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By T. C. Alex, K. M. Godiwalla, R. K. Jana

Manganese nodule, available in ocean beds, is a potential resource of the future for copper, nickel and cobalt. Recovering only these metals, containing less than 3% by weight, will result in the generation of large amount of residue. In addition to the material losses, several environmental and ecological problems arise out of this. The present study has been aimed at reducing the environmental and ecological problems associated with massive generation of this residue together with utilization of the resources. Presence of ~ 20% manganese and ~16% silicon in the residue has prompted us to check its suitability as a raw material for silicomanganese production. Lower manganese content and lower Mn/Fe ratio of the residue than that required for silicomanganese production has been corrected in this study by suitable blending. The efficacy of blending and its thermodynamic aspects using FACTSAGE software are discussed. The studies conducted indicate viability of bulk utilisation of the residue through silicomanganese production and thereby reducing the burden on environment to a great extent.

Jan 1, 2007

By Reinhold Schnell, Piers Wendlandt, Nathan Rouse

Drilling and blasting are key components of every hard-rock (i.e.,metal/nonmetal/coal) mining operation. Well-executed and maintained drilling and blasting can have a major positive impact on the overall success of such operations. This case study presents the implementation of a new drill and blast engineer position and systematic improvement of the drill and blast operations at a surface metal mine. The findings of and lessons learned from this case study can be applied toother mine operations to improve safety, production, efficiency, and cost savings. Focus areas for the project included refined communications, operational practices and procedures, planning, designing, and data collection and analysis. This case study showed improved efficiency in communication and planning among the engineers, operations team, and contractor groups over the course of the project. An increased awareness of long-term plans and needs for the drills and blasters reduced or eliminated existing delays. Test blasts that implemented new drill and blast designs and updated operational practices and procedures were tested to streamline the process. Constraints regarding explosive product shipments, geological considerations, and a uniform powder factor provided the basis for new blast designs.

Principal component analysis of the variation of Cu, Ni, Zn, Pb, Mn, and Cr in a control group of 96 samples of surface ironstone from the Yilgarn Block, Western Australia, was used to derive a simple graphical method, based on only Cu, Ni, and Cr, for discriminating between massive nickel gossans and other ironstones.When the graph was tested by plotting 400 control samples, it failed to correctly classify only nine out of 176 gossans and 11 out of 224 other ironstones.

Jan 1, 1974

By John F. Elliott

Six major trends that have had and are continuing to have major effects on the use and supplies of pig iron and scrap in the United States are (a) gradual replacement of the basic open hearth furnace (OH) by the basic oxygen furnace(BOF); (b) use of the electric furnaces for the production of plain-carbon steels, a trend which is closely related to the first; (c) United States changing from being a net exporter to a net importer of steel; (d) replacement of ingot casting by strand casting; (e) increased exportation of scrap; and (f) the lack of growth of the capacity of the U. S. steel industry to produce pig iron in the last 5 to 8 years. This report gives an analysis of the relationships between these trends and the use of processes for the production of raw steel in solidified form.

Jan 1, 1975

By Paulo Jesus Aniceto

Variações no tratamento termomecânico influenciam as propriedades dos metais e suas ligas. Em particular, na obtenção de chapas metálicas, a quantidade de passes de laminação e o grau de redução de cada etapa (caminho de laminação) influenciam na formação do estado deformado do material. Este estado, em conjunto com as condições de recozimento, determinará as propriedades finais do material. Este trabalho tem como objetivo estudar a influência do caminho de laminação no tamanho de grão final de dois materiais de diferentes energias de falha de empilhamento (EFE): cobre UNS C11000 e latão UNS C26000. As propriedades mecânicas das ligas escolhidas são em grande parte determinadas pelo tamanho de grão médio, que podem proporcionar aos materiais boa resistência mecânica aliada à boa ductilidade, condições desejadas em aplicações de estampagem. O estudo foi conduzido impondo uma redução total de 62% nas chapas utilizando-se duas condições diferentes: quatro e seis passes de laminação. O recozimento foi comum para os dois casos e resultou em uma diferença significativa (6 ?m) entre os tamanhos de grão médios das amostras de latão, enquanto o mesmo não foi observado para o cobre. A distribuição obtida de tamanho de grão foi lognormal para todas as amostras, à exceção do latão laminado com quatro passes. Os resultados foram analisados qualitativamente à luz da estrutura dos materiais no estado encruado.

