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By M. S. Hunter, Al Bishop

In 1994, Lone Tree Mine invited Hunter Hawk to participate in a problem-solving arena at their mine located in Valmy, Nevada. Lone Tree was experiencing consistency problems with autoclave valve component quality and delivery. Based upon a prior working relationship at Homestake Mining Company's McLauglin Mine, located in Lake County, California, both customer and vendor enjoyed a measure of rap­po1i and trust - the keys to problem solving communication. This paper is an overview of the problem solving process that has contributed to Lone Tree's excellent record of 95 per cent autoclave availability since 1995.

Jan 1, 1998

By R. E. Gundersen

I have to express my surprise and must send a note of warning concerning the use of polyurethane foam as described in a paper by R.N. Torbin and R.F. Kovar, entitled "Innovative Shaft Lining Method," published in your February 1989 edition. In September, 1986, 177 miners lost their lives when they were exposed to fumes downwind from a fire in a tunnel lined with polyurethane foam. Whilst polyurethane exhibits reasonable fire retardent properties in small-scale tests, mass use in a tubular configuration, exacerbated by the furnace effect of cross-radiation, can lead to a rapid, uncontrollable conflagration.

Jan 1, 1990

By Cesar A. Busnardo

The carbonatite orebody in Jacupiranga is situated some 230km (140-mi) southwest of Sao Paulo and is mined by Serrana S/A de Mineragao, producing an apatite concentrate for fertilizer production and a calcite tailing for cement manufacture (see Figure 1). The orebody (Table 1) is mined by open pit and the total production is 4.5 million mt/year of carbonatite ore with a further 2.2 million mt/year of overburden. The carbonatite low-grade ore (Table 2) is fed to the concentration plant at 460 mt/h , comprising of four parallel lines of grinding, by rod mills 2.7m x 4.5m (9 x 15-ft), operating in closed circuit with hydrocyclones. The grinding circuit product is deslimed in four stages using hydrocyclones and the deslimed product is conditioned with corn starch and subsequently floated, using fatty acids as collector to, recover the apatite.

Jan 1, 1985

By Y. C. Lo

This paper attempts to answer whether or not the mill performance at Bougainville could have, in fact, been predicted by the population balance approach, or whether other special considerations are required to explain their behavior. In recent studies, the plant tests were performed at Bougainville and batch tests were carried out at the Utah Comninution Center. In all tests power measurements were made and several levels of energy input to grinding were evaluated. Also, tracer tests were performed for mill residence time determination. The performance of Bougainville's 5.5 x 6.4 m mill has been very successfully predicted by population balance methods. The prediction errors are only about 1% on product size distribution and 4% on power with a mill volume scale-up of 3790 to 1. It is significant that this approach will reduce the risk of failure in large mill design that has been recognized in traditional methods.

Jan 1, 1987

By David Chastka, Isidro Rivera, Shawna Von Stockhausen, Idit Zarchi

The City of Santa Cruz Water Department is replacing the existing Newell Creek Dam inlet/outlet works at Loch Lomond Reservoir in the San Lorenzo Valley. The project will improve the City’s overall operational efficiency, improve system performance, and improve the safety and reliability of storage for the City’s drinking water supply. The project comprises new inlet works* (three new inlets that control and convey flows into and out of the reservoir, and an intake control building), an inlet/outlet tunnel with a 48-inch conduit to convey flows into and out of the reservoir, and a new outlet structure at the toe of the dam. The outlet structure includes a release point for energy dissipation of emergency drawdown flows, a connection to Newell Creek Pipeline, and beneficial releases into Newell Creek. The project also includes a new dam seepage collection and monitoring system and appurtenant structures such as a culvert bridge over the spillway plunge pool to improve access to the new outlet. Notable complex project components include in-water work to connect the new intake shaft pipes to the three new inlets. The project includes one major milestone with a work window regulated by environmental permits that could only be amended/ extended with approvals from those agencies. If not met, the milestone work would have caused significant delays (potentially up to one year) to the project.

