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By J. M. Davey

Lead-zinc sulphide ores at Mount Isa are currently treated at the rate of 180,000 long tons per 28 day period in the No. 2 Concentrator of Mount Isa Mines Limited. Prior to June 1966 lead-zinc ore was treated in part of the No. 1 Concentrator up to a rate of 70,000 long tons per period. Since 1955, two major changes in ore type being processed have occurred. Because of these changes, problems arising from treatment of the ore have altered and during the period several major changes in practice have been advocated and experimentally tested. Most of these flow sheets were developed with a view to overcoming one major problem in the ore. These were invariably abandoned as the Mount Isa lead-zinc ore contains a number of equally major problems all of which must be overcome in the treatment process. MINERALOGY The orebodies are situated in the Mount Isa Shale Group which is Proterozoic in age (Carpentarian System). The sediments consist dominantly of fine grained dolomitic, quartzo-feldspathic shales and siltstones. Specifically, the Mount Isa orebodies lie in the Urquhart shale formation which is characterised by sediments of high albite and orthoclase content denoting a large volcanic component. The Urquhart shales are approximately 3,500 feet thick and extend at least north and south of Mount Isa for 20 miles in each direction. In the area of the silver-lead-zinc orebodies the Urquhart shales are highly pyritic and have a relatively high carbon content. The

Jan 1, 1970

By Michael Chender

The current outlook for financing new copper production is not very encouraging. At a time when companies are slogging through a protracted period of low prices as well as having to accept lower profits due to more stringent tax and royalty schedules, banks are beginning to require companies to take a greater equity interest in new projects. Mineral resource financing, including copper, seems to have lost much of its appeal to the lending institutions, and loans of any kind to many of the developing countries -from which over half of new copper capacity could be expected to come-are being examined much more critically than they were in the late 1960's and early 1970's.

Jan 12, 1976

By Robert Mehl

THE mechanical behavior of metals and alloys is presumably conditioned by two factors; namely, the crystalline symmetry and the interatomic forces. Considerable attention has been given to the first of these factors through the recent advances in X-ray .technique. It is the purpose of the present paper to call attention to the importance of the second of these factors, to point out promising methods of investigation, and to present some pertinent data. Plastic deformation takes place by-slip along atomic planes.1 This slip may be inhibited in a number of ways: by the interatomic forces of cohesion which bind the atoms rigidly in a lattice structure, which in pure metals is usually of high symmetry; by lattice distortion caused by solid ,solution formation or by mechanical strain; by the intercrystalline boundaries where slip is restrained by the non-registration of the atom planes in adjacent crystallites;2 and by the presence of small hard particles which serve to "key" the slip along the atom planes.3 In pure metals, and perhaps also in solid solutions, the atom planes, of easiest slip are those exhibiting the greatest density of atomic population and the greatest interplanar distance4 and apparently can now be predicted from the analysis of the lattices. Concerning the interatornic forces, which resist this slip by holding the atoms firmly together, little is known. Most textbooks on physical metallurgy, following the work of Bot-tone,5 correlate the hardness of the pure metals with the atomic volume;.

Jan 1, 1928

By Alan R. Grant

The Cascade Range of Washington can be considered metallogenetically to be primarily a copper province. Structural and chemical data compiled from examination of numerous copper occurrences in the Cascades indicate a marked parallel of physical conditions for sulfide deposition. In probable order of significance, the environmental criteria are as follows: 1) adjacent or subjacent, postregional metamorphism high-level intrusive activity, most commonly in the time range from 15 million years to 30 million years; 2) transverse northeast trending structural belts which obliquely cut the northwest regional trend of the range; 3) potassium-silica wall rock alteration; most important of the alteration suite of silicates are orthoclase secondary biotite and quartz; 4) the intersection of northwest trending and northeast trending structures. The varying geologic environments in the Washington Cascades present a complex setting for the sulfide deposits. The North Cascades are comprised of predominantly pre-Tertiary metamorphic rocks invaded by Tertiary calcalkaline intrustive rocks. The Central Cascades, lying south of the North Cascades, exhibit a younger, higher level geologic environment comprised of predominantly early to middle Tertiary volcanic rocks and subordinate sedimentary rocks which are intruded by Tertiary calc-alkaline igneous rocks. Although the Tertiary Cascade intrusions are dominantly quartz dioritic, copper mineralization is commonly found in rocks of quartz monzonite to granite composition. These acid rocks appear to be the product of late stage magmatic K alteration of the original quartz diorites. Sulfide concentrations are considered to be in part dependent on the degree of K-silicate activity and the intensity of transverse structural deformation.

