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By Gerald Pinter, David Nitsche, Márton Bredács, Markus Haager, Andreas Frank

"The reliable prediction of service lifetime of tunnel constructions is of essential technical and economic interest. Polymers used for tunnel liners have to fulfill the requirement of 100 years lifetime. However, today no reliably proven test method is available which confirms such long lifetimes. The current paper introduces a recently started research project which focuses on lifetime prediction of highly flexible, very low density polyethylene (VLDPE) for tunnel geomembranes. Different PE grades in combination with different antioxidant packages are conditioned at elevated temperatures and immersed in different media. Initial results confirmed significant material aging of unstabilized resins already after exposure of up to 34 weeks, at least at the highest exposure temperature of 80 °C. To consider application relevant material properties the material characterization was done by means of tensile tests and dynamic oxidation induction temperature tests. High pressure liquid chromatography was used for further investigation of antioxidant consumption kinetics. 1. INTRODUCTION For a reliable service of modern tunnel constructions a sustainable proofing against water infiltration is essential for the lifetime of the structure. Geomembranes made of polymeric materials have been used successfully for tunnel lining since several decades. Whereas previous geomembranes usually were made of plasticized polyvinylchloride (PVC-P), due to several technical advantages today very low density polyethylene (VLDPE) has become a more and more popular material for such applications. For modern geomembranes, current guidelines expect minimum lifetimes of at least 100 years (ÖBV-Richtlinie 2012). In contrast to this requirement it must be considered that today no test methodology is available which reliably confirms such long lifetimes of polymeric materials."

Jan 1, 2016

By Jr. Matthews

The Candelaria copper-gold deposit is located in Region m of Chile, 805 kilometers north of the capital, Santiago. Candelaria was discovered in 1987, following a six month exploration program. In late 1986, induced polarization (IP) surveys outlined an anomalously high response within the area of interest. The first test hole bad three intersections totaling 49 meters, with an average grade of 1.97% copper. Drilling eventually outlined approximately 390 million tonnes, grading 1.09010 copper and 0.26 grams/tonne gold. Production began in early 1995 and is estimated at 120,000 tonnes copper and 80,000 ounces gold annually.

Jan 1, 1996

By Frank F. Aplan, Edward C. Jr. Dowling, Richard R. Klimpel

Thirteen kinetic models that mathematically describe the flotation process have been statistically evaluated for the flotation of copper, lead and zinc ores. Comparisons have been made for a variety of circuits involving roughing, cleaning, scavenging and regrind followed by cleaning. Variations in collectors, frothers, depressants and activators have been considered. Based on the statistical criteria used for the evaluation, and the reagent, circuit and ore variations studied, the most reliable flotation models have been identified and subsequently used to characterize the metallurgical results.

Jan 1, 1986

By J. L. González-Chávez, A. Ballester, M. L. Blázquez, F. González

In recent years, the bioleaching of sulfidic raw materials has been of great interest. However, the application of this biotechnology is now very limited for many different complex reasons. The mechanism of the chemical and electrochemical reactions taking part in the process is not well understood. The application of electrochemical techniques is useful in its elucidation. Among the common sulfides, galena has been studied very little with respect to its behavior during bioleaching. Therefore, the electrochemical evolution of massive electrodes of lead sulfide in the presence and absence of' a mixed culture of mesophilic microorganisms was investi¬gated by the application of potentiometry, anodic and ca¬thodic polarization and cyclic voltammetry. The agitation rate, the use of pH control and the composition of the nutrient mediums did not have any significant affects on the oxidation of galena. However, the temperature (25 'to 45 °C), the scan rate (4 to 100 mV/s) and the acid used to adjust the pH were significant variables that influenced sulfide oxidation. There¬fore, the peak (600 to 1,000 mV) corresponding to the oxida¬tion of sulfide ions from the mineral was only detected in the presence of a complexing anion of lead. In the presence of bacteria, the peaks corresponding to galena oxidation de¬creased and, at the same time, new peaks appeared both during the oxidation at -300 mV and during the reduction of the mineral surface at 150 and -300 mV. These signals were more important when the attack time increased. The rest potential of bioleached mineral increased with an increase in leaching time, which was related to the electrochemical transformation of the galena surface.