Jun 13, 2021

By Russell L. Dahl

In a continuing effort to improve plant efficiency, United States Steel's Atlantic City Ore Operations completed the rubber lining of its balling drums in late 1982. This resulted in benefits of reduced bentonite consumption, reduced maintenance costs, improved production rates, and lower power consumption. These advantages far outweigh the disadvantages of increased oversize production and increased surging on the roll screen sizing devices. Certain operating characteristics and variables are discussed herein.

Jan 1, 1983

By Roger B. Jr. Herbert

Surface water samples were collected from water accumulations at the surface of a neutral pH mine tailings deposit in Kristineberg (Sweden) where algal growth and iron hydroxide precipitates were observed. Ferric iron in the aqueous samples was determined by (adsorptive) differential pulse - cathodic stripping voltammetry. The analyses indicated that labile Fe3+ concentrations were in the range <20 to 337 nM, while total Fe3+ levels were much higher at 0.9 to 8.3 uM. The labile Fe3+ levels are more than two orders of magnitude greater than would be expected based on equilibrium with ferrihydrite. These results suggest that iron complexation with strong ligands in the surface water competes with iron hydrolysis, and that these ligands may be of algal and/or bacterial origin.

Jan 1, 2000

By Yiming Sun, John Stolz, Jakob Walter, Drew Mason

The Courthouse Commons SEM Tunnel was excavated within 6 feet of cover beneath two buildings in downtown San Diego utilizing high-precision geotechnical instrumentation. The excavated dimensions are approximately 25 feet in diameter and 328 feet in length connecting two in-service detentionlevel security buildings. Presupport includes large-diameter grouted canopy pipes and smaller pipe spiles. Initial support consists of fiber-reinforced shotcrete with lattice girders. This paper presents observed ground and structure behavior and lessons learned. During construction an unanticipated brick structure was encountered, and methods were developed to improve adhesion of shotcrete to sandy soil and to reduce rebound

Dec 1, 2022

By Robert A. Bauer

Investigations of bedrock within subsided areas over abandoned coal mines reveal) very little disturbance of the bedrock. In areas that have surface subsidence of .3 to 1 m (1.0 to 3.25 ft), examination of cores from exploration drilling and investigations of the boreholes by means of closed circuit television have shown that fractures are spaced at least .9 to 3.6 m (3 to 12 ft) apart and are located within a zone 6 to 15 m (20 to 50 ft) above the collapsed area in coal mines 42.6 to 112.7 m (140 to 370 ft) deep. The dip of the fractures ranges from 25 to 60 degrees, cutting across nearly horizontal sedimentary bedding planes. Typical core recovery is 80 to 95 percent within the subsided areas and 100 percent outside the subsided areas.

Jan 1, 1984

By Clément F. Bernier

One of the chief sources of the world&apos;s supply of asbestos lies in a belt of ultrabasic rocks which runs northeastward through an area called the Eastern Townships, south of the St. Lawrence River in the Province of Québec. The productive portion of this belt extends from the town of Asbestos in the south, for a distance of some 9,5 km to beyond the village of East-Broughton. The first discovery of asbestos in this region was made in 1874. Only crude fibre was produced until 1888 when the first mill was erected near the town of Black Lake. Since the inception of the industry, almost 100 years ago, no less than 100 different compa¬nies have been formed and 46 different mines have been operated. There are presently 5 active companies in the area providing direct employment for 4100 workers, down from 6000 during the seventies.