Jan 1, 1973

By E. Hoek

The stability of a rock structure depends primarily upon the extent to which fracture develops within the structure, The prediction of the extent of potential fracture, the first step in the study of fracture development, involves a knowledge of both the stress distribution in the structure and the criterion which governs rock fracture under various stress conditions. While a great deal of research effort has been devoted to the development of techniques for analyzing the stresses in mining and civil engineering structures1-3 and to the investigation of the fracture mechanism of rock 4-6 relatively little attention has been paid to the application of available knowledge to the solution of practical engineering problems. This paper describes a photoelastic technique for the determination of potential fracture zones in certain types of rock structures. A practical example, based upon a problem which might be encountered in designing the layout of deep-level mine excavations, is given as an illustration of the application of this technique. STRESS ANALYSIS AND ROCK FRACTURE In deciding upon the technique to be used for the solution of a problem involving the prediction of rock fracture it is necessary to consider: 1) What type of stress information is required to satisfy the fracture criterion for rock; anti 2) How this information can most conveniently be obtained. It has been established, both theoretically 4,7 and experimentally 5,6,8that the fracture of hard rock depends primarily upon the relationship between the algebraically greatest and the algebraically smallest of the

Jan 1, 1967

By L. D. Godshall

A great deal has been written of late regarding the loss of silver in assaying; very discordant results have been published by different writers, and much uncertainty exists concerning even approximate losses in a careful determination of silver, as represented by a fire-assay. In the present paper it has been the aim of the writer to determine as accurately as possible the losses sustained by silver, under certain specified conditions, during the process of cupellation. Such losses are well known to be due to absorption by the cupel and volatilization. The conditions, however, which govern these losses are not believed by the writer to be so well understood. The most important of these are : 1. The effect of variable quantities of silver used. 2. The temperature of cupellation. 3. The character and quantity of impurities in the lead button. 4. The weight of the lead button. 5. The nature of the cupel. The following experiments were made for the purpose of demonstrating, as nearly as possible, the total loss of silver in cupellation under the most favorable conditions to be obtained in commercial assaying. Chemically pure silver and pure lead were taken. The latter was obtained from test-lead, first melted into a bar, from which pieces of the desired weight were cut and accurately weighed. The experiments recorded in this paper were planned by the writer, but executed throughout by Mr. J. N. Walker, whose ability as an accurate, careful and painstaking assayer is too well known and recognized throughout the West to require any further endorsement from me.

Jan 1, 1897

By Ripu Daman Lama

The size of coal pillars in mines until recently has been determined by experience without being based upon scientific investigations. As a consequence, the size of pillars had invariably been larger than could be accounted for because of the number of unknown factors involved which influence the strength, dictating the use of large safety factors. With the mining going deeper, the size of the pillars greatly increases and sometimes a considerable portion of the mineral property are blocked in the mine pillars required to support the superincumbent strata. With the advances in the field of Rock Mechanics, attention of mine planning engineers has been focused upon the design of mine pillars for safe and efficient working as well as decrease losses of coal. The problem involves the study of three factors: (1) Presence of stresses in the area and their distribution on pillars in the course of extraction. (2) The influence of external factors on the strength of coal. (3) The inherent mechanical properties of coal. These aspects have been studied by a large number of investigators, the first by in-situ stress measurements and photoelastic studies and the second and third aspect by studies conducted in the laboratory on small size specimens (Bunting, 1911; Evens & Pomeroy, 1961; Gaddy, 1956; Greenland et al, 1941; Steart 1954). The size of the specimens tested in the laboratory has been limited to a few inches and the results obtained have been extrapolated by large factors, sometimes several hundred times the largest specimen tested. In these tests much consideration has not been given to