Jan 1, 2000

By John S. F. Dunlop

One of the more difficult problems frequently facing geologists and mining engineers is that of estimating the ore reserves of mineral deposits. Cost conscious mining operations invariably require an accurate knowledge of tonnage and grade for both short and long term planning. A case study is presented, showing how a classical frequency distribution was fitted to a population of drillhole assays. Using these results, a grade- tonnage curve is derived using the Lasky expressions, and the results discussed. A geostatistical analysis is then presented. First, variograms are drawn, models fitted to them and analyses made of drift and anisotropy. Second, simple block kriging is carried out and the results plotted on large 1000 scale plans, suitable for overlay with routine .mine plans. Kriging results are verified using two independent techniques: random kriging on a regular grid and inverse distance weighting. Finally an attempt is made to optimize the drilling grid, and to fully tabulate the total computer running costs for the work described.

Jan 1, 1979

By Steve Kral

The Fourth International Symposium on Hydrometallurgy was organized to give those in the minerals processing field an opportunity to discuss current topics of interest in the broad field of hydrometallurgy. Held in Salt Lake City, UT Aug. 1-5, 1993, this fourth symposium also paid tribute to Milton E. Wadsworth for his many contributions in this area over the past 40 years. The science of hydrometallurgy has made great strides since the last symposium was held 10 years ago. The use of electrochemical principles and techniques has produced encouraging results. For example, the application of in situ electrode spectroscopy has helped to understand the mechanisms operating in hydrometallurgical processes. Sophisticated computer models have been developed to handle the thermodynamic properties of concentrated electrolytes. However, it is up to the hydrometallurgist to continuing working on bridging the gap between theory and practice. The successful application of solvent extraction-electrowinning (SXEW) is one illustration of the successful transfer of technology. Its widespread use in the United States during the 1980s played a significant role in the revival of the domestic copper industry. Currently, electrowon copper accounts for about 30% of total US production. Impressive developments in precious metals recovery have also occurred. Since the last symposium, carbon-in-pulp (CIP) and heap leaching have become widely used in gold recovery. And recovery of refractory precious metals ores and concentrates by pres¬sure oxidation and bio-oxidation have made significant advances. In all these examples, hydrometallurgy has played a significant role in the recovery of minerals and metals from primary sources. In addition, considerable attention has been focused on the treatment and recovery of values from secondary sources.

Jan 1, 1994

By F. H. Mertens

The concentrators of Gecamines are fed by a great variety of ores and produce different types of oxide and sulfide concentrates. It is therefore important to translate the performances of each circuit in terns of dollars in order to reach cost optimization in each mine to product line. A new system has been recently implemented for achieving this objective. Technical data and expenses are collected, allocated and analysed on mainframe applications. On the other hand, optimization and simulations are carried out on microcomputers which are linked with the mainframe files. Various kinds of auditing reports can be produced, including those leading to investments and cash-flow pattern which are

Jan 1, 1991

By Brajendra Mishra, Himanshu Tanvar

Niobium and tantalum extraction industries heavily depend on fluoride chemistry for metal oxide production. This study concentrates on developing a fluoride-free approach utilizing alkali treatment for selective dissolution of niobium and tantalum phases. The application of microwave heating in the alkali treatment of columbite significantly reduced the processing time, providing a higher reaction rate and recovery than conventional heating. A short duration of microwave exposure (6 min) elevated the sample temperature to more than 900 °C, resulting in the rapid formation of water-soluble niobium and tantalum complex. Metal recovery from the solution was attempted through direct precipitation using guanidine carbonate as the precipitating agent, resulting in a mixed oxide product with > 90% purity. On the other hand, solvent extraction was also attempted using methyltrioctylammonium chloride as an extractant, providing a niobium oxide and tantalum-rich mixed oxide with > 98% purity as the final product.

Mar 23, 2024

By T. A. Gray

There are several potential large-volume uses for coal ash in mining-related applications that could be environmentally and economically beneficial to mining companies. Actual usage, however, may be constrained by regulations or by perceptions of coal ash and the potential uses. To identify currently allowed uses and to assess constraints to coal ash use in the eastern coal fields, questionnaires were sent to state coal mining agencies to determine their policies on coal ash utilization and to mining companies to solicit their viewpoints on coal ash utilization. Identifying and understanding the constraints will allow for the development of a coordinated and consistent approach to remove or reduce these constraints and possibly allow for increased utilization of coal ash by the mining industry. This paper summarizes the findings of our investigation.

Jan 1, 1995

By C. D. Harrison

The 1990 Clean Air Act Amendments specify national objectives for reducing sulfur dioxide emissions from coal-fired power plants System-wide reductions can be achieved by combining various emissions controls technologies and allowances, or compliance credits, that can be purchased, sold, or traded. As part of the Coal Quality Expert development project funded by U.S. Department of Energy and the Electric Power Research Institute (EPRI), Black & Veatch has developed an interactive computer tool, the Acid Rain Advisor (ARA). ARA allows the user to develop integrated system-wide compliance plans by comparing the costs and emissions reduction benefits for emissions allowances and various SO2 control technologies such as coal cleaning, fuel switching, and scrubber retrofits.

