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By Harold L. Rhodes

The Bureau of Mines has developed a method for determining the H2S content in natural gas samples. A gas chromatograph with a flame photometric detector was used to analyze samples with H2S concentrations ranging from 5,000 ppm to a minimum detectable limit of 0.01 ppm. A mass spectrometer was used to analyze samples containing H2S in amounts greater than 5,000 ppm. Methods are presented for preparing containers for H2S samples and for preparing standards using partial pressure and weighed standard methods, Sample collection techniques are discussed, as are analytical results which illustrate the loss of H2S while in the sample container and provide a basis for evaluating containers used for sampling and standard preparation.

Jan 1, 1979

By George H. Schnakenberg

Automation of coal mining activities at the face offers improvements in worker safety, health, and productivity. Introduction of integrated computer-sensor systems to current mining machines will enable these machines to perform some of the most hazardous tasks through supervised teleoperation. The U.S. Bureau of Mines is pursuing the development of the enabling technology necessary to achieve this goal. The research program consists of both basic and applied research, each focused on the fundamental issues of computer and sensor technologies. Short-term research is directed to providing computer-assisted, remote supervisory operation of present underground equipment; the long-term goal is the development of progressively more intelligent mining systems. The research program includes a review of robotic machine and autonomous vehicle technologies and of current mining technology, which provides a base for developing innovative mining methods; research in navigation and guidance technology, emphasizing control of a continuous mining machine; research on coal-rock interface sensing technology for horizon control, and rib thickness control in highwall mining; the development of computer systems and hierarchical architectures for real-time control; and development of expert systems for machine system fault diagnostics and predictive maintenance. This report presents a brief background and the current status for each of these research areas.

Jan 1, 1989

By Hylton McWhinney, Doanh Tran, Jewel Andrew Gomes, George Irwin, Sameer Pallavkar, Md Islam, David Cocke, Mohammad Rafiqul Islam

"High-performance nickel-based nanocrystalline zinc oxide adsorbents have been prepared adjusting Ni/Zn mol ratio of 1 :5 by thermal decomposition, coprecipitation and sol-gel method for selective adsorption of thiophene in liquid hydrocarbon fuels at ambient temperature and pressure. To understand the nature of reactive adsorption of thiophene (C4H4S) on Ni/ZnO, the effect of preparation techniques, morphological and textural structure on the desulfurization activity was investigated. A model fuel (20 mL) consisting of pentane (C5H12) and thiophene was prepared and adsorption experiments were performed by a batch method under ambient conditions. The physicochemical behaviors of the fresh adsorbents were obtained using X-ray diffraction (XRD) with EDAX, scanning electron microscopy (SEM). The sulfur concentration in the mixture was monitored by UV-vis spectrophotometry. The adsorption reaction confirmed that ZnO played a crucial role in taking up S element to convert it into ZnS. The deposition of nickel on ZnO is an innovative approach which takes advantage of the selectivity of Ni towards S-species and the high adsorptive capacity of ZnO support.IntroductionLow temperature deep desulfurization of fuels via selective adsorption of sulfur compounds keeping coexisting aromatic hydrocarbons and olefins intact is receiving increasing attention in the research community worldwide in order to satisfy the upcoming environmental regulations and fuel specifications. The sulfur compounds in the transportation fuels is a matter of concern when global crude oil slate is becoming heavier and sourer and environmental restrictions on both the refining process and the refined products are becoming more stringent. According to the current refinery technologies, the sulfur content in refinery fuel is typically around 300-500 ppm by weight (ppmw) [1-3]. Starting in 2006, sulfur limits in highway diesel and gasoline were set to 15 ppm and 30 ppm, respectively. During combustion sulfur in the fuel are converted to toxic sulfur oxide (SOx) and contributes to air pollution and acid rains [ 4]."

Jan 1, 2011

By Duane A. Smith

They are gone now. Gone like that long ago generation that gave them birth. The Homestake Mine, nestled in the northern Black Hills, closed in 2001 after 125 years, the longest run of any major American gold mine. The Homestake Mining Co., which guided its destiny for those many years, is gone too. It merged with Barrick Gold. The Hearst family, which guided the early destiny of both, has long since gone beyond its mining heritage and into the national and even international spotlight. The mine and the company passed from the scene with as little fanfare as heralded their birth, amid the Black Hills gold rush of the 1870s. They both grew into American mining legends, as did the town they sired and nurtured, Lead. In a real sense, the mine and the company symbolized one of the last links to a vanished world and a mining era.