Jan 1, 1971

By J. J. Bailey, R. C. Dean

Dr. Maurer has reviewed the large and confused field of rock mechanics and drilling. We have focused our attention on advance drilling and the disengagement of rock. To understand drilling in greater detail is certainly desirable, but such understanding does not necessarily hold any certain promise of near-term practical advancement. In the longer term, it is probably essential. Present work on drilling and our understanding of drilling falls roughly into three separate classes (and, indeed, these are in no way peculiar to drilling): 1) we have knowledge of certain (scientific) topics which seem to be relevant to the process, 2) we have knowledge of the drilling process in both qualitative and quantitative terms from observation of the actual process, and 3) we have certain modeling procedures, by which we bridge the gap between these two previous areas. The usefulness of our scientific knowledge depends critically upon this last item. In all our following remarks we shall consider only those problems of drilling and the disengagement of rock in which the rock behavior is essentially brittle. Let us start by examining some of the problems of constructing an even moderately detailed theoretical model of the drilling process in the small. The prospects of any near-term success in that direction seem extremely meagre; nor is it clear that any great advancement in the practical art of drilling is even likely to result from the construction of such a detailed model. On the other hand, as we shall suggest later, considera-

Jan 1, 1967

By Dorsey Hager

THE rapid increase of water troubles in the Mid-Continent oil fields is causing much alarm. Troubles occur at Towanda, Eldorado, Augusta, Cushing, Blackwell, and Healdton, although they had, not been acute in the Mid-Continent field until about two years ago, when the unusual conditions in the deeper oil fields were first encountered. California faced the same situation, but, thanks to aggressive measures, has largely overcome the dangers. The following analysis of water trouble may throw some light on the subject and be of assistance in solving the problems involved. WATER TROUBLES CLASSIFIED The presence of water in large quantities in oil sands has the following results: 1. Diminishes oil production. 2. Diminishes casing-head gasoline production: (a) By curtailing the gas flow. (b) By making the use of vacuum pumps unsuccessful. 3. Increases lifting costs: (a) By making it necessary to pump large quantities of water, which requires. a fast motion and long stroke (third hole). (b) By requiring the use of compressors for air lift. (c) By causing break-downs and delays due to the high speed necessary to pump water. (d) By making it necessary to treat "cut" or emulsified oil. Oil production is seriously curtailed by the presence of large quantities of water. Lease records show that wells are shut down 40 to 60 per cent. of the pumping time where serious water trouble occurs. While a small quantity of salt water may cut the paraffine and keep the oil moving, several hundred feet, or a hole full of water, effectually "kills" the oil

Jan 10, 1918

By M. S. King, B. N. P. Paulsson

Four vertical boreholes in the vicinity of an electrical heater simulating a canister of nuclear waste in a granitic rock mass have been logged with an acoustic borehole sonde before and after thirteen months' heating. Excellent control of the structural geology and fractures present in the rock mass was provided by the considerable amount of oriented core recovered from the four boreholes used for acoustic logging and the large number of others used for a variety of rock mechanics instrumentation. Compressional and shear-wave velocities were measured as a function of stress on some twenty core samples, water-saturated and dry, which were recovered from the four acoustic logging boreholes. Further control was provided by a cross- hole acoustic monitoring program conducted before, during and after heating between the same four boreholes, and by measurements of acoustic velocities in an isolated block of granite in the same heater drift, which was subjected to an increase in temperature and to changes in uniaxial stress. It is concluded from the acoustic logging tests, taken in conjunction with the acoustic cross-hole and heated block experiments, that acoustic techniques: 1. Provide a means for locating and delineating systems of weakly- bonded or open fractures within the rock mass; 2. Provide a sensitive means for monitoring a rock mass for changes in moisture content or structural damage to the rock fabric induced by thermal or mechanical loading; 3. Together with the rock bulk density yield the elastic constants of the rock mass.