Jan 1, 1992

By Steve R. La Brooy

Techniques for dealing with copper-gold ores are reviewed. Cyanide has little selectivity of gold over copper, and depending on the reactivity of the copper minerals cut-off grades for gold recovery by direct cyanidation are generally below 0.5% copper for oxide ores and 1 % for sulfide ores. Non-cyanide gold leachants also tend to be reactive to copper. The cheapest option for sulfidic ores is to produce a flotation concentrate for smelting, while transition ores generally need a sulfidisation pre-treatment. The requirement for the concentrate to have a high enough copper grade to be acceptable to a smelter may compromise copper and gold recovery. This can lead to significant gold grades in the flotation tailing, and copper levels in the tailing that are too high for direct cyanidation to be able to recover the gold. Oxidised ores, flotation tailing or other material not amenable to flotation represent the greatest grey area for gold recovery. Copper removal by acid, alkaline or ferric pre-treatment is possible though not generally used. Cyanide pre-leaching to remove copper, followed by copper and cyanide recovery represents a potential option that has been installed at one Australian gold plant, where copper is recovered onto carbon, ahead of the slower leaching gold. Actual cyanide recovery depends on ore mineralogy, allowing for losses as cyanate, thiocyanate, carbonate and ferrocyanide. Alternative options for gold recovery following cyanide leaching include precipitation, ion exchange and solvent extraction of the gold. Ammonia-cyanide leaching may offer another option for more selective gold dissolution from flotation tailing and oxidised materials. A plant is currently under construction in Mauritania.

Jan 1, 1992

By Tony Treasure, Ian Ewart

The EMEW® cell has been developed to overcome a number of inherent limitations in conventional electrowinning technology, particularly the high cost and restricted process windows characteristic of conventional hardware. The EMEW technology has been widely demonstrated to achieve high performance for various metals under chemical conditions well outside the limits required for efficient operation of conventional cells. In particular application of the EMEW cell for recovery of silver offers significant operating and capital cost advantages over conventional Merrill Crowe technology used for cyanide based solutions. The cell also offers process advantages for direct silver recovery from nitric acid solutions. The performance of the EMEW® cell on silver cyanide solutions, producing high grade silver metal in a single step, is accomplished by providing a physical mechanism which presents metal ions to the cathode on a highly efficient and continuous basis. The simplicity of design and operation of the EMEW cell offers the following advantages for silver recovery from cyanide or nitrate based solutions: • High grade product in a single step. • Selective for silver over other metals in the electrolyte. • Wide operating concentration range (100,000 - 5ppm). • Ability of the cell to operated in a variety of acid or alkaline electrolytes. (Cyanide, Nitrate). • Simple liquor reticulation. • No pretreatment required - Clarification, deaeration or zinc dust. • High cmTent density and current efficiency compared to conventional electrowinning cell. • Modular design allows for flexible operation and production rate. • Pilot plant results using full scale cell result in accurate scale up design. • Easy/fast installation - cell banks are delivered pre configured with piping and wiring. • Enclosed cell minimizes corrosive vapor and liquid losses in the circuit.

Jan 1, 2000

By Alan G. Fricker

Cyprus Gold NZ Ltd will be recovering residual free cyanide in barren gold pulp by air stripping. Laboratory investigations by DSIR have indicated additional advantages by recovering the cyanide from pregnant pulp. These are a lower leach pH, a greater cyanide recovery and less carbon consumption. They have a net economic advantage of $1.20/tonne over recovery from barren pulp. The realisation of these advantages is dependent on three crucial technical aspects -optimum pH for dissolution, the absolute loss of cyanide and the stability of the aurocyanide ion. The laboratory investigations described herein address these aspects. Earlier work had indicated that the rate of dissolution of freely revolving gold discs at constant cyanide ion concentration increased with decreasing pH from 11 to 8. Attempts to repeat the work in a more controlled manner by measuring the corrosion potential and current density have, to date, not been reproducible, but do not contradict the earlier observations. Cyanide recoveries and balances were obtained on leaches at pH 10.5 and 9 at the same cyanide ion concentration -the lower pH requiring three times as much total cyanide. Unaccounted-for losses, unfortunately, exceed the accounted-for losses, making interpretation of the balances difficult. Nevertheless, it appears that the additional amount of cyanide at the lower pH of 9 may not be fully recoverable. It may not, however, prove necessary in practice to use more cyanide at a lower pH. Both the gold and silver cyanide complexes remain available for carbon adsorption, as do mercury, copper and iron. Zinc, and probably cadmium, nickel and lead, may precipitate during stripping, which is an environmental advantage.