Jan 1, 1984

By Brain W. Lawrence

Sublevel stoping generally is a large-scale open stoping method. It sometimes is referred to as long-hole or blasthole stoping. This method usually is applied to strong ore bodies that require minimal support and are surrounded by strong country rock. The ore body should be fairly regular in shape and well-defined. The dip of the footwall normally should be sufficient to allow broken ore to gravitate freely, although the method has been adapted successfully to mine some of the flatter ore bodies. Sublevel stoping is not dependent on the width of the ore body. Widths of less than 6 m (20 ft), however, make the utilization of long-hole drilling techniques more difficult. The main criteria for sublevel open stoping are competent ore and stable host rock, regular ore boundaries, and a footwall dip that exceeds the angle of repose of broken ore. Basically, the method entails providing access to the ore body at various subintervals between the main haul- age levels in order to drill and blast the intervening ore. Stope drilling is carried out from drilling drifts on the sublevels, and the ore is blasted in slices towards an open face, which generally is vertical on the downholes and may be inclined towards the open face for the up holes. The blasted ore gravitates to the bottom of the stope and is collqcted through drawpoints. Fig. 1 illustrates a typical sublevel stoping mine. The method requires extensive ore body development with relatively high capital expenditures. How- ever, much of the development is in ore, and production costs are comparatively low. Productivity rates are in the 13.6 to 27.2 t (15 to 30 st)/manshift range. The drilling, blasting, and loading operations are performed independently, and equipment utilization is high. Large outputs can be obtained with few units and limited personnel. Dilution with waste rock may occur if ore boundaries are irregular or if caving occurs, but 100% of the ore within the stope usually is recovered. Pillar recovery sometimes is a problem. It is at this point that most of the waste dilution occurs. At the time data was gathered for this report (1973), the sublevel open stoping method was used by more than 21% of the metallic ore mines in the US (9 out of 42 mines producing 1088 + t/day (1200 + stpd) and provided more than 12% of the total metallic ore production from these mines. DEVELOPMENT Access to a sublevel open stope mine is gained by a slope or shaft that is normally sunk in the footwall of the ore zone, away from any possible effects from blasting or other production operations in the stoping process. Main level interval is selected and usually varies from 45.7 to 121.9 m (150 to 400 ft), depending on the vertical extent of the ore body, the number of drawpoints required to maintain output, and the eventual stope height. The main haulage drifts are located at the bottom of the stope horizon, either directly in ore or in the footwall, with access crosscuts at intervals. Raises are driven up through the ore to connect to the level above and provide access and ventilation to the sublevel drilling drifts, which are driven horizontally in the ore for the length of the stope. Depending on the drawpoint system to be used, the stope is either undercut by a raise-and-cone system, from a scram or slusher drift, or simply provided with a drilling drift from which access is made at intervals to the main haulage level. A raise driven either at the end or in the middle of the stope (if stope access is from both ends) provides a start for opening up a vertical slot across the stope to establish a free or open face for long-hole drilling and blasting. Sublevel stoping has proved to be a relatively safe and economical system.

Jan 1, 1982

By W. Petruk, D. B. Sikka

Lithium-bearing lepidolites from three deposits in the province of Goias, Brazil, were investigated to determine whether there is a correlution between the lithium content of the mineral and the color of lepidolite and associated tourmaline. Such a correlation can be a useful guide to field geologists for outlining high-grade lithium ore zones. It was found that mauve-pink lepidolite associated with pink tour-maline, and brownish lepidolite associated with black tourmaline have high lithium contents, but that the color of lepidolite is not due to lithium. The pink color of lepidolite and tourmaline is likely due to Mn3+, and the brownish tint of lepidolite and black color of tourmaline to Fe3+. Lepidolites appear to be lithium- rich when the lepidolite and associated tourmaline contain relatively high amounts of Mn3+ and/or Fe3+.

Jan 1, 1988

By J. F. Abel, R. J. Spengler

Convergence measurement across the 17.4-m (57-ft) high shaft station/loading pocket at Mt. Taylor provided continuing verification of stability and safety. Three levels of instrumentation, consisting of three lines each, were installed and monitored. The instrumentation showed that the flexible lining restrained the adjacent rock. The flexible lining consisted of pea gravel with neat cement between rock and liner plate, wooden crush blocks between liner plate and steel ring beams. The loading pocket is elliptical, 11.6 x 9.6 m (38 x 31.5 ft) inside diameter. The crush blocks were designed to allow 15 cm (6 in.) of convergence. Maximum predicted convergence was 7.0 cm (2.75 in.), and 5.7 cm (2.25 in.) was measured. Convergence measurements also demonstrated decreasing deformation with respect to elapsed time and distance from the measurement station to the temporary bottom of the shaft excavation.