Jan 1, 2003

By G. W. Weems

The Bureau of Mines used the Burnett method and apparatus to determine the compressibility factors for helium and carbon dioxide mixtures at 0°, 10°, 20°, 23°, and 35° C and to pressures of 900 psia. Tables of compressibility factors and approximations of the virial coefficients are presented for seven binary mixtures as well as for helium and carbon dioxide. The results compare favorably with existing data.

Jan 1, 1969

By Sigurd L. Lamhauge, Karl Gunnar Holter, Svein E. Kristiansen

An innovative sprayable waterproofing membrane in combination with the traditional Nordic method of waterproofing with polyethylene foam sheets was used for the waterproofing of the tunnel. The sprayable membrane was integrated in the final sprayed concrete lining in a sandwich structure, hence constituting a composite water-proof lining based on sprayed concrete. The spray able membrane was applied in areas with small to moderate water ingresses, making up approximately 50% of the total area requiring waterproofing in the tunnel. State-of-the-art application technology with a computerized spraying robot was used. A consistent application of the required thickness at a high speed was thereby achieved.

Jan 1, 2007

By K. Madhusudan Reddy

"Pile response under combined uplift and lateral load is very important and it is imperative to evaluate the effect of combined loading and only few studies were reported on pile behavior under combined uplift and lateral loads. Model pile made-up of aluminum having an outer and inner diameter of 25.4 mm and 19.4 mm respectively is used. Dimensions of the model steel tank are fixed as 1.0 m x1.0 m x 1.2 m (depth) to avoid the boundary effects under combined lateral and uplift loads. Experiments were carried out on single piles at isolated uplift, isolated lateral loading and combined lateral and uplift loading, embedded in sandy soil. Results indicate that load–deflection behavior is nonlinear for isolated uplift and lateral load tests as well as in case of combined loadings. It is also observed that the behavior of piles under isolated loadings is substantially different when compared to combined loading.INTRODUCTIONPile foundations are generally used to support compressive loads from superstructures. Some structures, like transmission towers, mooring systems for ocean surface or submerged platforms, tall chimneys, jetty structures, etc. are constructed on pile foundations, which have to resist large lateral and uplift loads and moments. The various loads (compressive, lateral and uplift) and moments act on the piles simultaneously rather than isolated manner. There are well-established theoretical methods present to evaluate the pile behaviour under different isolated loadings namely, verticalcompressive, vertical-uplift and lateral (Poulos and Davis, 1980), but there are very limited studies focused on pile behaviour under combined loadings. Though there is good number of studies reported on pile behaviour under combined compressive-lateral and compressive-uplift loadings (Ramasamy, 1974; Jain et al. 1987; Zhang and Small, 1999; Dash and Pise, 2003; Karthigeyan et al. 2006 & 2007; , there are only very few studies reported on pile behaviour under combined uplift and lateral loads. Darr et al. (1990) described an approach to a rational solution of the interaction of pile to combined uplift and lateral loads based on analytical and experimental studies. Influence of cyclic loading was also considered. Narasimha Rao and Prasad (1993) investigated the uplift behaviour of pile anchors subjected to lateral cyclic loading. There were many onshore and offshore situations where lateral cyclic loading may affect both the pullout and lateral loading capacity of pile anchors. Jetty and wharf structures are usually subjected to lateral forces from wave and wind action. If these cyclic lateral loads are acting on the supporting piles, the resulting movement of the upper part of the embedded length of pile may reduce the skin friction. This progressive deterioration in pullout resistance may not be reflected by a pullout test made soon after the installation. Hence, Tomlinson and Woodward (2008) pointed out that a generous safety factor on the ultimate pullout load should be adopted for piles in such situations. Mroueh and Shahrour (2007, 2008) presented a threedimensional finite element analysis of the response of battered piles to the combined lateral and vertical pullout loads. Nevertheless, the model is not validated well due to lack of good experimental data based on rigorous experiments. Thus there is a scope for investigating the effect of lateral load on pile behaviour under uplift load and vice versa based on carefully designed experiments, which is main focus of the present investigation."

