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By David Humphreys

It is difficult to overstate the importance of China to the future of the world mining and metals industries. In a remarkably short time, China has risen to become the world?s largest producer and consumer of steel and its second largest consumer of non-ferrous metals such as copper and aluminium. It is currently the world?s largest buyer of copper on international markets, the second largest buyer of iron ore, and the third largest buyer of alumina. At the same time, it is the world?s largest or second largest producer and exporter of tin, lead, zinc, magnesium and a host of minor metals and industrial minerals, as well as a fast-growing exporter of coal.

May 1, 2002

By C. A. Petch

Abstract - The High Lake polymetallic deposit is located in the northern Slave province, 40 km south of Coronation Gulf, Nunavut. The main zone, the AB zone, hosts an estimated resource of 3.56 Mt grading 5.0% copper, 1.1% zinc, 0.06% lead, 1.7 g/t gold, and 18.2 g/t silver. Archean felsic metavolcanic and metavolcaniclastic rocks are the dominant rock type and are associated with lesser mafic metavolcanic and carbonate-rich metasedimentary rocks. The sequence strikes north-northeast, dips steeply to the west, and is truncated to the west by a large granodioritic intrusion. The mineralization at the AB zone is comprised of massive and stringer chalcopyrite-sphalerite-pyrrhotitepyrite± galena. At the core of the mineralized zone, intensely chlorite-altered rocks are locally metamorphosed to form distinctive zones of anthophyllite-magnetite-cordierite-altered rock. Peripheral to the mineralized core, alteration consists of sericitization, silicification, and weaker chloritization. Primary morphology and facing direction of the zone are difficult to interpret in part due to poor primary metal zonation of the deposit. However, the irregular shape of the mineralized zone and the erratic zones of zinc enrichment at the fringes are consistent with the interpretation that the zone was formed by the replacement of a porous volcaniclastic pile.

Jan 1, 2004

By Carl L. Bieniewski

In a Bureau of Mines supply evaluation, the known uranium resources in the United States are estimated to have a total recoverable uranium oxide (U3O8) content of 3,132,400 tons at prices up to $69.32 per pound. Only those resources were evaluated for which sufficient quantity data are available and process technology exists for recovering uranium. A total of 160,800 tons of U3O8 is available at $8 per pound from ore deposits presently mined and an additional 244,700 tons available at prices up to $30 per pound from similar but usually lower grade deposits. A total of 2,726,900 tons of U3O8 is available from four other resources: copper leach solutions, wet-process phosphoric acid, Florida phosphate rock Leached zone, and Chattanooga Shale. These resources contain from 30,000 tons of recoverable U30, at a price of $7.52 per pound as a byproduct of copper leach solutions to 2,557,300 tons at a price of $69.32 per pound from Chattanooga Shale.

Jan 1, 1971

By Lise Chénard

El presente texto señala los lineamientos del proyecto REFORMIN, así como su repercusión en la dinámica de promoción de la industria minera. REFORMIN surge en el 2001 como un proyecto bilateral entre Canadá y Bolivia, cuyo financiamiento proviene de la Agencia Canadiense de Desarrollo Internacional (ACDI). Su finalidad es apoyar al Viceministerio de Minas, facilitándole el acceso a la pericia canadiense para lograr una gestión más sana y eficaz de los recursos minerales del país. Para ello, se basa en los principios fundamentales tales como: mejora de la gestión del medioambiente minero, apoyo a la prevención y gestión de conflictos sociales en las comunidades mineras, a los mineros artesanales y a la promoción de los recursos minerales del país, -en tanto benefician al desarrollo de la industria minera en un contexto de mercado globalizado.