Jan 1, 1987

By Emily Sarver

"Across all sectors and commodities, a common theme is driving progress in raw resource supply: sustainable development (SD). Over the past few decades, the mining and minerals industries for their part have undertaken significant and intentional changes at every level to become more responsible — no longer to just their shareholders, but also to the environment, to the communities in which they operate and to society at-large. Led by some of the global majors, these industries have indeed helped to define and operationalize the basic principles of sustainable development. Now in the midst of a full-on cultural shift, they are also key players in the continual effort to re-examine and calibrate practices to meet dynamic and increasingly complex objectives.SME’s technical position statementAs a home for so many technical experts and practitioners, SME has long recognized the importance of a commitment to sustainable development by the mining and minerals industries. In April 2016, the Society formally adopted a technical position on the topic following years of participation in, and support for, related activities. The full position statement appears below. It was drafted, revised and presented for approval to the board of directors by SME’s Sustainable Development Committee.Statement of Technical Position on The Mining Industry and Sustainable Development:• The National Environmental Policy Act of 1969 (NEPA) and the Surface Mining Control and Reclamation Act of 1977 (SMCRA) imposed considerable environmental restrictions on the mining industry; SME has always reinforced strict adherence to the laws.• In 2002, SME established a Sustainable Development Committee to lead its efforts in this area and to propel the organization into global prominence.• SME is a signatory to the Milos Statement of 2003 on Sustainable Development, so it is committed to providing scientific, technical, educational, and research skills in minerals, metals and fuels.• SME recognizes that SD programs adopted by the industry have a tangible return on investment through brand recognition and loyalty, facilitation of permitting, reduced occurrence of community protests and vandalism and diminished political risks.• SME actively promotes educational programs that encourage professional growth and interaction with the engineering professional community through books, articles, symposia, short courses and/or conferences on sustainable development in the mining and minerals industries.• SME has developed abundant expertise to provide balanced advice to government bodies, congressional staff and other interested organizations."

Jan 12, 2017

By Robert S. Ondrey, Robert A. Haney, Kenneth G. Fields

As part of an MSHA program to assess the effectiveness of dust control parameters for longwall mining operations, respirable dust studies were conducted on six longwall sections. The purpose of these studies was to evaluate the influence of airflow and production on longwall dust control. The sections were sampled for 3 to 35 shifts. In addition to dust, ventilation and production measurements, other dust control and operational parameters were measured. The water spray system at each operation conformed with generally recommended practices. Therefore, improvements to the dust control system would be most appropriately achieved through improvements to ventilation along the face. Two methods of assessing the influence of ventilation and production were used. For two of the six mines where extensive sampling (22 and 35 shifts) was conducted, multiple linear regressions were used to relate the dust concentration versus airflow and production data. For these two mines, statistically significant correlations existed between concentration and both production and airflow. The multiple regressions fit to the data indicated that for every 0.47 m3/s (1,000 cfm) increase in airflow, there would be approximately 0.04 to 0.07 mg/m3 reduction in dust concentration; and, for every 1,000 ton increase in production, there would be approximately 0.15 to 0.50 mg/m3 increase in dust concentration. For the four mines with limited data (3 to 10 shifts), as well as for the two mines with extensive sampling, an average ratio of airflow per ton of coal mined was calculated by proportioning the airflow to production and the designated occupation personal respirable dust exposure to a 2.0 mg/m3 concentration. The airflow-to-tons ratio required to maintain a 2.0 mg/m3 dust concentration ranged from 0.0038 0.0071 m3/s per ton (8 to 15 cfm/ton). Both of these data treatments were used to calculate airflow requirements based on normal production rates. For the two mines where both the regression and airflow-to-tons ratio were calculated, results from the two methods agreed within 25 percent.

