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By Edgel P. Stambaugh

Oxides are important for use in the production of metals, ceramic hardware, paints, permanent magnets, magnetic recording tapes and many other uses. In some of these applications, particle morphology, degree of crystallinity, purity, and homogeneity are relatively insignificant, while for other uses, these same properties are of critical importance. Many conventional processes are based upon recovery of the oxides from aqueous solutions by processes which include neutralization, evaporation of solvent, and precipitation of a complex salt. Consequently, many of these techniques lead to oxides of low quality. There is a growing demand for oxides of high quality, i.e., materials with narrow particle size distribution, controlled particle morphology, high purity, few structural defects, and high degree of crystallinity and homogeneity. This demand has prompted industry to search for new approaches for the manufacture of these special materials. One new approach for preparing high quality oxides is hydrothermal precipitation. This process has been used for preparing simple oxides such as ZrO2; mixed oxides such as ZrO2-SiO2; and complex oxides such as BaTiO3. These oxides were prepared in a high state of purity with a high degree of crystallinity and., in many cases, without the addition of precipitants. Many impurities- that are normally precipitated by conventional methods such as neutralization present no problem since they remain in solution. Nature of the process and its applications are discussed in this article.

Jan 1, 1977

By D. -P. Georgescu

A native sulfur mineralization associated with pyrite and iron oxides containing 20% iron was quarried in Calimani Mountains, Oriental Carpathians. The wastes resulted from this exploitation activity, with a volume of 33 millions m3, were stored in four dumps while the wastes resulted from ore processing using flotation and the subsequent treatment were disposed of in a settlement pond. The investigations carried out in the entire mining area focused on the following two aspects: - the impact of environmental factors mainly on the hydrographic network; - the characterization all pollution sources, namely dumps, leachates and the quarry and the assessment of acidic drainage generation. The total sulfur content of the excavated ore was 3.8% while in dumps it ranged between 0.54 and 1.06%. Analysis of samples collected along the hydrographic network, draining the mining area, resulted in pH values ranging between 1.7 and 2.83 as well as high concentration of iron (4525 mg/L to 1.6 mg/L), copper (1.87 mg/L to 0.04 mg/L) and zinc (13.13 mg/L to 0.3 mg/L). Samples from the quarry, the dumps and the tailings pond were analyzed in order to deter-mine: - the maximum potential acidity (MPA); - the acid neutralization capacity (ANC); - the net acid production potential (NAPP).

Jan 1, 2005

By M. Nyoka

Consideration of the economic, environmental, and social impacts associated with the life-cycle of a technology is of increasing importance for decision-making in industry. It has been suggested that economic assessment of technology deployment projects requires the translation of associated environmental effects into monetary values. This paper introduces an approach for identifying and evaluating environmental damage in monetary terms. The approach groups the environmental impacts associated with a technology life-cycle system into four main criteria: air, water, land, and mined abiotic resources. The valuation of the impacts on the resources consists of an economic cost benefit analysis (CBA) procedure that comprises four steps: the compiling of an impact inventory, a monetary valuation of the inventory, discounting, and a risk/uncertainty analysis. The monetary valuation step for impacts on air resources is primarily based on published externality costs for Europe and the United States, which are adopted and converted to reflect the South African context. Local opportunity costs are utilized for the other resource criteria. The damage costs are transformed into South African Rand at 2005 prices. The paper demonstrates how the approach may be applied in the assessment of projects in the metallurgical industry. Shortcomings in the approach are identified. For example, not all of the aspects that are considered necessary to assess environmental performances comprehensively can be valued in monetary terms. Also, certain values, specifically those pertaining to opportunity costs, need to be determined on a case-by-case basis. Furthermore, the uncertainties associated with the indicators obtained may strongly influence the usability of the results of an environmental performance assessment, e.g. future damage costs will change with fluctuations in the markets. It is concluded that although such an approach has merit in increasing the understanding of the potential financial implications of a technology?s environmental performance, further research is required to improve the approach described if it is to be used further in the South African metallurgical industry. Damage cost estimates that are specific to South Africa need to be developed to reduce uncertainty, and the combination of both quantitative and qualitative approaches is recommended for comprehensive sustain-ability decision-making.