Jan 1, 1991

By Mike L. Aziz, Keith D. Ferguson, Glenda Ferris

The Equity Silver mine has been a severe producer of Acid Rock Drainage (ARD) since 1982. The mine was closed in 1994 and a compacted clay cover installed, but ARD continues to be produced. Three permanent employees manage the collection and treatment system at the site. The site still poses a significant environmental risk to the environment and downstream users and requires a high level of diligence. Various stakeholders' perspectives of the risk posed by Equity, and what constitutes acceptable risk, will be examined in this paper from a company operation staff, corporate environmental manager and downstream environmentalist perspective.

Jan 1, 2000

By Lana Alagha, Ashraf Alsafasfeh, Amal Al‑Hanaktah

As freshwater resources are becoming scarce, the use of seawater as replacement of fresh water is appealing in order to make mineral processing operations more sustainable. Since froth stability plays a critical role in determining the performance of flotation operations, there is an urgent need to study the effect of frother dosage and seawater on froth stability. In this study, flotation tests in seawater were conducted to examine the effect of frother’s dosage (MIBC) on the froth stability and flotation performance of low-grade phosphate ore. The stability of the froth layer was assessed by measuring the froth growth velocity and the froth maximum height at equilibrium. Results indicated that the best flotation performance was obtained at 75 g/ton of MIBC where ~ 90% of phosphate minerals were recovered. At this recovery value, the concentrate grade was determined to be ~ 70%. Results from froth stability experiments showed that the stability of the froth layer increased by increasing MIBC dosage. At MIBC dosage of 75g/ton, the calculated values of dynamic froth stability and the froth height were ~ 0.4 cm/sec and 16 cm, respectively.

Jan 17, 2024

By Gene R. Block

The most economical method of reclaiming land that has been mined, whether it be in urban areas or in rural areas, is when the final configuration of the mining area is that which is required by the subsequent use. Surprisingly, there are a number of examples of this situation. In the arid southwest where water production for the expanding population is a problem, many urban sand & gravel excavation areas subsequently serve as holding basins for ground water recharge. In other areas of the county where water is not in short supply, sand and gravel excavations can be planned in such a way that subsequent land uses such as parks and homesites can be enhanced by utilizing the excavated areas as a water amenity. Reclaiming land for agriculture is another example of utilizing the excavated area for a subsequent use providing the excavated area has not been mined too deep. Other than replacing the layer of topsoil on the excavated area, the final configuration of the mining area is in many cases ready for the subsequent agricultural use.

Jan 1, 1984

By R. M. Wheeler

For years the blasting industry has recognized eight milliseconds as the minimum delay time interval required between charges in order for them to be considered to fire independently of each other. However, computer analyses of seismic recordings made of several surface mine blasts reveals that this time interval may not always be sufficient for adequate vibration separation to occur. In some situations a combination of short delay periods and low frequency vibrations can result in waveform reinforcement. Various analyses of seismic recordings obtained from single hole detonations can be used to predict delay intervals that may enhance or reduce blast vibration effects.

Jan 1, 1987

By Elżbieta Węglińska, Andrzej Leśniak

The earthquake locations are generally scattered mainly due to a simplified velocity model or seismic event picking errors. The aim of our research was to increase the resolution of the cloud of microseismic events recorded during mining activity in the Bobrek hard coal mine on the 3/503 coalface to delineate seismically active structures using unsupervised machine learning algorithms. We presented results of applying two completely different algorithms for reducing scatter in microseismic location to all events recorded during mining activity on the coalface - the collapsing (proposed by Jones and Stewart in 1997) and condensation (proposed by Kamer in 2015). The collapsing method simplifies the seismic cloud by shifting events inside their error ellipsoids towards local source densities. The error ellipsoids are determined by errors in the measured parameters and seismic network configuration. The advantage of the collapsing method is the partial elimination of blurring of the microseismic cloud. The condensation method reduces the size of the set of seismic events without changing the geometrical information. The reduction of the number of seismic events in the catalog takes place through the condensation of localized events with larger uncertainty into events with lower uncertainty. The spatio-temporal analysis of microseismic events was performed separately on two processed clouds – collapsed and condensed one. We examined how collapsing and condensation methods affect the automatic detection of clusters of microseismicity using density-based spatial clustering of application with noise algorithms. We compared structures detected by the machine learning algorithms in both seismic clouds first created by collapsing and second by the condensation. We identified structures created by mining activity and structures related to the local tectonics activated by mining. The presented results are essential for the prediction of future tremors induced by the mining operation and tectonics and thus ensuring safety in the mine.