Jan 1, 2017

By D. Bois, P. Keating, J. Lemieux, M. A. Vallée, M. Allard, R. S. Smith, L. Z. Cheng, M. Chouteau, K. Fountain

"A comparison of data from INPUT, GEOTEM, and MEGATEM airborne electromagnetic (AEM) systems over the Aldermac deposit, Québec, Canada, was undertaken to evaluate the relative ef¬ficiency of these systems for the detection of small, deep conductors. The Aldermac orebody was mined between 1933 and 1934 to a depth of 200 m. A deeper mineralized zone was discovered in 1987. The MEGATEMII system was used to acquire 90- and 30-Hz data over the deposit in 2003 as part of a research project. These MEGATEMII data were compared with data acquired by other AEM systems (GEOTEM and INPUT), and the results show that the MEGATEMII response is ten times larger than the other sys¬tems. For the dB/dt response, 30 Hz gives a better signal-to-noise ratio, whereas 90 Hz has a better signal-to-noise ratio on the B-field.The data were evaluated by numerical modeling. The deposit was best represented by a complex mod¬el, comprising two weakly conductive bodies to approximate the alteration halo, two deeper prisms repre¬senting known orebodies, and three bodies ranging in thickness from 3 to 6 m and in resistivity from 12 to 20 ohm·m, representing the chargeable overburden. This implies that the MEGATEMII system is able to see a small conductive body at more than 200 m depth in an area where the response is contaminated by conductive overburden."

Jan 1, 2009

By T. Gerritsen, R. C. Delgado, J. Janzen, E. R. Veloza

The paper describes the components of an Integrated Furnace Control system for covered-arc (shielded arc) smelting with results from the recently started 75 MW Cerro Matoso Line 2 Furnace. The paper starts with a review of the mechanisms of power and feed input and heat losses in the shielded-arc smelting process, and describes how the details of the control system are tailored to the process. The control modules of a covered-arc smelting furnace are described including measured results and screen captures. This paper focuses on Integrated Furnace Controls tailored to shielded-arc smelting, but similar approaches have been recently applied to other furnace processes including immersed-arc smelting.

Jan 1, 2004

The clay slime generatea in many sand washing operations is usually very difficult to de-water. Treatment of these slimes is often limited by economic considerations and the properties of the solids to a gravity-driven process. The moisture characteristics of kaolinitic slimes from two different sand washing operations were measured.From these curves, equilibrium moisture contents for sedimentation and for drainage were calculated using the methods of soil physics. The validity of these calculations were confirmed by column experiments.The results show that the increased de-watering to be gained by drainage, as compared with sedimentation, is significant. Furthermore, observed rates of outflow indicate that water can be removed considerably morerapidly when drainage is possible.The practical application of these results to the dewatering of clay slimes is discussed.

Jan 1, 1978

This is the third in a series of reports on properties of commercial motor fuels, made in accordance with a cooperative agreement between the Cooperative Fuel Research (C. F. R.) Committee and the Bureau of Mines of the Department of the Interior. The first report gave data on motor gasolines sold during the winter of 1935-36.3/ The second report gave the same data for motor gasolines sold during the summer of 1936)4/ As was the case with the first cooperative gasoline survey, reports were received for some areas from only one company and in other areas from two companies that did not in all instances report on the same brands of gasoline. In still other areas reports were received from five or six companies on the same brands of gasoline. Thus, it can be seen that data on gasolines are unequal in regard, to the number of reports that were averaged in calculating the data shown in table 1. The data from the Pacific Coast were averaged by the Pacific Coast technical group before submission and are published exactly as they were submitted.

Jan 1, 1937

This is the third in a series of reports on properties of commercial motor fuels, made in accordance with a cooperative agreement between the Cooperative Fuel Research (C. F. R.) Committee and the Bureau of Mines of the Department of the Interior. The first report gave data on motor gasolines sold during the winter of 1935-36.3/ The second report gave the same data for motor gasolines sold during the summer of 1936)4/ As was the case with the first cooperative gasoline survey, reports were received for some areas from only one company and in other areas from two companies that did not in all instances report on the same brands of gasoline. In still other areas reports were received from five or six companies on the same brands of gasoline. Thus, it can be seen that data on gasolines are unequal in regard, to the number of reports that were averaged in calculating the data shown in table 1. The data from the Pacific Coast were averaged by the Pacific Coast technical group before submission and are published exactly as they were submitted.