Aug 17, 2017

By J. P. P. Silva

Sodium silicate (water glass) is a modifier reagent widely used in flotation with the function of a depressant or dispersant. The interaction between sodium silicate and mineral surfaces is still not well understood. This investigation aimed to illuminate the sodium silicate action mechanism as a depressant in the flotation of the minerals quartz and calcite. The experiments were done with high-purity mineral samples in the particle size range below 147 µm. The microflotation tests in a modified Hallimond tube showed that, in all systems tested, the efficiency of sodium silicate increased with the concentration. At concentrations above 1,500 g/t, almost total depression (96% for calcite and 97% for quartz) was achieved. The variation of sodium silicate modulus did not alter the quartz flotation performance in the presence of amine (150 g/t). The most efficient depression pH range was observed between 5 and 8. Above pH 10, the depressant action of sodium silicate was negligible. The infrared spectra obtained at pH 7 after silicate contact showed the presence of the groups OH and Si-OH, both suggesting that the adsorption of the neutral species Si(OH)4, as well as siloxane groups (Si-O-Si), attributed to adsorption of polymeric species. Sharing electron pairs is the proposed adsorption mechanism between Si(OH)4 and polymeric species and the surface sites (Si-O on quartz and Ca-O on calcite). At pH 11, the electrostatic repulsion prevents the species adsorption, impairing the sodium silicate action.

By J. T. Kalala

Energy consumption and wear of grinding media and liners are the major cost factors in milling plants. Since the beginning of the last century, much effort has been directed at the prediction of the power draw as affected by the mill operating conditions. This paper explores the prediction of the liner wear using the discrete element method (DEM). A mathematical model taking into account adhesion, abrasion and impact wear which occur in dry mills is derived in order to predict the loss of material on liners. The mathematical model is implemented in the DEM code using an objective function in order to produce realistic simulated profiles. Our DEM simulated predictions are compared to published experimental and industrial data. Keywords: modelling; discrete element method; liner wear

Jan 1, 2004

By J. C. van Dyk

The objectives of this study were firstly to characterize and quantify the inorganic material in the Secunda gasification feedstock. Secondly, the effect of washing on coal properties and sulphur content was investigated. Coal from a single source and a coal blend from 6 different mines were tested. Composite samples were visually sorted by a geologist in the groups containing roof, floor, C-shale, pyrite, carbonates and siltstone material. Inorganic mineral types from the single source and coal blends were characterized separately. Characterization results indicate that the average mineral matter distribution (mass %) of the coal tested was as follows: carbonates (6%), carbon-shale (19%), pyrite (12%), roof (18%), floor (46%) and siltstone (22%). The roof, floor, pyrite, carbon-shale, carbonates and siltstone in the single source and coal blend have similar chemical properties and characteristics, except for the ash melting temperatures of pyrite and kaolinite in the siltstone. By implementing selective mining and increasing mining management practices, the percentage discard in the run of mine coal can be significantly reduced, by up to 45%, if the mining of roof and floor material can be avoided. No significant impact of mining practices on sulphur content is expected in this case due to the low concentrations of sulphur in the roof and floor material. In summary, selective mining practices will probably result in almost45% decrease in the discard content in the run of mine to gasification, an increase in the carbon content from 55.0% to 58% (air dry basis) and a decrease in sulphur content from 1.1% to 0.9% (air dry basis). It is clear from this study that the main source of sulphur is not in the high ash-content mineral types (e.g. floor and roof), but in situ in the coal structure. Keywords: inorganic material, effect of washing, roof, floor, pyrite, C-shale, carbonates and siltstone