Apr 22, 2003

By Leiv Kolbeinsen, Stian Seim, In-ho Jung

"The current work presents new experimental data in the iron-unsaturated region of the FeTiO3-Ti2O3-TiO2 slag system. The samples are prepared by melting pure reactants in a high frequency induction furnace that employs a cold crucible. A similar experimental set-up has been described in literature and proven suitable to investigate high titania slags. The FeO content of the samples range from 3.7 to 21.8 wt% and the Ti2O3 content range from 3.6 to 30.1 wt%. The liquidus temperatures of the samples are measured in-situ by a spectropyrometer and range from 1450 to 1645 °C.In addition, an improved thermodynamic database for the FeO-Ti2O3-TiO2 system has been developed. Ternary parameters have been included and optimized to fit previously published experimental data. This optimization minimizes the discrepancy between experimental data and thermodynamic calculations as previously discussed in literature. New liquidus projection plots are proposed for the FeO-Ti2O3-TiO2 and the FeTiO3-Ti2O3-TiO2 systems.IntroductionIlmenite (FeTiOs) smelting is a relatively small industry world-wide. However, a reasonable focus on the process has been applied in Norway due to the location of one such smelter in Tyssedal, which is located in the western part of Norway. The process is essentially carbothermal reduction, where most of the iron in the ilmenite is reduced to its metallic state, and the titanium oxide is concentrated in the slag product. The metallic iron is sold as a high purity pig iron and finds applications in cast products. The slag concentrate is further processed for the production of TiOvpigment and/or titanium metal. This further processing can be performed through different routes according to the purity of the slag concentrate."

Jan 1, 2012

By John Brennan

OK, I’ll admit it: I’ve always been a big Monty Atwater fan. Not only is the man credited with being the father of modern avalanche forecasting and safety in the United States, but he is also responsible for developing the avalauncher. Through its more than 40-year history, the avalauncher has gone through many changes yet continues to prove its worth in avalanche mitigation work.

Jan 1, 2007

By S. Feuerstein

THE influence of environment on the mechanical properties of metals has been extensively studied and documented.' Most investigations have dealt with an interaction between a particular environment and a specific metal surface and the concomitant change in bulk mechanical behavior. Typical contributing media are oxide and metal film:;, electrolytes, and other surface-active agents. In the last category fall controlled gaseous environs (i.e., pressure or vacuum). Most vacuum exposure experiments prior to 1963 were conducted at pressures s>10-6 torr and elevated temperatures, or in such a manner as to prolong the exposure (e.g., by stress-rupture, creep, and fatigue). Little attention has been given to vacuum environment effects on the mechanical behavior of metals subjected to simple uniaxial deformation at room temperature. Test times and temperatures were assumed too ineffective as far as bulk changes were concerned. Further, the contribution of surface effects to the bulk mechanical behavior of metals was considered minimal. Under vacuums of the order of 1.0- 8torr and higher, molecular densities and, consequently, the rate of monolayer formation are such that exposures from seconds to days would be required for complete gas coverage. Thus, atomically clean surfaces created under ultra-high vacuum could conceivably maintain their cleanliness for time intervals orders of magnitude greater than at higher pressures. The influence of this unusual type of environmental surface phenomenon on the short-term bulk mechanical behavior of aluminum was first observed by Krame and Podlaseck in 1963.' kin equivalent effect was reported for magnesium by Williams and Nelson.3 It was concluded from these studies2,3 that vacuum and, consequently, the monolayer formation rate of the oxide, were responsible for the described changes in flow behavior. The presence of an oxide layer impedes dis- I) EXPERIMENTAL DATA: MOLYBDENUM The tensile behavior of molybdenum was investigated by the author4-6 at ambient temperature over a range of pressures from 760 to 10-10 torr. These studies revealed that the flow behavior of the bulk specimens (0.200 in. diam by 2 in. gage length) was independent of pressure on sintered (0.062 mm grain size) and arc-cast polycrystals (0.012 to 0.149 mm grain sizes) and single crystals. Since the specimens were relatively large in size, it was assumed that any flow behavior effect would be surface-limited because of the short-term deformation procedure. Strain-rate-change experiments performed to determine the activation volumes for individual specimens at 760 to 10- 10 torr further indicated that the surface flow contribution was either minimal or zero, contrary to the findings of Shen el a1.7 on aluminum. Although the flow behaviors did not change, specimen ductility did change. For the sintered material at a strain rate of 4.2 x 10-4, specimen ductility was -9 pct higher at l0- 10 torr than at atmospheric pressure (dry nitrogen). A more comprehensive investigations on this same material revealed a distinct pressure dependence, Fig. 1. Intermediate and atmospheric pressure tests were obtained by backfilling the system from l0- 10 torr with extra dry, prepurified nitrogen. Other environments (air and purified argon) were also utilized for the 760 torr experiments; the results were essentially the same as those for dry nitrogen atmospheres. Departure from the fracture strain values obtained at 760 torr takes place in the vicinity of l0-6 torr, as indicated by the scatter band; a noticeable ductility increase is apparent at l0-8 and 10-10 torr.