Jan 1, 1937

By Maria I. De Rosa

Combustible materials, when burned, produce toxic gases and smoke, which may vary dramatically from one material to another, with resultant different total toxicity and smoke obscuration levels. This U.S. Bureau of Mines report presents smoke property data acquired for a variety of mine combustibles and shows that there exists a correlation between the smoke properties, the relative toxicity, and the smoke obscuration levels of those combustibles tested. These correlations can be used to devise simple, standard tests for determining the toxic and smoke obscuration hazards of mine materials during fire.

Jan 1, 1989

By E. Craig Simmons

Uranium is an element incompatible with respect to the major rock-forming minerals crystallizing from granitic magma, entering in- stead trace minerals such as zircon. The relationship between the saturation limit (SL) for such a mineral and the bulk distribution coefficient (Do) for U is central to understanding the distribution of U and its availability to late- stage fluids which can form ore deposits directly, or labile U which can be remobilized later. Low SL values imply early crystallization of zircon, but in very small proportions, minimizing Do and maximizing the degree of enrichment of U in late-stage fluids. Thus, granitic rocks with low Zr contents (due to a low saturation limit for zircon) are most likely to evolve U- enriched differentiates; this will be reflected in a high U content of the zircons (but not necessarily high U abundances in whole-rocks). Thus, the ratio of the U content of zircon to the Zr content of the corresponding whole-rock is potentially a very useful parameter in identifying granitic rocks which are most likely to have U-enriched solutions associated with them. The granitic rocks associated with the U deposits of the Midnite Mine area, Washington, have geochemical characteristics which fit very well the model presented here. The rocks are very low in Zr (100 ppm) and contain zircons with extremely high U contents (3,000-4,000 ppm).

Jan 1, 1981

By Paul Laframboise, Nigel MacDonald, Mike Hallewell, Robert Thorpe

"Galmoy Mine, owned by Arcon Mines Limited, has operated since 1997, and is one of three operating lead/zinc mines in Ireland. Changes in ore type starting in mid 2002 created challenges to metallurgical operations at Galmoy. This resulted in unacceptable lead and zinc flotation performance, which prompted initiation of a formal plant review and a subsequent stabilization programme. This involved a structured review of operational practices, development of a new Standard Operating Procedure (SOP) which in turn led to significant changes in process control equipment needs in conjunction with extension of zinc flotation cell residence time.This paper will describe the metallurgy of the Galmoy operation. Reasons for the poor metallurgy experienced in 2002 will be described, as well as the solutions identified to overcome these problems. By the second quarter of 2003, these solutions had been implemented and recoveries had risen to record levels.INTRODUCTIONGeneralGalmoy Concentrator is located in County Kilkenny (Refer to Figure 1 below) and was constructed during 1996 and commissioned in 1997.The concentrator at Galmoy had been designed initially to treat 650,000 tonnes per annum of primarily CW ore type. The main mineral of economic significance was sphalerite (Typically 10 to 11% Zn) with some minor galena (0.7%Pb) in a dolomite (Magnesium Carbonate) host rock.The only other competing sulphide mineral was pyrite (Circa 3 to 5% Fe in Mill Feed. This CW ore type predominated the first 6 years of production, but in August 2002, the ore mineralogy changed due to significantly higher levels of pyrite rich G ore body being blended in with CW ore."

Jan 1, 2005

By J. -P. Nepper

It has been possible to largely contain converter aisle emissions of SO2 and fumes in the case of batch-wise operated Peirce Smith converters during normal blowing periods with the help of suitably designed primary hoods. Controlling the escape of off-gas during the periods of turning the converter in or out of the stack has been problematic in the past. Effective automated control systems have been developed for the purpose and successfully applied in smelter operations in Spain, Taiwan and Germany. This has led not only to an effective reduction of emissions in the converter environment but also to an improvement in the converter operation.

