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By T. Egleston

For several years 1 have been engaged in studying the behavior of iron and steel under varying conditions of tension and compression, as well as of shock and abrasion. Some of these observations have been communicated to the Institute at various times. Within the past year I have been looking at the various observations that I have made as a whole, and have been led to the conclusion that there is a regular law of fatigue and refreshment of metals, and that the change which produces either the fatigue or refreshment, is a. chemical one, which is, however, in almost all cases accompanied by physical and molecular changes at the same time. That metals under conditions that were more or less well understood became worthless, has been known for many years. It has been known to blacksmiths that iron and steel, when improperly treated in their fires, become "burned," as they call it, and could no longer be used, and some of them have had a scrap heap into which such material was thrown. A few of them knew that after a period more or less long the iron or steel recovered some of its original properties and could, with many precautions, again be used, but that these phenomena followed any law has not to my knowledge been announced. My attention was first attracted to the varying conditions under which iron and steel rails break in service. It was not long before I became convinced that there was a general law applicable to all metals which allowed of their being used with safety within certain limits, and caused their rupture when the use extended beyond these limits, and this law I have called the law of fatigue- of metals. When me observe the causes of deterioration in iron and steel rails, we find that they are principally shocks, either slight and frequent, like those produced by the passing of a train over a road-bed in good order, which produces a vibration sensible to the ear laid on the rail, for very long distances, but distinctly audible for only a short one; or from sudden and heavy blows, like the descent of the locomotive and each car successively from a high to a low rail.

Jan 1, 1880

By Clarence R. King

Diamond drilling of Cove Creek deposits and development of flotation-refining process may lead to commercial operation of property worked sporadically for almost a hundred years.

Jan 4, 1953

By Robert Lewis

Some recent experiments in the use of compressed air for rock drills at higher than usual pressures, up to 150 lb. per sq. in., emphasize the importance of maintaining the compressed-air system in the best condition if the greatest possible over-all efficiency is to be secured. No claim of high over-all efficiency can be made for the compressed-air system of braking that is used on railroad trains, yet the air brake works effectively. Compressed air is not used efficiently in the rock drill, but no other type of machine drilling is yet a serious competitor of the air-driven rock drill.

Jan 1, 1930

AS I told you in the chapter on salts, saltpeter is a mixture composed of many substances extracted with fire- and water from arid and manurial soils, from that growth which exudes from new walls or from that loosened soil that is found in tombs or uninhabited caves where the rain cannot enter. It is my belief that it is engendered in these soils from an airy moisture that is drunk in and absorbed by the earthy dryness. Considering its effects, I do not know how to decide and say exactly what the nature of saltpeter is. The learned and very wise physicians find it salty and with a subtle sharpness both in taste and in their medical experiments. Considering its strong biting qualities, they decide to say that it is of a hot and dry nature; on the other hand when they see that it is engendered from the air and that when touched by fire it becomes inflammable and vaporous, and rises with a fearful impetus when mixed in powder for military guns, it manifestly shows itself to be of a hot and moist airy nature. And then when they see that it is shining and transparent with whiteness and is fusible in every fire in a manner corresponding to a thing of a watery nature, and since it. is heavy, it seems that it can be said to be watery in nature. To this is added the experience of touch and of the great cooling action which it has on water in summertime when wine is to be cooled, and since it crushes and breaks with but little pressure, it might be thought to be earthy in nature; especially when it is seen to change into a hard, white stone when burned with an equal amount of sulphur. Thus it seems that every one of the elemental qualities is predominant in it. Now the ancients called this, or a similar thing, nitrum. [150] Pliny, in Book XXXI of his Natural History, has said that it was a thing not much different from salt, that doctors do not seem to have yet known its nature, that it is found in various places, and that the best is found in Macedonia. But among the moderns and especially in our regions, it is not known today what it is that Pliny and other writers refer -to, since according to the aforesaid Pliny and other ancient writers it is a natural mineral. Some say that in place of, the natural kind the artificial will serve for the same medicinal purposes, since it has the same nature and is perhaps more powerful.