Jan 1, 2007

By B. W. Jong

As part of the Bureau of Mines program to develop substitutes for critical and strategic materials for metallurgical applications, the Tuscaloosa Research Center has evaluated the effect of additives and starting materials on the sintering and strength properties of sialon (silicon-aluminum-oxynitride) compositions fabricated by conventional pressing and sintering techniques. Sintering and MOR (modulus of rupture) data were developed for sialon compositions produced from three components, Si3N4, A1203, and AIN. When doped with Y203 to aid in sintering, the highest MOR values were obtained with compositions containing between 20 and 30 mole-pet (A1203 + AIN). The effect of the crystalline phase of the Si3N4 and Al203 used in the three-component system on MOR also was investigated. Alpha-Si3N4 and ?-A1203 were found to be the best starting materials. A sialon composed of 67.4 mole-pct a-Si3N4 plus 32.6 mole-pct (?-AI203 + AIN), doped with 5 wt pct Y203, had MOR values at 25°, 1,200°, and 1,400° C of 40,300, 40,300, and 31,100 psi, respectively. Samples of this composition doped with Gd203, MgO, Zr02, and ZrSi04 also were evaluated. The ZrSi04-doped sialon had higher MOR values than Gd203-, MgO-, and Zr02-doped materials but lower MOR values than the Y203-doped sialon. The MOR values of ZrSi04-doped sialons were 25,000 and 25,900 psi, respectively, at 25° and 1,400° C.

Jan 1, 1981

By J. G. Bennett

Coal consumption has increased globally by 57% over the last ten years. Underground mining typically provides coal of the highest calorific value and accounts for the greatest proportion of production. Despite a negative environmental image and indeed impact, this industry appears likely to thrive on the global scale for many years to come. Such mining consumes large amounts of electricity with implications for carbon dioxide emission at power plants and emits substantial quantities of the powerful greenhouse gas methane. In response to this significant carbon footprint, the European Union has funded research to examine the potential for a range of improvement technologies in a project entitled Low Carbon Mine Site Energy Initiatives (LOWCARB). Coal properties related to seams and mines, together with longwall characteristics, provide the basis for research into modelling optimally efficient methane drainage with a view to assisting mining as well as maximising electricity generation at surface and hence oxidation of the methane. Possible systems for the oxidation of very low concentration methane in ventilation air, which contributes the greatest greenhouse gas impact due to the volumes emitted, have been studied and modelled. Simulation and investigation of intelligent optimisation of electricity demand patterns provide the basis for reducing the demand peaks at mines and hence the cost and ultimately the carbon footprint of a mine, while specific investigations have been undertaken into ventilation efficiency at an unusually challenging mine and simulation of mine water pumping in order to develop an innovative method to monitor pumping systems efficiency. For post-mining use, the potential of disused shafts for compressed air energy storage to improve the operation of future electricity grids with high renewable energy penetration by reducing peak generation capacity requirements has been studied. While underground coal mining will always by definition be related to a significant carbon footprint, this paper provides an overview of a set of initiatives that can make a positive environmental impact while controlling costs across a huge global industry.

Aug 1, 2013

By Wynne Potter

"On the west coast of Cape Breton Island four coal basins have been identified, varying in age and extending from Port Hood northeasterly to Chimney Corner. Those of Chimney Corner - St. Rose in the north and Port Hood in the south belong to the Pennsylvanian Riversdale Group while lying between them are the coal basins of Mabou and Inverness belonging to the younger Pictou Group. Almost all of the coal basins are submarine and coal mining was carried out on all basins at various times. The seams in all basins dip steeply seaward at angles from 10 to 20 degrees but were found to flatten seaward. The coal is ranked as a high volatile C bituminous coal. Ash and sulphur contents are high compared with Sydney coal and the coal has a tendency to spontaneous combustion when stored in large quantities.Of the four basins, the most significant is that of Mabou. At Mabou recent seismic and drilling investigations have indicated that although a sizable reserve of coal may be found offshore the structural problems, particularly faults, and the poor quality of the coal encountered will make it a resource of the future, if at all. Inferred resources have been calculated at 150 million tonnes in four seams over a 10 km2 area and extending 3 km from shore. The quality of the Mabou coals varies with ash, ranging from 5 to 25 per cent and sulphur up to 6 per cent. Calorific value ranges from 25.3 Mj I kg to 31. 7 Mj I kg. The Port Hood and St. Rose -Chimney Corner fields (Fig. 1) contain 16 million and 3 million tonnes respectively, but the Inverness basin is considered to have been depleted. The active mine in this area is the Evans Mine at St. Rose that is currently producing between 30 -50,000 tonnes a year from proven reserves of approximately 3 million tonnes."