Apr 26, 2022

By Erik Vlot

"The mining industry has recognized the advantages of high density backfill or ‘paste’, which is typically pumped with a hydraulically driven piston pump. Due to the discontinuous flow of this type of pump, pressure pulsations can occur in the discharge line. Pressure pulsations are an undesired phenomenon in pumping installations for a number of reasons that include: damage to the pumping system; piping and supports; disturbing noise levels; and even safety risks for operators and maintenance personnel.This paper describes an advanced system on the GEHO® piston pumps, which will prevent virtually no pressure pulsations from occurring, rather than merely reducing the already existing pulsations.INTRODUCTIONThe first GEHO® hydraulically driven piston pump was developed in the mid-1970s. It was an industrial design pump designed to operate in the high-standard industrial environment with regards to operating hours per day, duties, maintenance and lifetime of the pump and spare parts. This type of pump has a proven track record and has been further developed for the type of applications that we are describing today. The special feature of this pump type is its ability to pump extremely viscous slurry with solids content of up to 90% by weight, at high pressures. Typically, in the mining industry, this pump is used for tailings transportation, with a focus on mine backfill and is often referred to as a paste pump.In the 1980’s the hydraulically driven piston pump made its entry into the application of mine backfill, thanks to the high discharge pressure capabilities enabling the mines to pump higher density (i.e. higher solids concentration) slurries and pastes over longer distances.Part of the ongoing development was (and still is) the increase in discharge pressure and flow capacity to comply with the ever growing demands for high power piston pumps. In line with the technological developments and increase in performance duties, the popularity of this pump type increased significantly and many other industrial applications have discovered the benefits of this pump type.Together with the increase in pump discharge pressures and flow capacities the effect of an undesired phenomenon also increased: the phenomenon of pressure pulsations. Before we explore this subject in more detail it is important to first understand the design and the characteristics of a hydraulically driven piston pump."

Jan 1, 2017

By John G. Myers, William A. Vogely, Harold J. Barnett

INTRODUCTION, CONCEPTS, AND MEASUREMENT Introduction Periods in the history of man, from his earliest appearance to the present, are often characterized by the principal materials used. In nearly all cases, the material or fuel is of mineral origin-stone, copper, bronze, iron, coal, and so forth-indicating the principal ingredient of the tools or source of power of the period. Each of these periods represented great improvement over the preceding one in terms of human well-being, as measured by population growth and other indicators (Cipolla, 1978). A major reason for the improvements in production and well-being was the nature of the material or fuel, each successively superior to the preceding, which made it possible to produce more food, fuel, shelter, and clothing with a given amount of labor. If we accept this well-documented description of economic progress as accurate, we may then turn to the consideration of two related questions concerning this development. The first, easily answered,-is why man spent long periods of time (millenia, in many cases) making tools from inferior materials, such as copper, instead of passing directly to superior materials, such as iron and steel. The second, closely related question, concerns the relation between the rate of economic growth and the quantity of mineral reserves available at any time. For the first question, the answer is that the technology required to discover, extract, and process each successive material had to be discovered and developed before the material could be used. Once the technology was available, the new material could be and was exploited widely, raising productivity-output per unit of labor- and consequent consumption per person. This familiar idea underlies a fundamental principle of the economics of resources, namely, at any time, available resources depend upon available technology. No mineral or other raw material is a resource unless the technology has been developed to utilize it. But once the technology is at hand, the new resources associated with it provide the means for economic growth and rising levels of living. This principle is subject to certain conditions. For example, governments or other institutions may prevent a mineral from being used, even though the technology is available. And, if a mineral is located in a remote place, transportation charges may make it uneconomic to exploit. Such minor qualifications do not, however, change the thrust of the argument that technology is the overriding determinant. With respect to the second question, it might seem apparent that the greater the quantity of reserves available, up to some point, the more economic growth will be facilitated. This line of reasoning leads to the conclusion that as re- serves are consumed the quantity available will be reduced and economic growth will eventually be restrained. Reasoning of this sort underlies much popular (and scholarly) thought, in which depletion of mineral and other resources is assumed to lead to constraints on economic growth, through higher materials costs and absolute limitations on materials use. Two important qualifications must be made to this explanation, however, which together

Jan 1, 1985