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By J M. Menacho, L Zhang, A Hoadley, L Verdugo, B Etschmann, W Bruckard

Since the introduction of Lithium-Ion Batteries (LIBs) in 1991, the market for lithium-ion cells has been driven by the high demand for portable electronic devices and more recently for batteries for the electric car industry. It is expected to grow rapidly to reach 2600 GWh globally by 2030 (US Government, Office of Energy Efficiency and Renewable Energy, 2021). However, there is a desperate need to recycle LIBs to recover valuable cathode materials and graphite. For this reason, several physical and chemical recycling technologies have been proposed to recover these materials from spent batteries. Amongst these, froth flotation technology is a potential cost-effective technology for separation of the graphite fraction from the lithium oxide components due to the natural hydrophobicity of graphite and density difference between graphite and cathode materials (Folayan et al, 2021).

Aug 24, 2022

There are two mechanisms in the flo- tation process by which particles are transported from the pulp to the con- centrate: bubble-mineral aggregation and entrainment. It is the chemical processes which occur in the pulp which are critical to the success of flotation since they control the floatability of different min- erals and the selectivity which can be obtained. However, these chemical pro- cesses are so complex that metallurgists are still limited in their ability to predict the floatability of particles in industrial circuits by consideration of the minerals present and the chemical environment. The alternative approach to understand- ing flotation is to examine the behaviour of minerals in industrial flotation pro- cesses, to recognise similarities and differences, and to define the "laws" which appear to apply. Using this ap- proach it has been found that minerals float at a rate which is proportional to their concentration in the pulp, and that the rate of flotation of different min- erals is influenced by variables which' affect the pulp or the froth phase. The ultimate application of this approach is the use of models for circuit simulation purposes. It is this alternative approach which is the theme of this paper. One of the most important problems in understanding the technology of flotation has been in defining the characteristics of the particles being floated. Particles entering flotation vary widely in size and mineral composition, and different par- ticle types float at different rates. These rates do not change uniformly as operating variables change. It has been conventional practice to assess flotation performance in terms of the metal contents of total streams because no better method has been available, and this procedure has obscured important effects which occur in

Jan 1, 1984

By Whiten WJ, Narayanan S

Data from ball mills of a wide range of sizes are analysed using detailed mathematical models and non-linear least squares fitting techniques. This analysis reveals that the relative power inefficiency of large ball mills is due to inefficient grinding of coarse (plus 4 mm) particles in these mills. A qualitative physical hypothesis is proposed to explain this behaviour. The results of the analysis can be used to scale up ball mill behaviour, using the mathematical models and techniques developed. A simpler ball mill scale-up procedure is also proposed, and its limitations stated. Laboratory experiments are being conducted to determine the average size distributions of single particles of different ores after breaKage. These experiments can distinguish between the different ores, and it is hoped to use their results to model and predict the grinding of different ores in ball Mills.

Jan 1, 1978

By G Bournival, Y Pan, S Ata

A custom-made set-up that measures bubble coalescence time and the thin film balance (TFB) technique were used to explore the role of residual xanthate (potassium amyl xanthate, PAX) and salt (NaCl) on the adsorption of two frothers (methyl isobutyl carbinol-MIBC, and di-propylene glycolDPG) at the air-water interface. This paper is primarily focused on the comparison of these two techniques in studying the interaction between the flotation reagents and salt emphasizing their capabilities and limits. The results from the coalescence rig showed that the presence of PAX improved the stability of bubbles in both frother solutions and led to a bubble coalescence inhibition at 50–500 ppm DPG. These measures were compared with the results from the TFB. Findings from the TFB were overall in good agreement with the bubble coalescence time, but a higher stability level was observed in thin films under the same condition. The effect of salt on the frother and PAX mixture was also explored, and the results showed an adverse impact of the salt on the interaction of frother and PAX with both techniques. However, variations were found between them in some cases. The TFB is much more sensitive to the presence of dissolved gas and oil droplets.

Aug 24, 2022

By Chapman G. J

Mining operations require detailed and precise methods and procedures for the optimum selection of ore from waste. A fundamental procedure applied to achieve this selection is accurate sampling. The key parameter to accurate sampling is an understanding of the degree of heterogeneity of the key element contained within a sampling mass. This paper will describe the methods applied for the calculation of the fundamental sampling error and the techniques used to achieve a representative sample in the Fimiston Open Pit, Kalgoorlie.The utilisation of Pierre Gy's sampling theory has optimised the blast hole sample quality and quantity for submission to the assay laboratory. This has resulted in reduced cost and optimised assay reliability in statistical terms. Similarly the analysis of exploration drill holes for resource definition has optimised drilling procedures in terms of the drilling method, sample length and sample quantity.