Jan 1, 1942

By Takahide Wakamatsu, Shigeru Mukai

Fundamental investigations were made on the treatment of slime and the chrysocolla flotation, both of which are urgent problems to be solved in copper oxide mineral flotation. Unfavourable effects of slime on flotation are caused by the slime adsorption at the air/liquid Interface as well as the slime coating on the mineral surface. The adsorption of slime at the air/liquid interface was measured by using various kinds of slime particles. As a consequence, goethite, bentonite and talc tended to adsorb markedly at the interface. As a desliming method, slime flotation with a polymer flocculant such as polyethylene-oxide prior to the ordinary copper oxide flotation was found to be effective. The use of both a copper-avid organic reagent and an alkyl xanthate was examined for a selective collection of chrysocolla through xanthate adsorption tests, chrysocolla float- abllity tests and flotation tests for synthetic and natural ore. The copper-avid reagents used were salicylaldoxime, 8- hydroxyquinollne and benzoin-a-oxime. As a result, the ad- sorption of higher xanthate such as amyl xanthate on chrysocolla as well as the chrysocolla-to-air bubble attachment was increased by the presence of a copper-avid reagent under suitable reagent addition and pH of pulp. Flotation tests for synthetic and natural ores confirmed that chrysocolla could be floated sufficiently and selectively with a copper- avid reagent like 8-hydroxyquinoline or salicylaldoxime with its subsequent collection by amyl xanthate.

Jan 1, 1976

By Read Winterburn

This discussion covers only one method of pressure drilling—that developed in the Kettleman Hills field. Thus it is probable that many departures from the procedure herein described would be advisable, and perhaps necessary, in using this method of drilling wells in other localities. Purpose of Pressure Drilling By the early part of 1936, formation pressures in the heavily produced north end of the Kettleman North Dome field had declined to range from 1000 to 1500 lb. per sq. in. This low pressure, combined with the depth of the wells (8000 to 9000 ft.) permitted water to be filtered out of the mud into the producing sands during drilling operations. The loss of water was indicated by loss of fluid from the suction tank while drilling, accompanied by an increase in mud weight. It was found that when water was added to the mud stream at such a rate as to keep the fluid level in the suction tank constant, the mud weight would not vary. This indicates that water only was forced into the sands. The rate of this loss at various wells ranged from 2 to 5 bbl. per hour. At some places complete loss of circulation occurred, and drilling mud to the extent of 200 to 1000 bbl. had to be pumped into the sands before returns were regained. It was believed that these conditions had already begun to harmfully affect production, and that such effect would become more pronounced as formation pressures continued to decline. Pressure drilling with oil was introduced because it eliminated the danger of loading the formations with mud and water. The method also afforded a convenient means of testing as drilling progressed, lessening the amount of formation testing, which had become necessary because of encroaching edge water.

Jan 1, 1938

By Franc R. Joubin, D. H. James

Uranium exploration in the North Shore area of Lake Huron goes back to 1847 when J. L. LeConte, a distinguished American geologist, identified a pitchblende-like mineral which he called coracite from specimens sent from a locality north of Sault Ste. Marie. In 1948 a search for the LeConte occurrence resulted in discovery of the Camray field, some 70 miles north of Sault Ste. Marie. Prospecting the Camray field yielded about 30 pitchblende occurrences spread over approximately 200 sq miles. Almost without exception these discoveries consisted of narrow, short, pitchblende-filled fractures, within or along the contacts of diabase dykes cutting pre-Cambrian Archean granite and gneiss. Eight discoveries were diamond drilled and three were explored underground, but none proved to be of economic value. Uranium prospecting at this time spread far afield, and it was in 1949 that radioactive conglomerate was discovered in Long Township of the Algoma district midway between and 90 miles from Sault Ste. Marie and Sudbury. F. Joubin examined this discovery at that time but could not interest capital in its development.