Jan 1, 1970

By Armin C. Supp

Since 1975, about a dozen high capacity flotation plants have been installed in the Ruhr district. Depending on the size of the preparation plants, the design capacity of the flotation section is between 100 - 150 t/h. The flotation units generally comprise rougher and cleaner stages in which 5 to 6 or 4 to 5 agitators respectively are arranged in line. The unit volume allocated to each agitator is up to 16 m3. The type of flotation machines, the design of these plants and their instrumen¬tation and control equipment are described in detail. The run of mine coal in the Ruhr district is characterized by a wide variety of the volatile matter. Generally, a distinction must be made between coals with more than 30 - 35% V.M., which are preferably used in power station, and coal with lower V.M. content, which are preferably used as coke-oven feed. The difference between these coals in respect to grain-size distribution, ash cotent and flotation properties will also be described in detail.

Jan 1, 1985

By Herry Poernomo, Agus Prasetya, Iga Trisnawati, Himawan Tri Bayu Murti Petrus, Gyan Prameswara, Panut Mulyono

We studied yttrium extraction from untreated zircon sand processing waste tailings. Xenotime mineral as the rare earth element source with an abundance of yttrium (REY) was detected in sufficient grade for extraction. As much as 9.03% yttrium exists in zircon tailings (analysed by X-ray fluorescence spectrometry). The presence of yttrium was confirmed by X-ray diffractometry in xenotime minerals, which are yttrium carriers (Y-PO4). The purpose of this research was to determine the effect of leaching conditions on yttrium recovery from zircon sand after alkaline fusion treatment. Alkaline fusion was chosen to decompose phosphate into hydroxide in the xenotimemineral,which will reduce further required hydrometallurgical processing.Alkaline fusionwas carried out for 3 h at 450 °C, with a ratio of sodium hydroxide to zircon tailings sand of ~ 1:1. The alkaline fusion product was leached with water, followed by hydrochloric acid treatment to leach the yttrium. Yttrium recovery reached 87% under optimum conditions (60 °C, 1MHCl, and solid-to-liquid ratio = 1/10 for 7.5 min). A suitable model for yttrium dissolution with hydrochloric acid was diffusion through a solid particle ash layer. The calculated activation energy (EA) for this model was 20.21 kJ/mol.

May 26, 2020

Would you give us a short biographical sketch including your birthplace, education and current activities? I was born Jan. 16, 1920 in Minneapolis, Minnesota, and lived there the first 22 years of my life. I also spent quite a bit of time on a farm about fifty miles north of Minneapolis owned by relatives. During the Depression, we lived off of ten cows and about fifty chickens. I'm a full-blooded Swede all along the line, and I'll be the last one in my family since my wife is not of Swedish descent. I attended Macalester College, a small school in St. Paul, to study for the ministry originally. However I soon realized that I really didn't have the talents for the ministry and I could probably do as much or more in a field where I did have some talent.