Jan 1, 1985

By B. K. McMahon

Block caving is an efficient mass-production method for the underground mining of large orebodies. However, the block-caving method requires a substantial investment in developmental works, based on the assumption that the rock will cave. Efficient block caving is prevented if the rock forms stable arches or breaks into fragments that are too large to pass easily through the finger raises. Under these conditions, the cost of the additional labor, drilling, and blasting required to assist caving may be sufficient to make marginal orebodies uneconomic or alternative mining methods more attractive. Reliable methods for the prediction of the block-caving behavior of an orebody are clearly needed at the initial planning stage. These methods should be capable of considering both geological and engineering aspects of a block cave, as experience has shown that the manner in which a block cave is initiated and developed may be almost as important as the geological conditions such as the nature of the rock material, degree of alteration, characteristics of the joints and faults, etc. The initial state of stress in the rock mass should also be considered.

Jan 1, 1969

By N. Kanari

Reactivity of MgO towards C12+air, C12+N2 and C12+CO gas mixtures was studied up to 1000 °C. Carbochlorination of MgO occurs at temperatures lower than that of its oxychlorination. Effects of gas flow rate, temperature and partial pressure of the carbochlorinating gas mixture on the reaction rate were investigated. The apparent activation energy of MgO carbochlorination is 49 kJ1 mol between 425°C and 600°C. At 550 °C, the apparent reaction orders with respect to C12+CO, C12 and CO, are 2.37, 1.47 and 0.89, respectively. At this temperature, the maximum reaction rate was obtained using a C12+CO gas mixture having a Cl2lCO molar ratio equal to about 0.6.

Jan 1, 1998

By D. Song

In this paper, the differential equations governing the mass transport and the electrochemical reaction in a cathode catalyst layer of polymer electrolyte membrane fuel cells are solved based on the polynomial series expansion method. Explicit expressions for the polarization curve as well as for the distributions of oxygen, current density and overpotential are obtained when a quadratic, cubic or quartic polynomial is employed to approximate the oxygen concentration distribution. These kinds of explicit solutions are desirable for MEA design and diagnosis purposes. The comparison between the conventional numerical approach and the explicit solution approach proposed here shows that satisfactory accuracy can be reached by the first four terms of the polynomial series. The effect of the catalyst layer thickness on the accuracy of the obtained explicit polynomial solutions is also discussed.

Jan 1, 2005

By AIME AIME

THE Tuesday afternoon session", H. A. Bedworth chairman and T. S. Fuller, vice-chairman, was opened with D. J. McAdam, Jr.'s paper entitled "The Influence of Cyclic Stress on Corrosion." This paper dealt with the influence of cyclic stress on corrosion of alloy steels, corrosion-resisting steels, monel metal and aluminum alloys. The paper was discussed by T. S. Fuller, who pointed out that steels under stress corroded more than unstressed steels when subjected to steam.

Jan 1, 1930

By Jan Jekielek

Increasing capacity of bulk material handling systems creates difficult problems for accurate in-line material weight measurements. At the same time increasing system complexity and growing user demands call for more measurements. Precision in-line weight measurements for bulk materials are usually accomplished by application of conveyor belt scales. Belt scale accuracies listed by scale vendors are applicable for ideal situations with suitable conveyor design, belt scale location and calibration means. This paper attempts to provide designers and users with simple means to evaluate belt scale accuracy for practical scale installations. Based on known mathematical models simplified formulas for measurement errors are derived and discussed. These formulas allow for simple determination of achievable accuracy for alternative scale installations on the conveyor, conveyor designs, etc.

Jan 1, 1979

By Y. E. Brylyakov, M. A. Kostrova

"The apatite staffelite ores (ASO) of Kovdor deposit are dominated by fine-grained aggregates containing both phosphate minerals and silicates — vermiculite, smectites, zeolites. These minerals exhibit ion-exchange properties. In this connection, the magnitude of cation exchange, along with the content of P2O5 and CO2, is an important property of apatite staffelite ore, which largely determines the performance of concentration processes. In the examined ASO samples, the magnitude of cation exchange measured in terms of Ca2+ is 2546-4790 g/ton. The conducted laboratory studies of apatite staffelite ores with various mineral composition showed that adding calcined soda improves the recovery of P2O5 into the flotation concentrate. Full-scale tests were conducted at the apatite staffelite ore processing plant at Kovdor Mining and Concentration Operation and demonstrated the high performance of the proposed agent treatment. The test results showed that in the flotation of apatite staffelite ores, the optimum calcined soda feed rates range from 3,500 to 5,000 g/ton of the flotation feed. With close flotation feed and concentrate grade parameters, the P2O5 recovery gain is 17%. The effect of adding soda is associated with the desorption of the hardness cations from the minerals, precipitation in the pulp and, accordingly, improvement in the ionic composition of the liquid phase of the flotation feed due to a reduced content of calcium ions. Based on the test results, the proposed agent treatment with an elevated feed rate of calcined soda was implemented at Kovdor Mining and Concentration Operation in the flotation of apatite staffelite ore. The apatite staffelite ores (ASO) of Kovdor deposit are dominated by fine-grained aggregates containing both phosphate minerals and silicates — vermiculite, smectites, zeolites. These minerals exhibit ion-exchange properties. These minerals have certain properties requiring a more detailed examination for a better understanding of the flotation properties of apatite staffelite ores."