Jan 1, 1982

By Richard W. Lodge

The following work, performed by Mr. W. A. Tucker, of the class of 1893, in the mining department of the Massachusetts Institute of Technology, seems to me to be worthy of publication. I believe it has always been considered that the presence of arsenic especially interferes with the extraction of gold by the cyanide method. Mr. Tucker's work, although made on a laboratory scale, certainly seems to disprove this view, and to show that even with a very large percentage of arsenic present in the ore, a high extraction may be obtained without an excessive consumption of potassic cyanide. The ore from which the concentrates were obtained was a gray argillaceous schist. and slate, with stringers and veins of quartz running through it. It carried free gold and about 12 per cent. of sulphides. The ore was crushed with stamps; the free gold was collected in the ordinary way on silver-amalgamated copper plates; and the sulphides, which consisted chiefly of arsenopyrite and pyrite, with very small amounts of galena and chalcopyrite, were concentrated and collected by means of a Frue vanner. A carefully-taken sample gave: Gold,........6.17 ounces per ton. Arsenic,.......30.6 per cent. The latter figure would correspond to about 66.5 per cent,. of arsenopyrite in the concentrates. The work to be done was outlined as follows: 1. Sizing the concentrates; 2. Assaying the different sizings; 3. Treating these different sizings with ECy of different degrees of strength for different periods of time.

Jan 1, 1896

By J. W. Koger, R. E. Hurnrnel

QUENCHED, bcc p brass, P1, transforms to a mar-tensitic phase, when it is cooled below room temperature.' This transformation can be followed using resistance measurements since the resistivity of the martensitic phase is considerably larger than that of the parent phase, Fig. 1.' phillips3 first reported that, when Cu-Zn alloys containing between 37.0 and 39.0 wt pct Zn were quenched from the 0 region to room temperature, variable amounts of a phase could be observed depending on the mode of quenching. If the quench occurs very rapidly, the a phase forms by a "massive transformation". The resultant phase has the same composition as the high-temperature P phase from which it was formed. If the quench is less severe, the alloy is retained largely in the p form; however, some a is formed by precipitation. In this case, a contains more copper than the high-temperature 0 phase from which it has formed. The a phase most probably does not undergo a transformation in the temperature range where p transforms to low-temperature martensite. This can be deduced from the Eesistivity-temperature relation which is linear in this temperature range, Fig. 2. The stable a phase which is present along with R. E. HUMMEL is Assistant Professor, Department of Metallurgical and Materials Engineering, University of Florida, Gainesville, Fla. J. W. KOGER, Junior Member AIME, formerly with University of Florida, is now with Oak Ridge National Laboratory, Oak Ridge, Tenn. Manuscript submitted December 13, 1967. IMD.

Jan 1, 1969

A discussion of the paper by Mr. Campbell, which was read by title at the Lake Superior meeting, but first presented at the New York meeting of the Iron and Steel Institute, October, 1904 (see p. 772). These papers are here published onder a mutual agreement between the Councils of the two Institutes, and will also be found in the Journal of the Iron and Steel Institute for the year 1901, vol. ii. Mr. William R. Webster, Philadelphia, Pa., said: We are under great obligation to Mr. Campbell for his exhaustive investigation, and the results he has put before us to-day. They are the most conlplete series of tests that have ever been made, where all the conditions of rolling, etc., were kept uniform. In discussing Mr. Campbell's first investigations, I claimed first, that the method of least squares, then used, would of necessity only gire the average value of any element, and that if the effect of any element was greater in the presence of high carbon than with low carbon this would not be shown by the method of least squares. Secondly, that the effect of manga nese should be considered on acid steel as well as on basic steel, instead of ignoring all the eff'ect of that element when it was below 0.60 per cent., as was then recommended by Mr. Campbell. I am pleased to note that the results of his present investigation confirm my views on these points. In presenting the results of his first investigation, Mr. Campbell referred to my investigation of 1893-94, and took exception to the value of phosphorus varying (depending on the amount of carbon present) from 800 to 1,500 lb. for each 0.01 per cent. He claimed that one might just as well consider the effect of phosphorus as being constant, and of carbon varying. I refer to this, as he now has introduced very similar conditions in his present tables, in that he gives variable values for manganese (depending on the amount of carbon present) for both acid and basic' steels. Can we now say, with more certainty than formerly, which element should be considered as haviup a constant effect ? There is one other point that I took up in my former discus-