Jan 1, 1993

Having provided basic data in the main paper I would now like to move on to discuss these areas in broader terms and to examine the various coalfields in terms of their tectonic setting and depositional environment and ultimately to make some brief comments on the factors which may have controlled deposition.

Jan 1, 1975

By C MacRae, N Wilson

CSIRO Minerals has recently developed an electron microprobe (EMP) based imaging (or mapping) method for characterising ilmenite concentrates. The method requires an electron microprobe analyser to collect elemental X-ray maps which are then processed via an in-house developed software module (CHIMAGE). The type of information readily available from EMP mapping includes; primary phase identification, modal analysis of phases, chemical analysis of individual phases, textural information (eg the alteration stages in the formation of leucoxene or pseudorutile from primary ilmenite and the development of macro-porosity), and the identification of coatings or pore-fill material. All of these parameters will impact on the choice of future downstream processing options considered for any particular ilmenite concentrate. The method has been demonstrated to be a sensitive analytical tool for assessing the distribution of aluminosilicate minor impurities in ilmenite feedstocks from the West Coast of Australia and also for characterising the complex chrome-spinel gangue phases common in East Coast ilmenite concentrates from the Murray Basin.

Jan 1, 2001

By Will D

This presentation is to outline the current practice of mechanised stoping a one-metre wide, gold bearing ore body to optimise fragmentation, minimise dilution and reduce stoping costs.Coolgardie underground operations have historically been mined using traditional shrink stope methods, but in this recent economic environment (with falling gold prices and high costs of traditional methods) it was necessary to look for alternative methods in order to reduce costs and increase productivity.Although still in a learning and refinement phase, CGNL is satisfied that it is feasible, practical and more economic to use mechanised long up-hole stope and long-hole rising methods to significantly reduce the mining cost, reduce dilution, increase safety and increase productivity three-fold compared to traditional airleg methods used throughout the Fasten Goldfields.

Jan 1, 1993

By V A. Diemar

The Chatree Gold Project represents a greenfields discovery of metallurgically clean shallow gold mineralisation in a logistically simple terrain. Total Measured, Indicated and Inferred Resources are currently 31 tonnes of gold and 160 tonnes of silver. Gold occurs in an adularia-sericite epithermal system within quartz-calcite-adularia veins, breccias and stockworks. Host rocks are volcanic arc porphyritic latite-trachyte flows, their pyroclastic equivalents and volcaniclastics of upper Permian to upper Triassic age. The mineralisation was deposited in dilated zones during repeated reactivation of pre-existing structures. To-date five mineralised prospects have been defined by drilling with three reaching JORC Code Mineral Resources status. The project is in its definitive feasibility stage and is anticipated to be in construction during 2000.

Jan 1, 1999

By Chappel R. A, Fishburn B. R

The Eastern Distributor Tunnels - the first major road tunnel project in Australia - are the preferred solution to traffic congestion problems, when compared with alternatives, in this inner urban environment. This is because of the reduced impact on residential housing, the improvement of the existing environment, less restrictions on future developments, and a reduction in noise and pollution. Developments leading to a tunnelled solution, traffic needs and reasons for route location are discussed. Criteria for design of tunnel alignments and geometry are described, including the restraints imposed by surface connections on profiles and grades resulting in low rock cover at tunnel portals. The main geotechnical restraints are a major weathered dyke at the shallow large span underground fork and the weathered Ashfield Shale capping the Hawkesbury Sandstone at a portal. Rock cuttability and excavation methods are discussed. Roadheader machines are the most suitable for the varying shallow arched cross sections required and the tunnel lengths involved but the use of blasting in special situations cannot be ruled out. Initial support for the major tunnel lengths will be provided by rock reinforcement in conjunction with shotcrete. Steel ribs are proposed in areas of low cover and weak ground. Final support will comprise an insitu concrete lining. Construction concepts and special tunnelling methods required at the shallow underground forks and tunnels are described.