Jan 3, 1974

By Takaaki Wajima

The slag was attempted to be converted into the adsorbent for phosphate removal from aqueous solution using the alkali fusion method. The slag was mixed with NaOH powder (NaOH / Slag = 1.6), and then the mixture was heated at 600 ? for 6 h to prepare the precursor. The precursor was stirred at room temperature in distilled water to synthesize the adsorbent, and the removal ability of the obtained adsorbent for phosphate from aqueous solution was investigated. The products, including hydrocalumite and calcite, were synthesized, and the removal efficiencies of the adsorbent for F- and PO43- showed higher than those of raw BF slag, especially removal of PO43- are excellent (99 %), while the removal of Cl- , SO42-, NO3- and Br- was minor. The adsorbent could remove PO43- selectively in the co-existing solution of Cl-, NO3-, F-, SO42- and Br-.The equilibrium adsorption capacity of the adsorbent for PO43- was extrapolated using Langmuir and Freundlich models, and experimental data are found to fit Langmuir than Freundlich. The calculated maximum adsorption capacity of the adsorbent for PO43- is higher than other adsorbent reported previously. The high affinity of the adsorbent for PO43- in aqueous solution was caused by the formation of hydroxyapatite [Ca5(PO4)3(OH)] and brushite [CaHPO4?2H2O]. The prepared adsorbent is expected to be anew inorganic adsorbent for the removal of phosphate ion from wastewater. Keywords: Blast furnace slag, Alkali fusion, Phosphate removal, High selectivity

Sep 1, 2012

By Fredrick L. Johnson

In 1984, at the request of the U.S. Forest Service, the U.5, Bureau of Mines began a study of the 94,370-acre Arc Dome study area (4-667) in order to appraise its mineral resources, The Bureau of Mines mapped and sampled mines, prospects, and mineralized sites in and near the area, The study area is located in the Toiyabe National Forest, about 54 mi north of Tonopah, Nye County, NV, It is estimated that over 500 claims have been staked in the study area since the mid-1800?s. In January 1986, there were 108 active mining claims completely inside and 59 on the boundary. Another 283 active claims were outside the study area but within 1 mi of the boundary, In addition to the large number of claims staked, exploration activity is also reflected by the almost 700 inactive workings that were found during field investigation.

Jan 1, 1989

By O. Nomland

The work of The Bahrein Petroleum Company, Ltd., on Bahrein Island consisted mainly in continuing development work and prospecting previously reported. The exploratory work, however, has been greatly minimized and new wells are being drilled, chiefly for the development of larger production; 20 wells had been completed by the end of 1935 and 8 were being drilled. In addition to what has been referred to as the ''main pay," two deeper productive horizons have been discovered, which apparently will greatly increase the potential of the field although the areal extent of this lower production has not yet been determined. The proven acreage of the "main pay" is more than 12,500 acres. Current production (principally from the upper horizons) is about 13,400 bbl. a day. The construction of a 10,000-bb1.-a-day refinery has begun and is to be in operation by July, 1936. It is expected that the capacity will be considerably increased at a later date. The construction of office buildings and a permanent camp has been almost completed. In Saudi Arabia the California Arabian Standard Oil Co., a wholly owned subsidiary of the Standard Oil Company of California, spudded in a well in April, 1935, near the village of Dammam, on the Persian Gulf coast of A1 Hasa. Although several important showings of high-gravity oil and considerable gas have been found, the well is not yet considcred a commercial producer. Dammam well No. 2 has been started farther south on the same structure. A great deal of reconnaissance and some detailed geological work has been completed during the last three field seasons. In order to overcome difficulties of transportation over the desert sand, unusual methods have been used. The parlies penctrating the interior by the use of automobiles and trucks have been supplied with gasoline and provisions by caravans of camels. Mail and supp1ies of lighter weight urgently needed have been carried to the field men by an airplane operated by the geological division of the company. Each party has been supplied with a radio receiving and transmitting set to keep in contact with the airplane as well as with geological headquarters at Jubail on the coast of A1 Hasa.