Jan 1, 1992

By Qingguo Xue, Jingsong Wang, Siyang Long, Jun Zhao, Haibin Zuo

In order to effectively use of low rank coal, the thermally dissolve coal (TDC) was extracted from four kinds of low-rank coals by N-2-methyl-2-purrolidinone (NMP) at high temperature and high pressure. The structures of thermally dissolve coal and residues were characterized by element analysis, FT-IR spectra. The effects of temperatures, coal rank, solid-liquid ratio and extraction time on the extraction yields of TDC were studied, respectively. Moreover, the extraction mechanism of TDC at mild conditions is proposed. The results show that the ash contents of TDCs from four raw coals are significantly lower than that of raw coals, and the volatile contents and H/C are significantly improved. For KL coal, with the increase of temperature, the extraction yield of KL-TDC is improved evidently from 33.75% to 56.25% and the ash content is decreased from 0.57% to 0.49% at 350 °C.

Mar 1, 2018

By M. F. He

There are three polymorphic modifications in pyrrhotite (monoclinic, hexagonal and orthorhombic), with monoclinic and hexagonal polymorph being more abundant. The floatability of different crystalline structures of pyrrhotite (monoclinic and hexagonal) is studied in this paper. It is shown that the floatability difference of monoclinic and hexagonal is obvious and that the flotation recovery of monoclinic pyrrhotite is greater than that of hexagonal pyrrhotite using different collectors . Using butyl dithiophosphate as collector, the flotation recovery of pyrrhotite is higher than when sodium diethyl dithiocarbamate and sodium butyl xanthate are used as the collectors. Monoclinic and hexagonal pyrrhotites are more easily activated by Cu2+ in acidic conditions than in alkaline conditions, while Cu2+ can not activate hexagonal pyrrhotite when sodium diethyldithiocarbamate was used as the collector. By the measurement of contact angle, it is indicated that monoclinic and hex-agonal pyrrhotite float well and are easily activated by Cu2+when dithiophosphate was used as the collector. Using sodium diethyl dithiocarbamate as a collector, the flotation behavior of pyrrhotite was investigated. The relationship between potential and pH range for pyrrhotite flotation was established. The results show that the flotation of pyrrhotite is dependent on pulp potential at certain pH values.

Jan 1, 2014

By Floyd R. Hertweck

The helium resources of the United States were estimated by the Bureau of Mines to be 1,037 Bcf as of January 1, 1981. These resources are divided into four categories, in decreasing degree of assurance of their existence: (1) helium in storage and in measured natural gas reserves, which totals 211 Bcf, (2) helium in indicated natural gas resources, which is estimated at 207 Bcf, (3) helium in hypothetical natural gas resources, which is estimated to be 318 Bcf, and (4) helium in speculative natural gas resources, which makes up the remaining 301 Bcf. These helium resources are further divided into depleting, nondepleting, and stored classifications, The depleting resources are those associated with natural gasfields that are, or will be, produced for the natural gas they contain. All of the helium in undiscovered (hypothetical and speculative) natural gas resources is included in this classification. These depleting resources are estimated to contain 897 Bcf of the total helium resource base. Nondepleting resources are those in shut-in, abandoned, or otherwise nonproducing natural gasfields. Helium resources contained in nondepleting natural gas resources are estimated to total 100 Bcf. There is 40 Bcf of helium in storage in the Federal Government-owned Cliffside Gas Field near Amarillo, Tex.

Jan 1, 1983

By L. J. Kane

Conventional methods for determining the size of dust suspended in a gas require that agglomerates (clusters of particles) first be broken into particles, but in evaluating industrial dust-removing equipment the size of the agglomerates as they actually exist in the gas stream is far more important. This paper presents results of an investigation by the Federal Bureau of Mines to develop methods for determining the size of dust agglomerates suspended in a gas stream. The studies are part of the Bureau's continuing research on synthetic liquid fuels. The size and size-distribution of agglomerates as they exist when the gas reaches the filter was determined by using a membrane filter in conjunction with a dust count under a microscope. A membrane filter is a cellulosic sheet about 150 microns thick containing millions of holes per square centimeter--holes of uniform diameter that run directly through the sheet without interconnection.

Jan 1, 1960