Jun 1, 1956

By Samuel M. Cassidy

The exact date of man's first use of coal is lost in antiquity. The discovery that certain black rock would burn was undoubtedly accidental and probably occurred independently and many times in the world over thousands of years. It is quite likely that these independent discoveries were made when primitive man chanced to build camp fires on exposed ledges of a black rock, then was amazed when it caught fire. The Chinese recorded the use of coal 1100 yearn before the Christian Era and from the Bible we learn that King Solomon was familiar with coal in what is now Syria. In Wales, there is evidence that the Bronze Age people used coal for funeral pyres, and it is known that the Romans used this fuel. There are other ancient references. So the knowledge that coal would burn, and even some uses of that knowledge, go back thousands of years. However, practical and consistent use of coal seems to date to England in the Middle Ages. COAL IN AMERICA In the Americas, there is evidence here and there of occasional use by the Indians. However, the first recorded discovery of coal, in what is now the US, was by French explorers, who reported an outcrop exposure on the Illinois River in 1679. Following this, other discoveries were made by French and British explorers, but the first recorded actual usage was in Virginia in 1702, where a French settler was granted permission to use coal for his forge. Earliest recorded commercial mining was in 1750, from the James River coaEeld near Richmond, VA, a deposit now abandoned. Besides local consumption from this field, shipments were made to Philadelphia, New Pork, and Boston. During the Revolution this coal was of impor- tance in the manufacture of shot and shell; so important, in fact, that the British sent an expedition in 1781 to destroy the iron works and

Jan 1, 1981

By Henry Howe

THE brilliant and very original matter in Professor Jeffries' discussion ? should rank not only as an independent paper, but as a most important one. In particular, the explanation which it gives of the remarkable Sauveur phenomenon, over which so many of us have puzzled long and hard, is so clear, complete, and cogent as to go far toward establishing Professor Jeffries' hypothesis. The very features of Professor Sauveur's photographs which fit this hypothesis so exactly are reproduced in Chappell's photographs of steel coarsened under somewhat different conditions. 1 The ideas developed by these discoveries are so novel that conven- ience of language seems to call for new conventional terms for expressing them. In, what follows here I propose certain terms for this end, for criticism and improvement, and I attempt to generalize from Professor Jeffries' hypotheses. Generally speaking, a given set of grains which undergo no growth in the cold will, when the temperature is raised progressively, start to grow on reaching a certain temperature, and will continue growing at all higher temperatures. The "germinative" temperature is that at which growth begins, quite as the conditions which cause a seed to grow are "germinative." We have then. an inert temperature range below the germinative temperature, and a growth range above it, the germinative temperature being the limit between these two ranges. So, too, a germinant grain is one which is at its germinative temperature, and hence beginning to grow, while inert grains are those below their own germinative temperature, and the term "growing grains" includes those which are germinant and those which are above their germinative temperature. These last could be called "supergerminant" if the distinction should be needed.

Jan 12, 1916

By ZJ. H. Brophy, A. L. Prill, H. W. Hayden

The effect of Group VIII transition-element additions on the sintering of tungsten powders is shown to be dependent on the phase relationships of the particular tungsten-Group VIII metal alloy system. The acceleration of sintering with nickel additions is diminished by alloying nickel with copper which is known to diminish both the tungsten solubility in nickel and the solid-vapor surface energy. In work previously published on the effects of additions of Ni, Pd, Pt, Rh, Ru, and Ir, which form solid solutions or intermediate phases of wide composition width with tungsten, sintering behavior is independent of element concentration beyond that concentration necessary to form a continuous layer on the surface of the tungsten powders employed. The sintering behavior of tungsten with additions of iron or cobalt, which form intermetallic compounds with tungsten, is highly dependent on addition-element concentration. Additions in excess of amounts necessary to form continuous layers lead to successively decreased sintering rates. The effects of certain Group VIII transition metals on the sintering rates of tungsten at temperatures below those at which a liquid phase would be predicted have recently been investigated by the present authors1-4 It was found that small additions of palladium, nickel, rhodium, platinum, and ruthenium accelerate the rate of tungsten sintering. Additions of iridium decelerated the rate of densification compared to that of pure tungsten in the same temperature range. In all cases the rate of densification changed with increasing amounts of these additions, up to those compositions at which a continuous layer was formed on the surfaces of the tungsten-powder particles. The rate of densification was then independent of further increases of the compositions of any of these addition elements. These observations were consistent with a sintering model in which the addition element formed an interface with tungsten in which tungsten dif-fusivity was either greater or less than its grain boundary self-diffusivity. Kinetic analysis of this model indicated that linear shrinkage should vary according to the relation:

Jan 1, 1964

By Carl R. Christiansen, James J. Scott

Advance mine planning, coupled with good mining practice, can be employed to develop underground space in stone mines for future industrial usage. To assure the developer the maximum return on his investment, initial planning should consider all aspects of the commercial operation, including surface layout, mining, and underground industrialization. The modular concept of mining to compartmentalize the space offers several advantages over conventional methods. Some expenditures can be considered as mining costs with a reduction of profit from stone production while lowering the capital requirements for conversion for usable space.

Jan 1, 1977

By L. A. Rapport, J. R. McCord, W. P. Drews, K. H. Coats

Water movement about an oil or gas reservoir can be predicted provided an aquifer influence function is known. This function is generally determined from an electric analyzer study or by fitting an idealized mathematical model to field data. A prohlem arises in determining that influence function which best reproduces field data and satisfies certain smoothness requirements, without making any idealizations concerning aquifer geometry and heterogeneity. This study shows the problem to be solvable through the linear programming technique and presents applications to one oil reservoir and two gas storage reservoirs. In addition, a theorem is stated and proven which confirms influence junction smoothness requirements heretofore accepted on physical intuition and establishes additiotzal smoothness constraints formerly not recognized. INTRODUCTION The pressure decline accompanying production results in water encroachment into oil and gas reservoirs situated adjacent to aquifers. The importance of this water movement derives from the significant dependence of production rate upon reservoir pressure and of pressure, in turn, upon water encroachment. Pressure and rate of water movement are uniquely related through an "influence" function which may be in the form of reservoir pressure response to a unit water encroachment rate or of water movement caused by a unit reservoir pressure drop. This influence function reflects the heterogeneity and geometry of the aquifer and is therefore particular to each reservoir. If the influence function is known, then reservoir pressure may be predicted from a production rate schedule, or vice-versa, with the aid of the material balance equation which relates water influx to reservoir production and pressure. The problem of determining this influence function for a given reservoir has been approached in three different ways. Van Everdingen and Hurst calculated and tabulated certain influence functions pertinent to idealized mathematical models which satisfy simplifying assumptions such as aquifer homogeneity and elementary reservoir-aquifer geometries.' Other studies developed additional tables for a variety of elementary reservoir-aquifer geometrical con- figurations and demonstrated their validity and utility.:' Hicks, et al. described the use of an electrical network to determine an influence function giving "best" match of field history and allowing prediction of future performance.' Finally, Hutchinson and Sikora5 and Katz, Tek and Jones attempted to develop a calculation method for deriving the influence function directly from field data with no idealizing assumptions concerning aquifer geometry and homogeneity. They encountered difficulties with inaccuracies in field data and with satisfaction of well-known smoothness requirements of the influence function. This study is concerned with the determination of influence functions from field data and, more specifically, treats the following problem: given field pressure-production data of arbitrary accuracy, how does one determine the influence function which, subject to satisfaction of known smoothness requirements, gives best agreement with field history? A rigorous solution to this problem is ohtained through linear programming as described below. Example applications to one oil and two gas storage reservoirs are presented. In addition, a theorem is proved which confirms influence function smoothness requirements heretofore accepted on physical intuition and establishes additional smoothness requirements formerly not recognized.