Jan 1, 2005

By Moacir Medeiros Veras

A tecnologia de sensor-based sorting faz uso de sensores high-tech para pré-concentrar seletivamente partículas de minérios que tenham teores toleráveis para planta de beneficiamento, rejeitando as partículas que são totalmente estéreis ou rejeitos. A pré-concentração de carvão assistido pelo método Dual Energy X-Ray Transmition possibilita separar seletivamente o carvão com melhor quantidade de matéria orgânica das rochas silicáticas com maior densidade. O objetivo desse trabalho foi investigar a afinidade da tecnologia de sorting na pré-concentração do carvão mineral da Carbonífera do Cambuí/PR assistido por sensor de raios-x. Os testes foram realizados em dois lotes cujo range granulométrico foi -4”+2” e -2”+1”. A pré-concentração foi feita em 2 cortes de separação, o primeiro para retirar o rejeito e o segundo para obter 2 tipos de produtos. Os resultados indicaram que 52,15% da massa foi rejeitada, concentrando 47,85% do material de carvão na fração média -2”+1”. Na fração grossa -4”+2” foi rejeitado 62,51% da massa e concentrado 37,49% de carvão. As análises imediatas dos pré-concentrados mostraram que na fração grossa houve redução de 44,57% de cinzas totais e houve aumento de 4,59% para 8,29% de enxofre [S], enquanto na fração média a redução foi de 36,98% de cinzas totais e de 1,19 % [S].

Oct 30, 2017

By A. F. Neil, A. S. Bahaj, P. Watkins, P. M. Hyslop, C. E. Kirby, P. A. B. James

The results of initial work indicate that for 3 of the 5 quarry sands bioleaching reduces the iron oxide content to a commercially acceptable 0.035 wt% Fe20 3, although the time taken to achieve this is 14-22 days against a target leach time of 7 day. Subsequent work has identified strains of Aspergillus niger that are more efficient at producing the array of complexing agents for iron and is yielding excellent and rapid reductions in Fe levels. Potentially, bioleaching offers a more environmentally friendly and energy-efficient process for the removal of Fe from glass-making sands than conventional routes but the production of organic acids by fermentation must be achievable with low-cost substrates such as sugar-beet molasses and lactose permeates for bioleaching to offer a commercially viable alternative to treatment with hot mineral acids. Silica sands usually contain three groups of Fe minerals: iron oxyhydroxides, which comprise crystalline types such as goethite and limonite tending to occur as thin, discontinuous coatings and in cracks and crevices on the surface of the quartz; the assemblage of heavy trace minerals, which include ilmenite, rutile, leucoxene, chromite and haematite, commonly present at levels of 0.1 wt% or less as discrete grains or sometimes cemented to the quartz; and clay minerals cemented in pits on the surface of the quartz and in association with weathered, discrete feldspars. The response of the assemblage of iron minerals to short periods of exposure to hot inorganic acids is broadly related to which group they belong to, those that form coatings being accessible to acid and tending to react rapidly whereas the trace minerals are usually resistant and react very slowly, if at all, and the clays are probably digested. The note reports on a preliminary study of the use of microorganisms to develop an alternative clean technology that will give results comparable to those achievable with hot inorganic mineral acids but with more environmentally acceptable procedures. Various fungi and bacteria produce organic acids when grown in certain media. When these acids come into contact with Fe-stained sand grains the iron is removed as soluble complexes. Several strains of Aspergillus niger have been found to produce organic acids from sugar, predominantly citric, gluconic and oxalic acids, their relative yields depending on cultivation medium and conditions. Sand samples were prepared from five quarries in the UK: Levenseat, Lothian; Redhill, Surrey; King's Lynn, Norfolk; Chelford, Cheshire; and Oakamoor, Staffordshire; ranging in iron oxide content from 0.035 to 0.153 wt% Fe203