Jan 1, 1993

By E. A. Martell, K. S. Sweder

INTRODUCTION Lung cancer in uranium miners has been attributed to alpha irradiation of basal cells of the bronchial epithelium by radon daughters, primarily by 7.7 MeV alphas from polonium-214 (Altshuler et al., 1964). It also has been was observed that for a given cumulative radon progeny exposure, uranium miners who smoke cigarettes have an incidence of lung cancer about 10 times higher than nonsmoking miners (Lundin et al., 1969). It has been pointed out that the large excess of lung cancer deaths among smoking uranium miners is a multiplicative effect (Doll, 1971), which suggested possible synergistic interactions between airborne radon progeny and cigarette smoking. Experimental studies of the complex pattern of interactions between radon progeny, cigarette smoke particles, and the cigarette smoking process are in progress in our laboratory. Preliminary results, reported elsewhere (Martell, 1981), implicate alpha radiation from indoor radon progeny in the etiology of lung cancer in all cigarette smokers. Cigarette smoking produces high concentrations of smoke particles of low mobility and respirable size--particles between 0.5 and 4.0 µm in aerodynamic diameter (see below). The attached fraction of indoor radon progeny is highly dependent on the air concentration of small particles from cigarette smoking and from other combustion sources (Martell, 1981). The size distribution and other properties of radon progeny associated with cigarette smoke particles enhances their effectiveness in the induction of bronchial cancer in man. In this paper we discuss the properties of radon progeny associated with cigarette smoke, the fractionation of radon progeny and modification of their aerosol properties in burning cigarettes, the role of 218Po in these processes, the production of insoluble 214Pb and 212 Pb enriched particles in burning cigarettes, and the consequent differences in the patterns of polonium isotope alpha irradiation in the bronchial epithelium of smokers. EXPERIMENTAL PROCEDURES Experimental methods used in these studies involve the use of small experimental chambers of known radon and radon progeny concentrations in combination with aerosol collection and sizing techniques and sensitive radioactivity detection methods. The use of low-level [ß-] counting for radon progeny determination, providing a measure of 214 Pb plus 214Bi activity, makes it possible to carry out chamber experiments with small radon emanation sources and relatively low air concentrations of radon and radon progeny concentrations in the range from 100 to 1,000 pCi per liter. Thus, for example, in a typical experiment we use a 10 nanocurie 226Ra solution standard in a 10 liter chamber, providing an equilibrium concentration of 1,000 pCi of radon per liter. In small sealed chambers, radon progeny plate out rapidly on the chamber walls, with steady-state concentrations of airborne progeny less than 2 percent of equilibrium levels. This is experimentally convenient because, upon introduction of high concentrations of cigarette smoke particles or small particles from other sources, there is a systematic ingrowth of attached radon progeny, providing a tagged aerosol source of known age and radon progeny composition. In some chamber experiments a 226Ra solution standard of small volume, acidified to O.1N HNO3, was used as the radon emanation source. When used with a bubbler the holdup of radon in an 8 ml volume of 226Ra solution standard at 0.1N HN03 was only 2% of the total radon in the chamber at equilibrium. For experiments with 212Pb-tagged aerosols, we used a dry Ba(228Th) stearate emanation source prepared by the method of Hursh and Lovaas (1967). 226Ra and 222Rn determinations were made by radon gas counting. The 222Rn in a sealed air or water sample is transferred, using helium gas as a carrier, successively through a dry ice cooled trap at -80°C to remove water, through ascarite to remove C02, and through a small activated charcoal trap at -80°C to collect the 222Rn. Subsequently, by heating the charcoal to 400°C, the 222Rn is transferred next to an LN2-cooled capillary trap, and finally into an alphascintillation counting cell of the type described by Lucas (1957). As already stated, radon progeny activities were determined by low-level [ß-] counting, which provides a measure of 214Pb plus 214Bi. The radon progeny samples, collected on efficient Delbag polystyrene micro-fiber filters or on impactor foils, are placed in close, sandwich geometry between two thin-walled flow counters inside shielding anticoincidence counters and a 15 cm thickness of steel shielding. This configuration provides nearly 4II geometry and a low background of only 0.25 to 0.30 cpm. Aluminum absorber was added to provide a combined thickness of absorber and counter wall exceeding 7.0 mg/cm2 to eliminate the variable contribution of 7.7 MeV alphas from 214Po. 212 Pb determinations also were carried out by low-level [ß-] counting, in this case using a combined absorber and counter wall thickness of 9.0 mg/cm2 to eliminate contribution of 8.8 MeV alphas of 21 Po. In each experiment the [ß- ]activity data were corrected for decay to an appropriate common reference time for assessment of activity distributions.