Jan 1, 1987

By L W. Palmer

"Evaluating the geological risk associated with ore deposits is becoming common practice in the mining industry. While geostatistical simulation is a useful tool for evaluating this risk, the effect of applying different types of simulation is less understood. For simulation of categorical variables like rock types, available methods perform simulation in fundamentally different ways. In this study, the geological risk relevant for informed mine planning is studied with two categorical simulation methods, PluriGaussian Simulation (PGS) and Sequential Indicator Simulation (SIS). Risk is expressed as a probability of repeated occurrence of lithological units in the same location across simulations. Significant differences are observed between the methods in terms of spatial distribution of risk. To identify the most plausible risk model, the input parameters at every step of both techniques are scrutinised. PGS and SIS inputs are classified as four parameters that are: fundamental to implementation of the methodfixed to enable comparison of PGS and SISdetermined by user interpretation, hence variablenormally optimised during application of PGS and SIS. The effect of parameter selection from categories 1 and 4 on the risk model is investigated using drill core data from a leucogranite deposit. A corresponding block model is created for assigning outputs from PGS and SIS. Risk models produced by either method are illustrated in a cut-out from the block model to enable bench-by-bench comparison. For PGS, risk associated with relatively rare lithologies is relatively sensitive to variation of parameters. Independent of the abundance of lithology, a location-dependent effect of variogram and vertical proportion curve parameter selection is observed, with risk increasing towards the deposit edge. Although SIS requires fewer inputs, single lithologies must be modelled in turn. Using small numbers of samples in the search neighbourhood, all risk models differ substantially. For larger numbers of samples, the risk models are similar. Overall it appears that the risk model produced using SIS is less sensitive to changes than PGS but further work is required to confirm this.CITATION:Palmer, L W and Glass, H J, 2014. Risk associated with rock type prediction using simulation techniques, in Proceedings Ninth International Mining Geology Conference 2014 , pp 217–228 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Aug 18, 2014

By Guarascio M, Massacci P

In process simulation, more reliable prediction of industrial results and evaluation of data for design purposes and process optimisation may be attained by the combined use of: the modelling and simulation of ore characteristics, and 2. the modelling and simulation of the process. It is well known that geostatistical methods allow the defining of models of orebodies in which the variables considered are the grades of the valuable components. These models are proper for reserve estimation, geostatistical contouring, design and simulation of the exploitation method, and, in addition, for evaluating the variability of the ROM which is expected to be fed to the processing plant. However, no data are normally incorporated in the orebody model in order to evaluate the ore characteristics relevant for a reliable process simulation. The procedure for process simulation aimed at predicting plant results normally used so far consists in collecting samples from different orebody sites and building up a so-called 'representative sample'. On this sample, the ore characteristics (eg liberation, washability, grindability, etc) and the processing tests are referred to as the 'average behaviour in the orebody', assumed constant. A more reliable methodology consists in collecting samples from different orebody sites, in performing tests to characterise the samples from the point of view of the process (ore patterns), and in using synthetic parameters (process features). The values of the parameters are processed using geostatistical methods in order to develop a model for simulating the feed to the process. The estimation may thus be referred to the amount of recoverable minerals instead of to the existing minerals. Furthermore, the selection of the processes, the sizing of equipment and the design of control devices, as well as the prediction of results, become more accurate and reliable.

Jan 1, 1993

By Hoban M, Smith CJ

Norwich Park Mine commenced production of export coking coal in November 1979. Attention to consumables control was limited during the early running of the plant. Once higher than anticipated magnetite consumption levels were confirmed, efforts were directed at determining the causes. Extensive plant sampling, monitor- ing of operational procedures and plant modif- ications have led to a significant reduction in magnetite usage.

Jan 1, 1978

By S Gannon, J Abols, T Hughes

In the past year, two very innovative gold ore processing plants have been designed, built and commissioned by Gekko Systems Pty Ltd. The first plant in Vietnam utilises conventional crushing and ball milling followed by gravity concentration (Inline Pressure Jig (IPJ) and Falcon concentrator), flotation, intensive leaching (GFIL), the first industrial scale use of AuRIX«100å ion exchange resin and a cyanide destruction circuit. The second plant, in Australia, uses a three-stage crushing circuit to crush the gold ore to minus 1 mm, followed by gravity concentration utilising a rougher, scavenger, cleaner circuit of IPJs and a Falcon concentrator. A direct smeltable gold concentrate is produced as well as a lower grade concentrate for future intensive leaching or sale. Both plants were designed and built within very tight time frames and budgetary constraints. The experience gained during the plantsÆ design, commissioning and operation are discussed.

Jan 1, 2006

By Stewart Gillies A D, Just G. D

An internationally recognised and uniform method for classification, categorisation and designation of mineral and energy resources is not yet available. With the increasing need for reliable and comparable coal resource data it is necessary to standardise the traditional classification procedures by quantifying the three basic evaluation criteria of economic feasibility, geologic assurance and recovery. For well documented deposits, geostatistical methods can considerably improve classification quality. A review is undertaken of major classification with particular emphasis on those that incorporate limits on estimation error.A geostatistically based algorithm for classifying coal resources within the current Queensland and New South Wales codes has been developed.Application of the classification algorithm for resources from a number of seams exhibiting different structural characteristics is assessed. The method is found to give classification results that closely reflect the error associated with an estimate of resource quantities based on current sampling densities.lbis requires a careful geostatistical analysis with an emphasis on geological awareness. Resource category restrictions although albitrarily assigned should remain constant for all deposits being compared. This requires some engineering judgement with additional interpretation also required for isolated and peripheral block.