Jun 18, 1905

By Jian Zhou, Shuai Huang, Wenqin Xi, Kun Du

The deep oceans harbor a wide variety of mineral resources that are characterized by their abundance and high quality. Nations worldwide are actively pursuing the exploration and extraction of these resources. This paper provides a concise overview of the mineral resources found in the deep sea, highlighting the challenges associated with their exploitation. Furthermore, it presents a comprehensive analysis of the historical development of deep-sea mining technology and equipment, offering valuable insights into this field. By examining the current issues and obstacles faced in deep-sea mineral extraction, this study concludes that the future of deep-sea mining lies in the direction of automation, intelligence, and standardization. Additionally, it identifies the key technological advancements that need to be achieved in order to overcome the challenges associated with deep-sea mining.

Jan 5, 2024

By Virgil J. Stachura

The Bureau of Mines has investigated techniques and instrumentation that measure accurately the airblast overpressures from surface mine blasting. The results include equivalencies between broadband research instrumentation and commercially available impulse precision sound levels meters measuring: root-mean-square, peak, fast, slow, impulse, A and C weighting, C-weighted sound exposure level (CSEL), and "linear" (flat) response. These values were obtained from field measurements and broadband FM tape recordings of production blasts at area and contour coal mines, limestones quarries, and iron mines. Frequency response was determined for 14 commercial systems.

Jan 1, 1981

By D Roldpo, M Vidigal, J F. C L Costa

The local cumulative distribution function (lcdf) of a selective mine unit (SMU) can be estimated by conditional simulations using the statistics derived from the sample points, generating multiple equally probable scenarios. Conditional simulations permit the evaluation of the lcdf at any support, taking into account the spatial variability, ie the variogram, and the two statistical moments, mean and variance, of the conditioning samples. The SMU ore losses and dilution depend on the mining method and mining equipment selectiveness that, in its turn, depends on the predicted block size. A new approach to predict ore loss and dilution was developed in this study. Monte Carlo simulation is used to randomly generate a grade value derived from the lcdf at the mining stage (Zs_mc(t)) in order to make a decision about the SMU destination, ie processing plant (ORE) or waste dump (WASTE). If Zs_mc(t) is lower or equal to the cut-off (Z_cut-off) the block is ORE and, conversely, if Zs_mc(t) is higher than the cut-off (Z_cut-off) the block is WASTE. Considering these binary destinations ORE/WASTE, at the mining time t, and combining each realisation of the simulated random function Zcs_i (X), there are four possibilities for each SMU simulated value: 1. the block was simulated as ore and is actually ore (OO), 2. the block was simulated as ore and is actually waste (OW),3. the block was simulated as waste and is actually ore (WO), and 4. the block was simulated as waste and is actually waste (WW).The dilution factor is given by possibility 3 (WO), while the ore loss factor is represented by possibility 2 (OW). These results comprise the classical classification and reconciliation plots used in the mining industry. The new procedure proposed in this paper is based on the use of all the equally probable simulations to define the ore loss and dilution factors. An application of this methodology was carried out at Vale's iron mine in Brazil. The grade of silica was simulated and 50 multiple equally probable 3D models were generated. The mean and the standard deviation of the ore tonnage (OO + WO) for the 50 realisations, was 233 Mt and 0.5 Mt, respectively. The mean grade increased for the diluted ore (OO + WO) as well as their respective coefficient of variation (CV). The CV increases from 62 per cent in the undiluted ore (OO), to 101 per cent in the ore, considering the dilution factor (OO + WO). The mean ore loss (OW) was 10 Mt and the waste tonnage dilution (WO) was 9 Mt.

Jan 1, 2009

By Sverre Olsen, Kai Tang

The composition of ferromanganese slag is very important as it determines the slag/metal equilibrium relations including MnO content of final slag, melting relations and slag viscosity. The slag composition is further expected to influence the process temperature. The properties of ferromanganese slags are suitably described by its basicity and A/S mass ratios. The influence of slag basicity has been discussed in the previous papers. The present paper will discuss the effect of Al2O3 on melting relations, viscosity and MnO-content of final slag. This discussion will be based on assessed thermochemical databases and a recently developed viscosity model.