Jan 1, 1981

By Lawrence M. Brennan

Early in 1971 the Peabody Design and Preparation group began engineering on a preparation plant which was to process eight mil- lion tons per year of raw coal. For the first five or six years this product was to be furnished 50% from surface mining operations and roughly 50% from underground operations. By early 1980, 1008 of the production was to come from underground mines. Because of the large annual commitment from Randolph Preparation Plant, it was essential that the plant operate with minimum down-time. As usual, capital costs were to be kept at a minimum. Before we discuss the details of design, it would be best to discuss the overall picture. Underground production to be pro- cessed through Randolph Preparation Plant was to be delivered by means of one mile overland conveyor from Baldwin #1 Underground Mine to the plant. Surface Mine production was to be delivered by means of 100-ton haulage units dumping in a 1,000-ton capacity hopper. Because of the changing production rates in both the underground and surface mines as well as the great difference in size consist, it was decided that it would be necessary to divorce the plant as much as possible from production. For this reason, twin 6,500-ton raw coal silos were constructed to separate the two coals as well as allow blending. The preparation plant itself, was to be designed to Operate two shifts per day, five days per week, at an average rate Of 2,200 tons per hour with a maximum rate of 2600 to 2800 tons per hour. Coal was to be delivered to our customers by means of rail haulage at both unit train rates and plant process rates. The surface mined coal, after discharging into the 1,000-ton R.O.M. hopper, is fed by means of two 72" wide reciprocating feeders onto a 72" wide steel cable belt. The steel cabled conveyor discharges the R.O.M. coal onto a fixed grizzly, scalping out a percent of the 6 x 0 coal. The balance is fed to a 12&apos; x 27&apos; Rotary Breaker. The material passing through 6" round hole screens is added to the 6" x 0" from the scalping screen. The 6" x 0" is conveyed to the top of one of the 6500 ton silos designated for surface coal. Material that is not broken to pass the 6" breaker screen is discharged to a bin and disposed of with plant refuse.

Jan 1, 1976

By Dale W. Norris, John A. L. Campbell

INTRODUCTION Optimization, as measured by productivity gains, is being achieved in our nation&apos;s preparation plants principally by automation, economy of scale, and reducing maintenance. Increased tonnage per unit of investment, a1 so a measure of optimization, is being achieved by breaking with tradition and increasing plant utilization, while simultaneously improving on equipment re1iabi1ity. Improved qua1ity, another measure of optimization, is being attained through technical innovation. This review will concentrate on state-of-the- art unit operations and processes, and will not discuss emerging new technologies which are covered in detail in other presentations of this symposium. It is recognized that much of what will be discussed in this paper is not unique to the fine coal circuit, but is equally applicable to the entire preparation plant. However, the areas reviewed are the principal means being used today to optimize an existing preparation plant&apos;s fine coal circuit. Prior to designing and optimizing a fine coal cleaning circuit, the question that must first be answered is, "Do we even want a fine coal circuit? This is a much more complex question than is readily apparent, as most of you recognize. It can be argued either way. In the final analysis the "bottom line" will hold (Blackmore, 1982). If your sales contract a1 lows it, and the selling price can justify it, you most assuredly want to build a fine coal circuit into your preparation plant. In general today, most new preparation plants do have fine coal cleaning circuits. The purpose of fine coal cleaning has changed with time. Some of the early applications of fine coal cleaning were to prevent stream pollution rather than to prepare a product for market (Merrill a Pennington, 1962). During the 50&apos;s, 60&apos;s and into the 70&apos;s the principal thrust of fine coal cleaning was in metallurgical coal preparation. More recently, the emphasis of the 80&apos;s is on steam coal processing. There is no consensus on what is fine coal. Traditionally, fine coal would be anything below 1/4" in size. Because of the advances being made in intermediate coal cleaning processes, i.e. heavy media cyclones and jig cleaning, this discussion will define fine coal as -28 mesh (Aplan, 1987). Figure 1 is a plot of the size ranges of a large number of U.S. bituminous coals. In general the -28 mesh fraction of a bituminous coal will be between 7% and 18% of the ROM feed with reported ranges of 5% to 40% (Aplan, 1987). Consequently, traditional fine coal cleaning is general 1 y involved with a re1 actively mi nor portion of the coal feed. Every effort is taken both in terms of mining and preparation to keep it that way because of the high cost of cleaning fines. The move away from this posture, namely, the techniques to fine grind coal to liberate pyrite is probably the biggest challenge facing fine coal processing today.