Jan 1, 1990

Since the announcement of early experimental work on rotating magnetic field (RMF) separation at the Sixth Mill OperatorsÆ Conference in 1997, the concept of RMF separation has been developed and tested further, and a range of separator designs is now being developed for the mineral processing industry. Shortened, but full diameter, prototypes of these designs are now available for test separations. The main advantage of RMF low and medium intensity attraction separation is the significant reduction in particle entrapment. This reduction is so significant that RMF separators are capable of operating very close to their theoretical limit for separator precision. This makes small laboratory RMF attraction separators ideal for low to medium intensity magnetic sample analysis, and larger separators ideal for applications requiring sharp magnetic susceptibility splits. Feedrates and separation rates are comparable to those of conventional attraction separators. Although RMF attraction separators are now well advanced in development, RMF rotation separation is still in the early experimental stage. The exception to this is the dry particle rotation eddy current separator that offers eddy current separation of small non-ferrous metallic particles from about 2 mm down to about 100 microns. Wet small particle eddy current separation is also possible, but has not yet been developed to a practical stage.

Jan 1, 2000

By Feilding C

Vitrinite of humic source (often designated as vitrinite A) is the maceral by which the rank of a coal ought to be determined. Therefore its recognition, and the precise identification of other vitrinites is essential. The majority of Australian petrologists are not differentiating between the vitrinite group macerals in maturation studies, the results of which have led to unexplained phenomena in coal characterisations and evaluation, such as 'reactive inertinites' and inaccurate predictions in petroleum source rock studies. The Callide coal has been chosen as a case study, with examples from other coals. The coal seams from the Callide Coal Measures show variation in the predominance of some macerals, indicating successions of environmental changes. The application of transmission electron microscopy (TEM) to the study of the Callide coal has enabled a better understanding of the nature and origin of some of the less understood macerals such as micrinite and vitrinite B. Two forms of vitrinite have been observed, each with a distinct reflectance range. The wood-sourced vitrinite A displays an average reflectance of 0.56 per cent, and a range of 05. - 0.7, implying a higher rank than the 0.49 per cent Ro total vitrinite reflectance recorded in previous publications. Vitrinite B is one of the most commonly-occurring macerals in the Callide coal. The lower-reflecting vitrinite B which forms bands, often several hundred microns in thickness, in TEM appears to be electron transparent lipid rich. Vitrinite B is interpreted to represent accumulations of leaves, and is believed to be a major source of hydrocarbons in Australian sedimentary basins. The Callide coal has entered the oil window, and oil has been generated from some exinite, cutinite, and resinite, as evident from the amber to light brown fluorescence of exinite and the presence of exsudatinite in cell cavities and cleats. However vitrinite B, the major potential source of oil, is seen under the microscope to be generating oil, thus placing this coal at the top of the oil window. Micrinite, the origin of which has been much debated, occurs as cell filling or infill of spaces between laminations in vitrinite B.

Jan 1, 1991

The application of methods using large diameter down holes has become an important facet in both the development and stoping operations of mines within the Aberfoyle group. Holes of up to 98 metres (vertical) and 78 metres (inclined) have been successfully used in stoping operations. A number of rises have been developed to meet ventilation, servicing and escape-way requirements. The most ambitious rise to date has been a..vertical 93 metre long by 4.50 metre square ventilation rise. Although some early problems were experienced, the ultimate successful completion of this rise has enabled the technique to be incorporated with confidence in future mining plans. This paper summarises experience in long hole rising techniques, their evolution from the original cratering concepts, and the approach to further development of these techniques.

Jan 1, 1982

This paper presents results of the experiments carried out in Beth Energy No. 33 Mine for the purpose of alleviating problems associated with cutter roof. Cutter roof problems have delayed the advance of the entry development considerably and maintenance cost of these entries was very high due to the requirement of very extensive and heavy artificial supports. The study includes assessment of the problem, investigation of the geology and lithology of the mines, study of in-situ stresses and corrective measures to combat the problem. Two approaches were selected as the corrective measures: 1) implementing yield pillar concept in order to reduce the effects of in-situ horizontal stresses, 2) designing an effective roof reinforcement system and application procedure. Results of this study revealed that roof strata is weak and in-situ stresses are very high at the problem area which results in development of cutter roof. Implementation of yield pillar concept was found to be ineffective because cutter roof often developed at the entry face concurrent to the development. However, proper design and implementation of roof reinforcement system stabilized the roof and eliminated roof caving during both entry development and retreat of longwall face, despite existence of the cutter roof, at a much lower cost.

Jan 1, 1992

By Enever JR

In-situ rock stress measurements conducted in the Phillipines and on Bougainville have revealed stress fields significantly different from expectations based on intraplate experience. The results have potential significance in regard to both engineering practice in the Pacific Rim region as well as in helping to understand the geological processes occuring near subduction Zones.

Jan 1, 1987