Jan 1, 2007

By Chen Zhiqiang, Luo Chuansheng, Chen Ziqiang, Liu Jianguo, Rao Jinshan

To comprehensively utilize the valuable resource in tailings, increase the economic benefit of mine, reduce the amount of tailings, prolong the service life of tailing dam, the comprehensive utilization of tailing resource is arousing the attention of more and more mines. Research of comprehensive recovery of feldspar and silica from Cu-Mo floatation tailings has been furthered. Technology of "De-sliming-Magnetic Separation-Reverse Flotation-Feldspar and Silica Separation" has been developed to utilize the resource. Slime is removed and reagents cost is reduced by de-sliming. The specific effective collector ZL is used in gangues reverse flotation, and GZ-818 is the collector in feldspar and silica separation. The grinding operation is vital to ensure the liberation degree of feldspar and to eliminate the reagents pollution on minerals surface. To a Cu-Mo flotation tailing assaying K2O 5.22%, Na2O 2.22%, Fe2O3 1.95%, Al2O3 12.05%, SiO270.66%, superfine K-feldspar and silica concentrates can be produced. The feldspar concentrate productivity is 29.67% assaying K2O 8.99%, Na2O 2.86%, Fe2O3 0.16%, Al2O3 16.99% and SiO2 68.92%. The silica concentrate productivity is 14.20% assaying 0.17% K2O, 0.04% Na2O, 0.01% Fe2O3, 0.55% Al2O3 and 98.17% SiO2. The technology provides technological reference model for the similar mines.

Jan 1, 2014

By Ralph Hultgren, David W. Mitchell

MAGNESIUM alloys usually are superheated before casting in order to ensure fineness of grain. Superheat temperatures in common use range from 1600° to 1700°F while the casting temperature, which depends upon the mold shape, is usually 200° to 300°F lower. The process of superheating requires considerable time and seriously shortens the life of the iron pots used. Recently it has been reported' that if acetylene, carbon dioxide or natural gas is bubbled through molten electrolytic A.S.T.M. No. 4 alloy at 1400°F. for 5 min., grain refinement equivalent to that of superheating will take place. Addition of certain solids such as graphite or aluminum carbide accomplishes the same results.2 As will be shown in this paper, it is possible to achieve grain refinement in magnesium casting alloys at low temperatures by mechanical stirring of the molten metal for a short time. This process was developed in the course of research work, supervised by the War Metallurgy Committee under the "Restricted" Project NRC-550, for the Office of Production Research and Development of the War Production Board. This paper, based on that work, has been released for publication by the O.P.R.D. MATERIALS AND METHODS The alloys studied were the most common American sand-casting alloys designated as No. 4 and No. 17 by the American Society for Testing Materials. The magnesium used in these alloys was of both carbothermic3 and electrolytic4 origin. Chemical analyses supplied by the producers are shown in Table I. Each heat consisted of approximately 5 lb. of alloy melted in a Tercod crucible. It was refined by fluxing with Permanente No. 7* refining flux at 1300° to 1350°F. After cooling to 1200' to 1250°F., portions of approximately one pound each were ladled into iron crucibles contained in an electric furnace at about 1250°F. The molten metal was covered with Permanente No. 21† covering flux and then heated to the temperature to be investigated. Normally each of the four portions was given a different treatment. In a typical case one portion was stirred vigorously for 5 min., acetylene gas was passed through a second portion for 5 min., a third portion was superheated to 1600°F for 15 min., then cooled to casting temperature, and the fourth was held for 5 min. at the temperature of stirring or gassing without other treatment. Each portion was then cast into one-inch diameter cylinders in three "nonturbulent" molds of identical shape. One mold was made of cast iron and the other two of baked sand. The cast-iron mold and one of the baked sand molds were heated to 360°F., the other baked sand mold was at room temperature. The freezing times in these molds were