Jan 1, 1936

By O. Nomland

The work of The Bahrein Petroleum Company, Ltd., on Bahrein Island consisted mainly in continuing development work and prospecting previously reported. The exploratory work, however, has been greatly minimized and new wells are being drilled, chiefly for the development of larger production; 20 wells had been completed by the end of 1935 and 8 were being drilled. In addition to what has been referred to as the ''main pay," two deeper productive horizons have been discovered, which apparently will greatly increase the potential of the field although the areal extent of this lower production has not yet been determined. The proven acreage of the "main pay" is more than 12,500 acres. Current production (principally from the upper horizons) is about 13,400 bbl. a day. The construction of a 10,000-bb1.-a-day refinery has begun and is to be in operation by July, 1936. It is expected that the capacity will be considerably increased at a later date. The construction of office buildings and a permanent camp has been almost completed. In Saudi Arabia the California Arabian Standard Oil Co., a wholly owned subsidiary of the Standard Oil Company of California, spudded in a well in April, 1935, near the village of Dammam, on the Persian Gulf coast of A1 Hasa. Although several important showings of high-gravity oil and considerable gas have been found, the well is not yet considcred a commercial producer. Dammam well No. 2 has been started farther south on the same structure. A great deal of reconnaissance and some detailed geological work has been completed during the last three field seasons. In order to overcome difficulties of transportation over the desert sand, unusual methods have been used. The parlies penctrating the interior by the use of automobiles and trucks have been supplied with gasoline and provisions by caravans of camels. Mail and supp1ies of lighter weight urgently needed have been carried to the field men by an airplane operated by the geological division of the company. Each party has been supplied with a radio receiving and transmitting set to keep in contact with the airplane as well as with geological headquarters at Jubail on the coast of A1 Hasa.

Jan 1, 1936

By R. J. Roman

Several research groups have spent considerable time investigating coarse ore leaching. Coarse ore leaching includes both heap and dump leaching. The term "heap leaching" will be used in this paper to mean any type of coarse ore leaching. The results of their work are generally in agreement: the progress of leaching can be described by the shrinking core model and its associated mathematics. The shrinking core model is schematically represented in Figure 1. The particle is contacted by the leach solution on its outside surface and the solution migrates inward by filling the pores on the particle. As the solution filling the pores comes in contact with grains of ore mineral the reagent chemically reacts with the ore mineral to solubilize the contained metal. The solubilized metal diffuses outward to the particle surface and is washed away by the leach solution flowing past the particle. The leaching reagent in the particle interior is replenished by the diffusion of reagent from the surface of the particle to the interior of the particle. If the chemical reaction between the leaching reagent and the ore mineral is relatively fast compared to the diffusion rate of the reagent in the solution in the pores of the particle then leaching proceeds from the outside of the particle inward resulting in a "shrinking core" of unreacted ore surrounded by a "leached shell". The rate controlling step in the reaction can initially be a chemical reaction between the reagent and the ore mineral grain, however, once the reaction has proceeded a short period of time diffusion of the leaching reagent through the leached shell will be the slow step and hence the rate controlling step in the production of metal from an ore particle.

Jan 1, 1992

By K. Knuutila

The behaviour of thiourea, animal glue and chloride ions in the electro¬lysis of copper has been investigated by various different electrochemical experiments, i.e. polarization curves with stationary copper electrodes, long-time galvanostatic electrolyses and Hull cell experiments. Polarization curves with stationary copper electrodes show that animal glue has a polarizative effect on the deposition potential. Small thiourea contents affect depolarizatively when high concentrations retard the copper deposition. The microstructures of the deposited copper after the long-time electrolyses show that animal glue favours a basis oriented deposition structure. With thiourea the field orientated structure was evident. It was also observed that the deposited structure depended much on the grain structure of the starter sheet. The chloride ion concentration has a drastic effect on. the crystal size of the deposited copper as it was found out in Hull cell tests. Chloride ions flattened the the crystals and the deposition became smoother when the chloride ions were added. The cathode copper quality is discussed according to the literature. Special attention is paid on the codeposition of thiourea and the origin of sulphur impurities in copper cathodes.