Jan 1, 2018

By Alicia E. Ares

316 L Stainless Steel samples were solidified directionally under conditions which produced the columnar to equiaxed transition. The position of the transition was located in each sample and the distance from the bottom of the ingot was measured. During solidification the distribution of temperatures were measured by means of thermocouples located strategically. From the measured temperatures the following parameters were derived; the local temperature gradient, the cooling rate and the velocities of the liquid and solidus fronts. Comparing the location of the transition and the values of these parameters it was found that the temperature gradient reaches negative values of as low as -13.44 "C/cm, and velocities of the fronts of around 0.1 cm/s. Also, a supercooling of 5.81°C were measured which was associated with the supercooling for the nucleation and growth of the equiaxed grains ahead of the columnar front. In addition the primary and secondary dendritic spacing was measured in both regions. The spacing was compared with the predictions from available models. The results are presented and discussed in the frame of the results obtained for other alloys

Jan 1, 2002

By Brahm Prakash, R. Schuhmann

Chemical conditions for flotation and nonflotation of cassiterite and fluorite with oleic acid as collector and with alizarin dyes as modifying agents were studied by means of small-scale, vacuum-flotation tests. Artificial cassiterite was prepared for these tests by high-temperature methods, especially by crystallization from borax melts.

Jan 1, 1950

By The Staff

THE property of McKenzie Red Lake Gold Mines, Limited, consists of eleven claims located on McKenzie island in Red lake. The mine is about 4,Y:l miles by water from the Howey townsite on the same lake, and about 95 miles north of Kenora, Ont. (see Figure 4). Mail and express are flown-in daily, winter and summer, from Sioux Lookout, Hudson, Kenora, and Winnipeg. All heavy supplies are freighted-in during the summer over a water route, using four marine railway portages, from Hudson, Ont., a distance of about 180 miles. During the winter, freighting over the same route is clone by tractor if necessary, but costs are three to four rimes the summer rate. Due to these conditions, large inventories of supplies must be kept on hand, varying from a spring minimum of $45,000 to a peak of $110,000 early in November. The average cost of all freight brought in from steel during 1937 was $0.01 per pound.

Jan 1, 1938

By J. E. Lawver, B. J. Clingan, R. E. Snow

Response surface methodology is a well-known and powerful technique for determining optimum conditions in flotation systems. One disadvantage is the onerous task of the numerical calculations and curve plotting. This paper describes a system in which the investigator simply selects the range of several flotation variables after which the design of the experiment, data analysis, generation of response surface equations, and response surface plots are automatically carried out using a digital computer and a computer-driven curve plotter. Several typical response surfaces of important variables in phosphate flotation are presented as examples.

Jan 1, 1980

By R. J. Bethancourt, D. M. Collingwood

The use: of a pilot waterflood is very desirable where all of the pertinent data necessary to initiate a full scale waterflood are not. available. This paper attempts to take a specific case and .show the step by step process of starting with a pilot waterflood and progressing to a full wale flood as results are obtained. INTRODUCTION Many of the older fields of Soutlwest Texas are approaching depletion by primary produrtion methods. As primary protlllc:inp operations on individual properties approach their economic limit. conflicting considerations face management: cm the one hand. plugging and abandonment of wells for equipment salvage; on the other hand, further investment in secondary recovery installtions, equilent, and well workovers in the interests of conservation anal additional oil reserves. In main instances, where primary production by pressure depletion and gas solution drive has been comparatively good, there still exists the possibility of an economic secondary recovery by waterflood. This is not necessarily true to the same degrre of all such fields. nor all portions of large fields. To properly evaluate the economics of a prospective water-11ot1cI requires a considerable amount of precise geological. statitical. and physical data Such information on the older field.; is often very limited. and in the case of the property discussed in this paper was considered inadequate to justify investment in an overall waterflood. Primary production was estimated at :39 per cent of the original oil in place, yet sand conditions of permeability and homogeneity, and position in the field appeared to be favorable for a limited margin of profit from a carefully controlled waterflood. Thus a pilot waterflood, with its minimum initial financial risk, followed by extension as favorable results were obtained, seemed to be the answer for the Sun Oil Co L. Wiederkehr lease in the Nortl Government Wells Field, Duval County. Texas DESCRIPTION OF RESERVOIR Approxinately 8,200 wells have been drilled in Duval County. As of March 1, 1952, there were 3,350 producing oil wells in 92 different fields, with very few flowing wells (Fig. 1.) Sun Oil Co. operates the I.. Wiederkehr lease located in the North Government Wells Field in Duval Countv. 85 mile. west of Corpus Chriti and 100 miles south of San Antonio. The lease has been subjected in part to a controlled five spot waterflood. The North Government Wells Field is roughly 7 miles long and 3 miles wide, with numerous overlapping producing zones. The L. Wiederkehr lease of 3.085 acres. Has seven producing zones from 700 to 7.500 ft. The lease is in the northern section of the field where it is widest, and has 710 acres productive from the North Government Wells .and. (Fig. 2.) The North Government Wells sand, Jackson group. Eocene age, at an average depth of 2.250 ft (minus 1.750 subsea). has a thickness range of 25 ft on the east side of the L. Wiederkehr lease to 4 ft on the west side. It has a slight overall dip to the North and East of some 33 ft to the mile.