Jan 1, 1965

By H. C. Brown

SINCE 1934 the steel industry has been utilizing the spectrograph for supplementing wet chemical analysis in the production control of electric and open hearth furnaces. This means of control made great strides during the war years because of the general acceptance of the spectrograph and the increased emphasis that was placed on rapid control methods. However, in the post war era, with the demand still on increased production, it became apparent that a still more rapid and economical means of production control was needed. Since the spectrograph had been used mostly in the analysis of low alloying and residual elements, it also became apparent that equipment was needed to extend the spectrographic technique to the analysis of the high alloying elements in stainless steel. For these reasons, companies manufacturing spectrographic equipment were prompted to start development work on direct reading instruments. In June 1949, the Applied Research Laboratories of Glendale, Calif., announced that a direct method of spectrochemical analysis for stainless type steels had been developed. This paper will describe the use of the Applied Research Laboratories Production Control Quantometer in the quantitative control of stainless, silicon, and plain carbon steels being made at the Butler Pennsylvania Div. of the Armco Steel Corp. The Armco Butler Div. has one 70-ton electric furnace and six 150-ton open hearth furnaces. The electric furnace is employed in the making of all types of stainless steel and the open hearth furnaces are used for the production of silicon, wheel, and plain carbon steels. The ARL quantometer was purchased primarily for the purpose of controlling the steelmaking in the electric furnace, but its use has been extended for the analysis of final tests (ladle tests) on a number of different types of stainless, silicon, and plain carbon steels. Because of this additional work by the quantometer, substantial savings in manpower and time have been realized by the laboratory. In the analysis of a set of preliminary tests from the stainless steel furnace, approximately 40 min in laboratory time are saved due to quantometric analyses. Despite the fact that more specialty grades of stainless steel are being made in the electric furnace, the average tons per hour have been increased since the quantometer was put into operation. Specialty grades require more furnace time than regular commodity grades of stainless steel. The installation of the ARL production control quantometer was completed on March 13, 1952. By May 1, 1952, the instrument was calibrated for nickel, chromium, manganese, silicon, and molybdenum, which are the elements necessary for the production control of the stainless steel furnace. Within the following month, training of personnel on the quantometer was achieved and a study of the accuracy of the instrument showed that the results obtained were sufficiently accurate for control purposes. Therefore, on June 11, 1952, the quantometer was placed on production control for all types of stainless steels. Starting September 11, 1952, the instrument was gradually placed on ladle analysis (final tests) as the analytical curves were refined and additional curves were drawn. The quantometer has been relatively free of breakdowns since placing it on production control. The samples from only one stainless steel heat have had to be analyzed by wet chemistry because of instrument trouble. The previously existing heat-time record was also bettered by 15 min on a commodity grade of 18-8 stainless steel. Scope of Control In general, the quantometer determines all elements necessary for the production control of all types of stainless steel heats and for the ladle analysis of various types of stainless steel heats. It is also used in reporting final results for silicon, manganese, chromium, nickel, molybdenum, tin, copper, and aluminum on all silicon steel grades and manganese, chromium, nickel, molybdenum, tin, and copper on several plain carbon steel grades. Table I shows the elements and the concentration ranges of these elements in the various types of stainless, silicon, and plain carbon steel that are determined on the quantometer. A study of the results obtained on ladle test samples of stainless steel types 410, 430, 430 Ti, 446, 301, 302, 304, 304L, 305, and 17-7 PH will be discussed. Also included in the study are the results obtained on ladle test samples of a number of silicon steels. Apparatus In order to take full advantage of the potentials of the production control quantometer, the unit has been placed in an air-conditioned room with relative humidity control. The temperature is maintained at 73'22°F and the humidity at 45&5 pct. The air conditioning serves as a precaution to minimize the amount of adjustment and calibration needed during operation. It also reduces contaminating fumes and dust and thereby lessens the necessity for maintenance on the equipment. The quantometer is composed of three units: the high precision multisource unit, the 1.5 meter vertical spectrometer, and the console. The source unit supplies excitation conditions varying from spark-like discharges to arc-like discharges. The voltage to the source unit is supplied by a motor-generator

Jan 1, 1955

By Bayard Morrow

THE copper-bearing ores concentrated at the Anaconda plant of the Anaconda Copper Mining Co. are principally a mixture of copper and iron sulfides associated in a gangue consisting of quartz, lightly altered granite and feldspars, with sphalerite and galena and more rarely barite and hubnerite as accessory minerals. The predominant sulfide is pyrite. The copper minerals present are: chalcocite, bornite (Erubescite), enargite, chalcopyrite, covellite, tetrahedrite and some tennantite. Normal concentrator practice removes a slime prior to ball-mill grinding. The deslimed ore is ground to approximately 10 per cent plus 65 mesh for flotation. Two selective flotation circuits are used, one for deslimed ore and one for slime. The metallurgical results obtained are shown in Table 1.