Jan 1, 1987

By François Robert

"The Eastern Abitibi Sub province (Quebec segment), contains two main types of gold deposits: the common quartz-vein type and the rare pyritic type. Both occur in areas dominated by volcanic rocks and are spatially associated with major fault zones.Quartz-vein gold deposits consist of simple to complex networks of quartz-carbonate-pyrite veins in reverse shear zones and extensional fractures. They occur in areas dominated by mafic volcanic rocks and are commonly associated with small syn- to late-tectonic porphyritic felsic intrusions. Associated alteration, which postdates peak metamorphism, is dominated by carbonatization, sericitization and pyritization of the wallrocks. These deposits formed late in the geologicalevolution of the Abitibi.Pyritic gold deposits range from deformed massive sulphide lenses to zones of syntectonic pyrite-rich veinlets and associated pyrite disseminations. These deposits occur in environments dominated by felsic volcanic rocks that are typically converted to sericite schists near the deposits. The associated pre-metamorphic aluminous alteration is now characterized by metamorphic sericite, andalusite, kyanite and chloritoid, overprinted by a late retrogression of alumino- silicates. These deposits probably represent deformed volcanogenic massive sulphide deposits, but the timing of gold introduction in these is not fully understood.The differences in geological attributes reflect significant differences in the genesis these deposits: the pyritic deposits probably have a multistage genesis, including a pre-tectonic stage, in contrast to a single stage late-tectonic genesis for the quartz-vein deposits.RESUMELa partie Est de la Sous-Province de l’Abitibi( segment québécois) renferme deux types de gites d' or: ceux de type ""veine de quartz"" et ceux, plus rares, de type ""pyriteux"". Ces deux types se trouvent dans des secteurs particulièrement riches en roches volcaniques et mantrent une association spatiale avec des zones de failles majeures.Les gites de type ""veine de quartz"" correspondent à des réseaux de complexité variable de veines de quartz-carbonate-pyrite se développant dans des zones de cisaillement inverse et des fractures de tension. Ils se concentrent dans les régions dominées par des roches volcaniques mafiques et s’associent fréquemment à de petites intrusions porphyriques felsiques syn- a tardi-tectoniques. L’altération associée ace type de glte est postérieure à la phase majeure du métamorphisme et consiste en une carbonatisation, une sericitisation et une pyritisation des épontes. La mise en place de ces gites est tardive par rapport à l'évolution géologique de l'Abitibi.Les gites d' or de type pyriteux consistent en des lentilles de sulfures massifs déformes, des zones d' abondantes veinules pyrite uses syntectoniques, et des zones de pyrite disséminée. Ces gites se retrouvent dans des empilements contenant surtout des roches volcaniques felsiques qui sont transformées en schiste à séricine pres des gisements. L’altération a l’umineuse pre-metamorphique associée a ce type de glte a donné naissance, lors du metamorphisme regional, a la sericite, a 'andal ousite, a Ia lcyanite et au chloritoi""de; par la suite, les alumino-silicates ont été affectes par une alteration retrograde tardive. Ces gites representent probablement des depOts de sulfures massifs volcan gènes déformes, mais la chronologie de la mise en place de l'or dans ceux-ci est encore mal comprise.Les caractéristiques géologiques propres à chacun de ces types de gites reflètent des conditions de formation différentes: le type ""pyriteux"" montre une histoire génétique polyphasée, incluant une étape pre-tectonique alors que le type ""veine de quartz"" s’est développe au cours d’une seule phase tardi-tectonique."