Jan 1, 1953

By Paul Girodo

Government Approval For Foreign Workers 1.Service Canada Work Permit Tasks: i. Prove there are no Canadian Journeymen; ii. Use heavyweight stakeholders; iii. Understand the FWU transformation taking place today. Government Approval For Foreign Workers 2.Provincial Nominee Program (PNP) i. Build relationships; ii. Use heavyweight stakeholders; iii. Continually demonstrate benefits to the Province from foreign Journeymen. Government Approval For Foreign Workers 3.Letter from Union Supporting Temporary Foreign Workers i. Easiest path to approval ?CLAC model

May 1, 2006

By Alan D. Smith

[A standardized checklist in a questionnaire format, was established to investigate selected factors associated with coal nips roof falls, as derived from an intensive review of the literature. A plot study was undertaken to aspect and explore possible statistical relationships that may exist with these parameters. the Purposes of toe study were to: 1. Study in a systematic and empirical fashion selected parameters that may be capable of differentiating characteristics of roof falls; 2. Obtain some predictive indices cased on selected physical and management related variables so that predictions of future problems associated with mine roof falls can be completed, prior to its actual occurrence. Accomplishment of these goals should result in valuable guides to the mining engineer in scheduling exploration work and 4 determining economic feasibility of certain ground control and .lining pro and practices. The parameters associated with mine roof failure that where included in the questionnaire are: working section, county, spar., orientation degrees), pillar dimensions width, length), seam thickness, roof fall dimensions (length, width, surface area, volume), shape of fall (arch, dome, laminar), thickness of thinnest immediate layer, lithology of the first four i.e.-diate roof layers, thickness of h e first four immediate roof layers, type of initial support systems before failure, type of resupport system after failure, length and spacing of bolts in use before failure, length and spacing of bolts planned after allure, presence of .cater, time failure after It coal excavation, distance t3rest ace, physical operation during, time of coo failure, location of the roof fall entry failure occurred ence of sloughing of ribs before failure, and presence of floor heave condition before failure. The typical roof fall had an average roof spar of 20.3 feet, -06 feet depth o coal seam, occurred 136 feet from nearest face, coal seam thickness of inches, p--ar :width off 45 feet surface area D' roof fall 1151 ft2, mainly lamin- shaped, previously rat fore fall between good to very good, little floor heave presence, usually cracks before the fall about 40 percent of reported cases, shales in most of the immediate layers, and usually located in an entry or intersection. in addition, multiple linear regression techniques were employed in the testing process of 18 major research hypotheses in a search for relationships among the various parameters studied of which were found to be significant, once corrected for multiple comparisons.]

Jan 1, 1984

By A. W. Wensel

The adsorption behavior of sodium oleate on brucite, Mg (OH)2, has been studied by Fourier transform infrared spectroscopy. Both internal reflection and diffuse reflection (DRIFT) methods were used to characterize the adsorbed oleate on brucite. DRIFT measurements were shown to be quantitative, and an equilibrium adsorption isotherm was obtained. The conformational behavior of the adsorbed oleate was investigated as a function of adsorption density. It was found that at sub-monolayer coverage the alkyl chains of the adsorbed oleate had more ?gauche? character than at multi-layer coverages. Also, DRIFT spectra revealed that the adsorbed species were magnesium dioleate. For internal reflection measurements single crystals of MgO were hydrolyzed to form a thin Mg (OH)2 layer.

Jan 1, 1994