Jan 1, 1988

By T. Bednarski, T. McCallum

"Physical impurity transfer in solvent extraction (SX) has a significant impact on operating costs, electrowinning (EW) performance, and cathode quality. Some operations use a wash stage to limit impurity transfer by diluting the entrained pregnant leach solution (PLS) to prevent direct transfer to EW. Wash stage operating conditions vary impacting impurity transfer. A number of factors impact dilution efficiency including mixer continuity, wash aqueous acidity, and organic quality. The impact of these variables on dilution efficiency was studied and compared to current industry practice. INTRODUCTION With the exception of iron, impurity transfer in copper SX is due to PLS carryover in the loaded organic via aqueous entrainment and crud movement. The quantity of impurity transfer is influenced by many variables including operating set points, organic quality, and settler housekeeping. Crud management and treatment is a common practice aimed at minimizing transfer of impurities to EW. Crud is a complex solid-stabilized emulsion of aqueous and organic[9]. As such, it contains a large aqueous component and the associated impurities (from the PLS). A common practice is to remove interfacial crud to prevent movement. Additionally, mixer continuity can be altered to enable compaction and improve the efficiency of interfacial pumping[10]. Understanding the factors impacting aqueous entrainment and optimizing the available controls should be a key focus for any operation. Aqueous entrainment in the loaded organic can be impacted by: • Mixer continuity • Mixer organic/aqueous (O/A) ratio • Mixer speed and impeller type • Organic and aqueous depths • Specific settler flow • Use of settler internals (picket fences, coalescing packs) • Organic quality • Design and operation of loaded organic tanks Conventional thought is to run the E1 mixer in aqueous continuity to reduce aqueous entrainment. Generally, O/A ratios close to 1:1 result in improved metallurgical and physical performance. Mixer speeds should be chosen to achieve acceptable stage efficiencies while minimizing over-mixing. Organic depths can be increased in the E1 stage to increase retention time and minimize aqueous entrainment. Settler internals can also be used, but require maintenance to maintain effectiveness. The quality of the plant organic inventory will impact physical performance. Poor organic quality can lead to higher phase disengagement times increasing impurity transfer to the electrolyte. Additionally, the design and operation of the loaded organic tank can impact impurity transfer[8]. Despite the variables that can be used to reduce aqueous entrainment and crud movement, impurity transfer is still an issue in some operations. For these operations with high PLS impurity concentrations, a wash stage may be beneficial to manage impurity transfer. Understanding factors impacting wash stage performance is important to optimize performance and limit impurity transfer."

Jan 1, 2016

By E. Valdiviezo, J. F. Oliveira

Adsorption of residual flotation reagents onto equilibrium fluid cracking catalysts is a promising method of purification of flotation process water. In the present paper, adsorption of sodium dodecyl sulphate (SDS), dodecyl ammonium chloride (DAC) and sodium oleate onto a spent catalyst from petroleum industry was studied by analysing the residual concentration of the surfactant after contact with the zeolite catalyst. The adsorption of the DAC was rather low but SDS and sodium oleate presented a high affinity for the catalyst surface. The loading capacity was 4.2 kg/ton for SDS and 5.5 kg/ton for oleic acid. After the treatment of the loaded catalyst with a HCI 1 N solution these surfactants are desorbed and the catalyst may thus be regenerated. This would be an additional advantage to its low cost, not to mention its condition as a discarded product and its availability in large tonnages.

Jan 1, 1995