Jan 1, 1905

By W. C. Schroeder, A. A. Berk

Practical experience has shown that at elevated temperatures solutions containing sodium hydroxide may attack stressed steel in a manner that cannot be explained in terms of ordinary corrosion. Because the ductility of the metal has been greatly reduced during the reaction, the entire phenomenon is usually called "embrittlement." Thus, after several years of operation caustic evaporators have been so badly embrittled that rivets could be cracked off with the blow of a hammer. Since fine intergranular cracks are almost always present in the zone of fracture, it has often been assumed that a process of selective corrosion in grain boundaries was responsible for the failure, although this has not been clearly proved experimentally. Concentrations of sodium hydroxide below those necessary for the uniform, rapid attack of the steel surface are reported to be most effective in producing embrittlement2, 3. In the operation of steam boilers a similar type of failure has been found, mainly in riveted seams or other capillary spaces where the solution may concentrate and where high stresses may also exist. It is believed that in such localized areas the dissolved solids may reach a value many times the few hundred parts per million prevalent in the body of the boiler. While this type of boiler failure has been the subject of investigation for a period of 20 years1, an understanding of its mechanism and a rational basis for complete protection have not yet been secured. To procure this information the present investigation was

Jan 1, 1936

By A. A. Berk, W. C. Schroeder

Practical experience has shown that at elevated temperatures solutions containing sodium hydroxide may attack stressed steel in a manner that cannot be explained in terms of ordinary corrosion. Because the ductility of the metal has been greatly reduced during the reaction, the entire phenomenon is usually called "embrittlement." Thus, after several years of operation caustic evaporators have been so badly embrittled that rivets could be cracked off with the blow of a hammer. Since fine intergranular cracks are almost always present in the zone of fracture, it has often been assumed that a process of selective corrosion in grain boundaries was responsible for the failure, although this has not been clearly proved experimentally. Concentrations of sodium hydroxide below those necessary for the uniform, rapid attack of the steel surface are reported to be most effective in producing embrittlement2, 3. In the operation of steam boilers a similar type of failure has been found, mainly in riveted seams or other capillary spaces where the solution may concentrate and where high stresses may also exist. It is believed that in such localized areas the dissolved solids may reach a value many times the few hundred parts per million prevalent in the body of the boiler. While this type of boiler failure has been the subject of investigation for a period of 20 years1, an understanding of its mechanism and a rational basis for complete protection have not yet been secured. To procure this information the present investigation was

Jan 1, 1936

By Thomas L. Watson

MY thanks are due to Mr. Frank Firmstone, Easton, Pa., who has called my attention to the statement in my papers that " Barite, fluorite and quartz, though not observed in the Tennessee area," . . . as possibly misleading to the reader, if construed to mean that such a discovery had never been made. Mr. Firmstone is correct in assuming that this statement referred only to the study of the worked areas of the metallic ores, especially zinc, made in the course of the survey upon which my paper was based. The occurrence of barite and fluorite with lead-ores in Tennessee was reported by Prof. Safford,2 in 1869, and by Safford and Killebrew,3 in 1887, with the further statement that about 1,000,000 lb. of barite were annually mined in Greene, Washington and Jefferson counties, Tenn., and that considerable deposits occur also in McMinn, Smith and other counties. It is also noted that the barite ".usually occurs in veins, associated with galena." The present worked areas of barite are, however, distinct barite propositions, without workable quantities of either lead or zinc, so far as mining operations have gone, and the areas are more or less removed from the present areas of zinc-ores. Mr. Firmstone informs me also that, in 1892, he observed, in the magnesian limestone at Watauga Point, in Carter county, on the left bank of the Watauga river, a little below the mouth of Buffalo creek, small quantities of galena and some fluorite.