Jan 1, 1945

By M I. Pownceby, M A. Rhamdhani, S Purohit, G Brooks

The current practice of magnetite ore agglomeration involves high temperature oxidation roasting (typically at 1200–1350°C) of magnetite to hematite phase in order to improve the strength and reducibility of pellets. The requirement to pre-oxidise the magnetite before introduction to an ironmaking plant increases the CO2 emissions generated during the ironmaking process. In our previous papers, a novel, alternative agglomeration route for magnetite ores was presented where magnetite was converted to a reducible CaFe3O5 (CWF) phase through the addition of lime to produce a Lime-Magnetite Pellet (LMP) feedstock that can be directly charged to ironmaking units. The LMP process eliminates the magnetite oxidation stage, thereby reducing the CO2 emission during ironmaking. The concept was tested by thermodynamic calculations, high temperature experiments and scaled-down pilot scale test work. In this paper, larger scale synthesis of halfstoichiometric LMPs (1 mole of Fe3O4 and ½ mole of CaCO3) were prepared using a balling drum, followed by overnight drying at 110°C and induration at 1050°C for two hours. The LMPs were analysed using X-Ray Diffraction and Scanning Electron Microscope techniques for phase and microstructure characterisation. The LMPs were found to have 14–15 wt. per cent of CWF phase when indurated under a CO2/CO ratio of 8.5:1. Pilot scale testing of the LMPs was conducted following ISO standard test procedures. The test results indicated the LMP’s had a Reducibility Index (RI) of over 91 per cent, a Tumbler Index (TI) of 87 per cent and a Reduction Degradation Index (RDI) of 4.6 per cent. The results indicate LMPs may be useful as an alternative feedstock to ironmaking processes that would result in lower overall CO2 emissions.

Nov 8, 2021

By D. Nyembe, B. Mamba, Antoine F. Mulaba-Bafubiandi

Copper and cobalt are generally electro-won from their aqueous sulphate solutions. After optimised leaching of their ores, concentrates or calcine bearing minerals, the leachate is clarified and suitably purified prior to the electrolytic extraction of the metal of pursuit (Pearcy, 2006). Solvent extraction (SX) using appropriate organic solvents and ion exchange (IX) with relevant resins are known purification processes used for copper and cobalt recovery (Stanely, 1970).As zeolites in general and natural zeolites in particular, demonstrate ion exchange properties (Korkuna et al., 2005), an attempt has been made to use Southern African natural clinoptilolite in the recovery of copper and cobalt from their aqueous sulphate solutions. Initially, synthetic Co and Cu solutions were prepared. Preceded by laboratory ore leachate, plant solutions are to be used. AAS, XRF, XRD, Mossbauer spectroscopy and BET were characterization techniques used. Natural clinoptilolite was used as-received as well as acid activated; and cobalt and copper extractions were performed at room temperature.

Jan 1, 2007

By Mustafa Kumral, Yuksel Asli Sari

Underground mining operations are sensitive to price fluctuations because they usually perform with a narrow profit margin compared to open-pit mining. Furthermore, the economic evaluations regarding operation are based on estimated or simulated grades rather than actual values. These bring a high degree of uncertainty to the viability of an operation. Hence, mine planning that accounts for uncertainty is crucial for underground mining operations. As an underground mining technique, sublevel stoping has geotechnical, curing time, seismicity, cost minimization, and production requirements. A new mixedinteger linear program is proposed that considers the uncertainty associated with net present value using chance-constrained programming. The net present value (NPV) maximization objective is transformed into a multi-objective maximization problem where one objective is to maximize the mean NPV, and the other objective is to maximize the negative standard deviation multiplied by a scalar called risk or reliability level. The balance between the two objectives was maintained by this scalar and was selected based on the reliability level of the project. A case study was conducted with varying reliability levels, and sequences were generated. It was shown that the expected net present value increased at higher reliability levels, and the overall value of the objective function decreased as the reliability level increased. In other words, the variance component penalized the value of the objective function. Moreover, it was observed from the case study that at lower reliability levels, stope grade order bears similarity to the extraction order.

Aug 4, 2023