Jan 1, 1990

The properties of interfacial water at hydrophilic surfaces are of great importance in many technological areas including flotation, solid-liquid separation, dispersion and emulsions, flocculation, adsorption, corrosion, and soil contamination. This paper examines the use of FTIR/internal reflection spectroscopy (FTIR/IRS) to study the spectral characteristics of interfacial water at silica surfaces. FTIR spectra were characterized by consideration of the OH stretching region (3000-3800 cm-1) associated with the vibrational spectra of interfacial water. The broad peak in this region was deconvoluted in order to isolate overlapping spectral features that describe the nature of hydrogen bonding in interfacial water. Three distinct bands were found; -3600 cm-1 (free OH), -3400 cm-1 (incomplete tetrahedral coordination), and -3240 cm-1 (complete tetrahedral coordination) and the variation of their intensities with pH was found to be significant. This spectral information helps to explain orientation and bond ordering of interfacial water molecules at hydrophilic surfaces.

Jan 1, 1998

By N. M. Raju, B. Singh

The paper seeks to present the results of experimentation in room and pillar stopes with different ground conditions to determine the safe working span. In the experimental stopes, ground movement was monitored with gradual widening of the room span. The field measurements included closure between the stope walls and the extent of ground movement in the hangwall using borehole extensometers. hock bolting was used as an exclusive support system which enabled introduction of scrapers for improving productivity. In one nine, phosphate bed, 3 to 3.5 m thick dipping at 45O and overlaid by weak laminated shale, was worked at shallow depth of cover. h the experimental panel, five s topes were worked with spans varying from 5.5 to 7 m. In the second mine, the chalcopyrite orebody up to 6 m in thickness dipping at 25 - 30" was worked at a depth of 1100 m. The hangwall consisted of fairly competent schistose rocks and therefore 10 to 15 m wide spans could be experimented. The field measurements confirmed that in the phosphate mine with weak shale roof, 7 m span could be safely worked with subsequent caving of the bolted roof. In the copper mine, 15 m span could be worked and the stopes required subsequent backfilling for better ground control.

Jan 1, 1983

By G. J. Kipouros, N. Dadvand

"In recent years coatings of alloys have been produced for a wide range of applications including many for wire bonding application. The main characteristic of the baths of electroless plating is the presence of sodium hypophosphite as a reducing agent and also as the supplier of phosphorus. In the electroplating of alloys the Watts bath is predominantly used. This presentation compares the two techniques, electroless plating and electroplating, and discusses the possibilities of cross utilization of sodium hypophosphite in an attempt to formulate baths that eliminate the waste disposal issue related to some components.INTRODUCTIONThe importance of surface characteristics and the linkage of surface coating process to surface characterization has given rise to the evolution of surface engineering. Not only the surface preparation and morphology has become very important to the coating technology but also the knowledge of surface area exposed to the process of coating or corrosion is absolutely essential in ascertaining the behaviour of coatings and their adherence to the substrate. The above concepts are not unknown to researchers involved in the protection of surfaces, particularly metallic, from corrosion and/or erosion corrosion. However, the complexity of the surface defects, roughness, porosity, interconnected porosity and other related factors have contributed to the uncertainty of the true surface area versus the nominal surface area. Therefore critical parameters such as current density and chemical surface intensity although have been studied extensively at the atomistic level by carefully prepared surfaces are very difficult to be determined at the practical scale required during the coating processes.The most pronounced case calling for an understanding the relationship between the surface area and the effective protection is the coating of surfaces of items produced by compression or consolidation of powdery materials. With the advent of nanomaterials and the additive manufacturing through 3D metal printing this issue is becoming more important. Certain experience in this field come from the accumulated knowledge resulted from the attempts to characterize the electrochemical behaviour of powder metallurgy metals and alloys. Powder metallurgy has been a well-established process for half a century on basic metals such as iron, copper and their alloys. Recently the development of powder metallurgy process for aluminum, titanium and attempts to develop powder metallurgy processes for magnesium and its alloys has brought to light another important issue that of the development of coatings on difficult to plate reactive metals such as aluminum and magnesium. Despite of many successes in the development of powder metallurgy alloys the exact characterization of the corrosion behaviour of the coatings and the substrates is difficult to determine because of the unknown morphology of the exposed area i.e. the exact morphology and area of the exposed surface (Samal, 2007)."

Jan 1, 2016