Jan 1, 1933

By George A. Roberts, Arthur H. Grobe

H. H. Hausner (Sylvania Electric Products Inc., Bayside, N. Y.)—I tested the 18-8 stainless steel powder described by Grobe and Roberts and the results were excellent. The powder was compacted and sintered in purified hydrogen to a very low density (approximately 20 pct and more porosity). Where the other powders show very little ductility when sintered to such a low density, the described stainless steel was surprisingly high in ductility. I would appreciate it if the authors could give us some data on a similar powder but without silicon and also data on 430 stainless steel powder. H. S. Kalish (Sylvania Electric Products lnc., Bay-side, N. Y.)—I should like to verify the excellent results obtained by Grobe and Roberts with their pre-alloyed stainless steel powder. It seems to me, however, that their data are conservative and that even better densities and higher tensile strength can be obtained with these powders by the selection of proper particle size fractions. The accompanying data were obtained by sintering compacts pressed from the powder made by Vanadium-Alloys Steel Co. to 0.8 in. in diam about % in. high in a cylindrical double action die without the use of lubricant. The compacts were sintered for 1 hr at 2370°F in hydrogen purified by passing it through a Deoxo unit (palladium catalyst) and a Lectrodryer. Even the density obtained using the as-received (—100 mesh) compacted at 40 tsi was quite high as was the hardness. This indicates that by increasing the sintering temperature slightly above 2350°F the coining and subsequent secondary sintering operation can be avoided. With the — 325 mesh fraction, however, very much higher density can be obtained and a high hardness. I have no tensile data to present, but I feel that it is not too optimistic to expect. that unusually high tensile strengths and good ductility can be obtained in this sintered material on the basis of the density and hardness data. The sintered stainless steel made by the above-described methods came out of the furnace very bright and clean. The purified hydrogen atmosphere is important in sintering stainless steel to reduce the oxide present in the powder. The result of such a sintering is good densification and good ductility of the sintered product. G. A. Roberts (authors' reply)—We are greatly indebted to Messrs. Hausner and Kalish for their discussions of our paper. Their encouraging remarks are greatly appreciated and their confirmatory data will do much to add to the value of the paper. At the present time it is impossible to provide complete data on a similar stainless steel powder without silicon, but we do know that, in general, the properties are slightly inferior. Data on such a powder and on other stainless steel types are to be published in the near future.

Jan 1, 1952

By John Tyssowski

IN 1925, Harry Howard Stout, then metallurgist for Phelps Dodge Corporation, while investigating the cleaning of cathode copper by various gases at elevated temper-atures below the melting point of the metal, observed in the laboratory that particles of pure copper heated in a closed tube filled with hydrogen seemingly "stuck together." By further investigation he found that there was actual crystal growth across the boundaries of the particles of pure metal; in other words, there was a complete new crystal realignment and growth throughout the newly formed copper mass. It was coalescence, not adhesion; the several parti-cles had become one unit. From this dis-covery has been developed the coalescence process, whereby copper of cathode purity is squirted out in semifabricated form from an extrusion press, by the appli-cation of about 3000 tons pressure on a 10-in. piston. Stout decided that cathode copper pro-duced by electrolytic deposition was the logical source of the pure copper required for the coalescence process, but as there was no way of reducing the ordinary tough commercial cathodes to the small particles required he was confronted by a serious problem at the outset. Under his direction, this problem was solved by William H. Osborn and Harry Howard Stout, Jr. They developed the process and technique for producing cathode copper in brittle, friable