Jan 1, 1907

By J. MURRAY RIDDLELL

AN increase of 18 per cent in the production and consumption of all metals last year was readily met by the mines, but more than an average amount of development work was made necessary. Mining methods were improved appreciably; open-pit operations ad¬vanced more than underground practice: and the transportation phase of mining progressed to a greater extent than the other related functions. A new belt-conveyor system of mining was placed in operation at the Spruce open-pit iron ore mine at Eveleth, Minn. The gathering portion of the belt system was installed beneath the surface of the open pit, following closely the bottom rock, in especially provided drifts; beyond it inclined upward to the surface and finally discharged into a 500-ton shipping pocket. Length of the belt was 4500 ft. net vertical lift 386 ft. and capacity 750 long tons per hour. The mined ore found its way to the belt through one of three vertical raises, whose horizontal section was 10 by 10 ft. Each raise was equipped with a grizzly, crusher, pan-type feeder, and auxiliary equipment. Transportation of the ore from the working faces of the pit was accomplished as follows: (1) Two raises were equipped with tower and anchor stations, 3-cu.yd. drag scrapers, and related power units; (2) the remaining raise was provided with electrically driven power shovels and 20-ton trucks mounted on pneumatic tires. This installation has entirely replaced railway pit haulage and partly eliminated power shovels. In a similar

Jan 1, 1938

By R. A. Deju, R. B. Bhappu

The theory of electrophoresis is briefly outlined and an apparatus which may be used for electrophoretic studies is explained. The results obtained using this apparatus are in agreement with those obtained by other investigators. How to solve some of the complications which occur in the measurement of zero charge and zeta potential is explained. It is believed that the apparatus described in this paper will allow rapid measurements of zeta potential, zero point of charge, electrophoretic mobility and zeta coefficient. For many years the phenomenon of electrophoresis has been studied, and much work has been done in designing an apparatus for better measurements of mobility, zeta potential and zero charge of minerals. Up to the present, most electrophoresis experiments have involved cumbersome equipment and tedious microscopic observation. The modified cell proposed in this paper obviates these drawbacks by using a Rayoscope together with a special system of lenses and filters. It therefore allows a faster and more accurate measurement of zero charge and particle velocity. THEORY Most authors currently regard zeta potential as the potential difference in an otherwise uniform medium between a point some large distance from the surface of the mineral and a point on the plane of shear. Fuerstenau,1 Miaw,2 and Gaudin and sun3 have performed some calculations of zeta potential using Henry's equation.4 Their results show wide discrepancies, probably due to differences in the past histories of the minerals used. The authors have also noticed this difference on determining the zero point of charge of quartz as shown on Table I.

