum reduction plants, with 3 firms accounting for 63% of production capacity. Washington, Oregon, and Montana accounted for 36% of the total production; Gulf Coast States 19%, Northern States 29%, and other Southern States 16%. Based on published producer prices output of primary metal in 1976 was valued at $3.8 billion. Aluminum consumption by 25,000 firms was centered in the East Central United States. Of aluminum consuming industries in 1976 building accounted for about 25%; packaging 22%; transportation 19%; electrical 13%; , consumer durables 8%; and other uses, 13%.

Jan 1, 1977

By A. J. Fejes

The purpose of this Bureau of Mines report is to provide mining industry personnel and regulatory authorities with a subsidence-reference list and annotated bibliography that will aid them in locating subsidence information and in developing their own subsidence information sources. Over 700 references are listed in the Bureau's subsidence information center bibliography; approximately 600 of these references were obtained for assessment. Of these 600 references, 167 were selected to be rated, categorized, and annotated. All literature referenced in this report was published prior to 1984. Table 1 is a cross - referenced index that classifies and rates selected references with respect to specific keywords. References are rated not on quality of content but rather on applicability to given subject areas. Appendix A is an annotated bibliography of the references listed in table 1 and provides further information of each article to aid the user in selecting articles for specific areas of subsidence technology. Appendix B is a copy of the subsidence information center bibliography.

Jan 1, 1985

By Thomas M. Barczak

The era of the shield-supported longwall face began in the United States a little over 25 years ago. The most fundamental development of the shield in the past 25 years has been an increase in size and capacity and a progression toward two-legged designs in favor over four-legged shields. Is the “bigger-the-better” design philosophy justified? The advantage of the two-legged design is largely attributed to its active horizontal force caused by the forward orientation of the leg cylinders. How do we know this? You might be surprised to learn that shield loading data may suggest otherwise. In addition, what about setting pressures? Should they be set as high as possible? Some people have advocated that setting pressures should equal the yield pressure. Does this make any sense? Is yielding a good or bad thing? These are some questions still worthy of investigation that are addressed in this paper. The first major change in gateroad support was the use of cable bolts to replace conventional wood cribbing particularly in Western mines. Standing support changed very little until the mid-1990s, when Strata Products1 introduced the Hercules and Propsetter supports in Eastern mines and Burrell Mining Products introduced the Can support in Western mines. Since then, there has been a dramatic increase in new roof support technologies for longwall gateroad support. Historically, standing support, including shield supports, have been designed based on a simplistic model requiring the support to have sufficient capacity to support the gravity loading of a perceived detached rock mass. This approach ignores the stiffness of the support and the resulting ground deformation that is known to be critical to roof stability. Recently, a new approach based on the ground reaction concept has been promoted by the National Institute for Occupational Safety and Health (NIOSH) to account for the interaction of the support with the rock mass behavior in achieving ground stability. In addition to gateroad support design, this concept has ramifications for shield capacities, setting pressures, and recovery room support design that challenge current practices in these areas. Although longwall mining has matured into the safest and most productive underground mining method used today, traditional concepts of roof support design and practice should still be evaluated and challenged. Ultimately, advancements in the science of ground control are made by recognizing deficiencies in current theories and thinking outside the box.

By Alden H. Emery, J. J. Forbes

"IntroductionThe data contained in this paper were collected during the course of an investigation which covered 15 representative coal mines in 6 coal-mining States. The purpose of the investigation was to determine by atmospheric sampling how much dust was raised into the air during the various operations of coal mining, such as undercutting with machines, loading coal by hand, and transporting it from the working face to the surface. The data thus obtained were considered from two angles - namely, the possible physiological effect of inhalation and the explosion hazard of the dust. No attempt will be mode to discuss the former factor in this paper.CONDITIONS OF MININGThe mines in which this investigation was conducted were considered representative, and it is believed that the results obtained will suffice for the average dustiness encountered in most coal mines. .All of the coal mined was bituminous, from beds 30 to 120 inches thick. Only the ordinary room-and-pillar system of mining was employed. Daily production ranged from approximately 700 to 1500 tons and the men employed from 150 to 450. Coal was undercut by short-wall mining machines in all mines, with the exception of one in which pick mining was employed. Loading at the face was done by miners; none of the mines used mechanical loaders. Electric drills, both for brushing roof and for shooting coal, were commonly used although some roof work was done with jack-hammers and a. little of both with augers. Coal was hauled by motor, mule, or rope power in end-gate cars with capacities ranging from 1600 to 3600 pounds. With few exceptions, coal was won at the face by dry methods - that is to say, no water was employed fox wetting down the dust either during undercutting, loading, or transportation."

Feb 1, 1927