Jan 1, 1940

By E. V. Foran

AMONG the many newer disclosures that have accompanied the petroleum industry's progressively deeper exploratory drilling is the increased frequency with which the operators are encountering reservoirs of which the products at the time of discovery exist wholly or predomi-nantly in the gas phase. The popular term "distillate pool" is most often used within the industry when referring to this type of reservoir, and in this paper the term is used in that sense. These pools have been observed in many different surroundings. In some places the entire reservoir is filled with the wet gas containing its water-white condensible products in the gas phase but apparently with no dark oil or other hydrocarbon liquids in the reservoir. The 8200-ft. horizon in the Big Lake field in West Texas is a good example of this type. At other places the wet, or distillate-bearing, gas may form a large gas cap directly overlying and in contact with an extensive reserve of dark oil. Oklahoma City, Kettleman Hills, the 8500-ft. horizon in the Big Lake field, and many others are examples of this type. There are also many places in which the wet distillate-bearing gas fills nearly the entire reservoir space, while the dark oil occupies only a narrow, bandlike zone, which marks the boundary of the reservoir along its lowest productive contour. The heavier components of these deep pool gases are generally water white in color, a large portion of which are condensible in a conventional oil and gas separator, when operated under pressures of the order of 400 to 800 lb. per sq. in. Although the water-white products recovered in the separator sometimes have end points of 650° F. and higher on standard Engler distillation, they occur only in the gas phase in the reservoir. It is entirely possible that even some small amounts of dark colored reservoir components may occur in the gas phase when the temperature is 300° F. and pressures exceed 6000 lb. per sq. in. Close approaches to these conditions have been encountered in the deepest producing wells. The condensible content of the deep reservoir gases of the many pools that have been tested or produced to date shows a wide variation in both condensible content, per 1000 cu. ft. of gas, and physical character.

Jan 1, 1939

By J. J. Kramer, W. A. Tiller, G. F. Bolling

THE axial orientations of columnar crystals in unidirectionally solidified ingots of zone-refined zinc and tin have been examined using the techniques recently described by us.' Both metals had an initial purity of 99.999+ pct before zone refining and satisfied all qualitative guides for very high purity after zone refining. Fig. 1 presents the orientations of the columnar crystals for tin and zinc, respectively. For tin, there is a preference for grains growing in the [I101 direction, i.e., the dendrite direction.' For zinc, a weak preference for the [0001] direction is seen (a random population in the unit triangle would give equal density on either side of the 60-deg circle centered on [0001]).' There was no apparent evidence for dendritic growth in either metal. These results, and those previously reported,' confirm the recent investigation by Hellawell and Herbert of casting textures observed for zone-refined lead, zinc, and tin.4 The preferred casting orientations for these metals in both the impure and zone-refined states are given in Table I. In the experiments on zone-refined lead,' it was shown that two separate textures existed: a preferred (111) nucleation texture existed at the chill surface and a preferred (111) texture developed during solidification. Either effect is sufficient to produce the result recorded in Table I. Similarly the results recorded for tin and zinc may be attributable to either a preferred nucleation or a preferred growth phenomenon and additional experiments are required to separate these two possible explanations. Hellawell and Herbert' attribute their results to a preferred growth process and account for it on the basis of a "layer-growth" model proposed much earlier by one of the present authors.5 An equally satisfactory growth model would be that based upon anisotropic surface energies. However, both of these growth models would indicate that the preferred growth direction for very pure metals should be normal to the plane of closest packing in the metal. This is consistent for zinc but, contrary to the conclusion of Hellawell and Herbert, it is not consistent for tin since here the (100) is expected to exhibit a greater density of packing than the (110). Although tin is expected to exhibit an anisotropy of thermal conductivity, we would expect the thermal conductivity to be the same in the [1101 as the [l00]

Jan 1, 1963

By E. Nelson Fell

As this plant is the first ever erected in British Columbia for the treatment of tailings by the cyanide process, and as the ores of this, mine are of a character not unusual among gold-ores of this Province, it is probable that a description of the principal features of the plant, and of the methods employcd in its operation, may be interesting. These works were designed after a careful study of the process, in a small experimental plant, for a period of six months. During this period ten percolation-tests on charges of tailings of 1100 lbs. each, eight percolation-tests on similar charges of concentrates, and twenty-six tests 011 concentrates in a revolving barrel, were made, besides laboratory-experiments. The ore consists of a quartz gangue, containing a little lime and variable quantities of the sulphidcs of iron, lead and zinc. The following figures, giving the analyses of the ore before milling, and of the tailings after milling, which constituted the material to be cyanided, are based on the daily samples taken during February and March, 1901.

Jan 1, 1902

Jan 1, 1942