Jan 1, 1967

By J. A. Richardson

J. A. RICHARDSON[t]-Mr. Stuckey's account of the geology of the kaolins of North Carolina suggests that they exhibit some features similar to those of the Malay Peninsula. About one half of British Malaya (some 26,000 square miles) is occupied at the surface by igneous rocks, of which granite and its associated derivatives constitute fully 90 pct. The average granite is a biotic variety. It is predominantly potassic but carries, in addition, notable amounts of soda and lime so that albite and albiteoligoclase are generally common constituents of the rock. The minor derivatives from granite "magma" likewise include potassic and sodi-potassic members. Decomposition of the granitic rocks has led to the formation of kaolin in many localities, but, in general, the deposits are rather small and, at present, none is exploited commercially. True primary or residual kaolins (as defined by Stuckey; p. 48 Vol. 173, p. 2 TP 2219) have been developed from feldspar veins, pegmatites and from other granitic differentiates which cut through the larger masses of granite; they are usually small and narrow. Kaolin has been derived from aplite, quartz porphyry, quartz micro-porphyry, felsites and microgranites belonging to a complex known as the Chegar Perah-Pulai intrusion in northwest Pahang and southwest Kelantan. The bulk of the component rocks has been more or less strongly sheared. Kaolin-like end products have been formed from both sheared and nonsheared varieties. Kaolin has been formed also by the complete breakdown of trondjemite flanking the northwestern and western margins of the complex Bukit Ranjut syenite intrusion in northwest Pahang. These trondjemites range in composition from essentially quartz-free albiteplagioclasites to quartz-free microcline rocks; they are, in effect, the syenitic homologues of white sodic and potassic granite-aplites. The granites in Malaya have generally undergone more or less severe surficial weathering leading to the production of a spongy and rather cellular or a soft "mealy" material (sandy clay) down to depths of about 100 ft; in places the granite is strongly decomposed down to 150 ft. There has occurred, therefore, widespread partial kaolinization, but, in general, no extensive deposits of good quality kaolin seem to have been formed by these processes of decay. Frequently, the katamorphic processes of desilicification have advanced beyond the production of kaolin towards the formation of lateritic end products. The more important Malayan kaoiins seem to be confined to the western alluvial plains, particularly in areas either where granite crops out at surface, or where it forms the bedrock of the alluvium. There are numerous excellent examples around Gopeng and elsewhere in the Kinta Valley of Perak. Such kaolins belong to Stuckey's groups of secondary deposits, and, like them, these also may be bedded. Field observations have established the existence of what for want of a better name is referred to by the Malayan Geological Survey as "granite wash." It is believed that granite, undergoing extensive deeply penetrative and probably rather rapid destruction under humid tropical weathering (temperature around 90°F; rainfall about 100 in. per annum; high humidity) "flowed," was moved by "creep" and, in addition, probably slumped in large waterlogged masses of sandy clay from topographic salients onto the adjacent flats. Either during this period of transmigration or later when the sludged granite detritus, after having more or less come to rest, was attacked by flowing water, differential sorting and erosion took place with the result that the resorted debris was moved and later deposited as bedded alluvium. In this way, banded "granite wash" was produced comprising alternating bands of clayey sand (resorted granite sludge) and white

Jan 1, 1947

By R. P. Smith, L. S. Darken

FOR a high-purity iron-carbon alloy, the phases existing at equilibrium at temperatures slightly above the temperature of the metastable eutectoid are austenite and cementite (hyper-eutectoid) or austenite and ferrite (hypo-eutectoid) and those below the eutectoid temperature (carbdn content > 0.02 pct) are ferrite and cementite. Such an alloy, held in a carefully controlled and measured temperature gradient (about 1 cm per deg) which includes the eutectoid temperature, then quenched and examined metallographicall.y, provides a precise measure of the eutectoid temperature. The samples were hollow cylinders approximately 1.3 cm OD, 0.63 cm ID, and 2.5 cm long, which had been carburized to the desired carbon content at 1000°C with an appropriate hydrogen-methane mixture. In order to cool the samples to room temperature with a minimum change of carbon content and absence of cracks they were quenched in a Cerro Bend bath at 480°C, followed by a water quench to room temperature. Three cylinders were suspended in the furnace1 in a purified helium atmosphere, by a closed end, thin wall, silica tube which also served as a thermocouple well. The top and bottom cylinders served only as a means of making the temperature gradient along the center cylinder more uniform. The temperature was determined with a platinum-platinrhodium thermel calibrated by comparison with a thermel certified (* 0.5OC) by the National Bureau of Standards. After holding in the temperature gradient for 24 to 72 hr the samples were quenched in Cerro Bend at 480°C, followed by

Jan 1, 1960